专利号:US-9040444-B2 优先权日:2009-12-22 标 题:Semi continuous process for the synthesis of a catalyst for use in the manufacture of polyolefins 发明人:SINGALA KAMLESH; SINGH SAURABH; GUPTA VIRENDRAKUMAR 权利人:SINGALA KAMLESH; SINGH SAURABH; GUPTA VIRENDRAKUMAR; RELIANCE IND LTD 摘要:A semi-continuous process and system thereof, for the synthesis of a narrow particle size distribution Zeigler Natta procatalyst for use in the manufacture of polyolefins. The process comprises: (a) mixing a reaction mixture containing a titanium compound; (b) charging a first reactor with said reaction mixture; (c) removing excess reactants from said first reactor as a filtrate; (d) feeding said filtrate to at least one further reactor; and continuously removing excess reactants from said at least further reactor.
专利号:US-9605089-B2 优先权日:2010-07-12 标题 :Attrition resistant catalyst system for manufacture of polyolefins 发明人:GUPTA VIRENDRAKUMAR; SINGH SAURABH; JOSEPH JOMICHAN; SINGALA KAMLESH J; DESAI BHAVESH K 权利人:RELIANCE IND LTD 摘要:The present invention relates to regular shaped magnesium particles containing attrition resistant precursors and procatalysts thereof and processes for their synthesis and their use in the manufacture of polyolefins. More particularly, the present invention relates to a process for the synthesis of a said precursor particles which give highly active and improved surface area procatalysts for producing high bulk density polyolefin resins containing low fines and capable of incorporating high rubber content. In particular, the present invention relates to process for the synthesis of an attrition resistant precursors to prepare an attrition resistant Zeigler Natta procatalysts synthesized by using the precursors and to the polyolefin resin synthesized using the said procatalysts.
专利号:US-6054625-A 优先权日:1999-05-27 标题 :Heteropolyacids as catalysts for a synthesis of ketone peroxides 发明人:FRENKEL PETER; NWOKO DELPHINE; PETTIJOHN TED M 权利人:WITCO CORP 摘要:The process of preparing geminal dihydroperoxy alkyl peroxides and 1,1-dihydroperoxydialkyl peroxides, which comprises reacting an aqueous composition comprising a ketone with hydrogen peroxide in the presence of a heteropolyacid.
专利号:US-9687428-B2 优先权日:2001-05-01 标题 :Hydrogel compositions for tooth whitening 发明人:SINGH PARMINDER; CLEARY GARY W; MUDUMBA SRI; FELDSTEIN MIKHAIL M; BAYRAMOV DANIR F 权利人:A V TOPCHIEV INST OF PETROCHEMICAL SYNTHESIS RUSSIAN ACAD OF SCIENCES; CORIUM INT INC; A V TOPCHIEV INST OF PETROCHEMICAL SYNTHESIS RUSSIAN ACAD OF SCIENCES 摘要:A composition is provided, wherein the composition comprises a water-swellable, water insoluble polymer, a blend of a hydrophilic polymer and a complementary oligomer capable of hydrogen bonding to the hydrophilic polymer, and a whitening agent, preferably a peroxide. The composition finds utility as a tooth whitening composition and is applied to the teeth in need of whitening, and then removed when the degree of whitening has been achieved. In certain embodiments, the composition is translucent. Methods for preparing and using the compositions are also disclosed.
专利号:US-8633124-B2 优先权日:2008-04-25 标 题 :Spheroidal particles for olefin polymerization catalyst 发明人:GUPTA VIRENDRAKUMAR; SINGH SAURABH; MAKWANA UMESH; JOSEPH JOMICHAN; SINGALA KAMLESH; RAJESH SMITHA; PATEL VALLABHBHAI; YADAV MUKESHKUMAR; SINGH GURMEET 权利人:GUPTA VIRENDRAKUMAR; SINGH SAURABH; MAKWANA UMESH; JOSEPH JOMICHAN; SINGALA KAMLESH; RAJESH SMITHA; PATEL VALLABHBHAI; YADAV MUKESHKUMAR; SINGH GURMEET; RELIANCE IND LTD 摘要:The invention relates to a process for the synthesis of spheroidal magnesium alkoxide having improved mechanical strength and narrow particle size distribution, the process comprising reacting magnesium metal, in the presence of iodine, with a mixture of alcohols by step-wise heating first in the range of 40° C. to 65° C. for a period of 2 hours and then in the range of 65° C. to 80° C. for a period of 1 hour, further by maintaining reaction temperature at 80° C. for a period of 6-10 hours, the vapors of the mixture produced during the reaction being condensed in an overhead condenser, hydrogen gas produced during the reaction being vented off and the mixture of alcohols left after the reaction being filtered and reused. The invention also relates to spheroidal magnesium alkoxide particles synthesized by the method, to the Ziegler natta procatalyst synthesized by using the alkoxide and to the polymer resin synthesized using the procatalyst.
专利号:US-2013053521-A1 优先权日:2009-12-22 标 题 :Semi continuous process for the synthesis of a catalyst for use in the manufacture of polyolefins
1: Kurohane K, Kimura A, Terasawa R, Kobayashi K, Suzuki W, Matsuoka T, Imai Y. An Aliphatic Ester Diisopropyl Sebacate Exhibited an Adjuvant Effect on Fluorescein Isothiocyanate-Induced Contact Hypersensitivity Mouse Models. Biol Pharm Bull. 2018 Jan 1;41(1):147-150. doi: 10.1248/bpb.b17-00723. Epub 2017 Oct 27. doi: 10.1002/jsfa.8028. Epub 2016 Nov 1. doi: 10.1248/bpb.b15-00199. Epub 2015 May 9. doi: 10.1080/19440049.2013.781683. Epub 2013 Apr 24. doi: 10.1080/19440049.2011.644588. Epub 2012 Jan 18. doi: 10.1021/jf902683m. doi: 10.1897/07-399. Epub 2008 Feb 9.
合成参考文献
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198 摘要:Fogel, M. S.; Shellnutt, Z. S.; Koide, K., Science of Synthesis: Dearomatizations, (2026) .