📜苯硅烷置于potassium Fluoride,Copper(L) Iodide,Copper Dichloride体系中,用 四氢呋喃 作为反应溶剂,化学反应 168000.0H,以53%的收率获得产物苯基三氟硅烷
参考文献:Selective Synthesis Of Halosilanes From Hydrosilanes And Utilization For Organic Synthesis
标题:Selective Synthesis Of Halosilanes From Hydrosilanes And Utilization For Organic Synthesis
摘要:Selective Synthesis Of Halosilanes Has Been Examined. Various Types Of Halosilanes And Halohydrosilanes,Such As R3Six,R2Sihx,R2Six2,Rsih2X,Rsihx2 (X = Cl,Br,F),Were Obtained By The Reactions Of The Corresponding Hydrosilanes With Cu(II)-Based Reagents Selectively In High Yields. This Method Could Be Also Applied To The Synthesis Of Chlorofluorosilanes And Chlorohydrogermanes. On The Other Hand,Iodo-And Bromosilanes And Germanes Were Obtained By Pd-Or Ni-Catalyzed Hydride-Halogen Exchange Reactions Of Hydrosilanes With Alkyl Or Allyl Halides. Their Synthetic Applications Have Been Demonstrated By Using Iodo-And Bromosilanes And Chlorofluorosilanes. (C) 2003 Elsevier Science B.V. All Rights Reserved.
DOI:10.1016/s0022-328X(03)00254-7