CAS: 17283-81-7; 4-(2,6,6-Trimethylcyclohex-1-En-1-yl)Butan-2-One
该化合物是一种有机化合物,被归类为类,特别是-离子的衍生物;其特点是其美味,花粉和果味芳香,在香味和口味行业中成为流行成分;二氢-离子的分子结构具有环状环状,配有氯酮功能组,有助于其独特的气味特征;该化合物一般在室内温度下是无色的,不为黄色的黄色液体,在有机溶剂中溶解,但在水中溶解,但溶解性有限;二氢-离子由于具有诱人的嗅觉特性,常常用于香水,化妆品和食品调味;此外,它可能表现出某种生物活动,尽管其主要用途是在香味和口味部门;安全数据表明,应当谨慎处理,如同许多化学物质一样,以避免潜在的刺激或过敏反应.
- 英文名称4-(2,6,6-Trimethylcyclohex-1-En-1-yl)Butan-2-One
- 中文名称4-(2,6,6-三甲基-1-环己烯-1-基)-2-丁酮
- IUPAC名称4-(2,6,6-trimethylcyclohex-1-en-1-yl)butan-2-one
- 其它别名二氢-β-紫罗兰酮; Dihydro-Beta-Ionone
- CAS编号17283-81-7
- MFCD编号:MFCD00456730
- EINECS号:241-318-1
- FDA UNII编号:710YK6CESE
- 分子式:C13H22O分子量:194.32
- 产品CID: 884254
- 产品分类有机原料→分子砌块→脂肪环类化合物→环己烷类化合物
相似化合物
472-66-2 3293-47-8 17283-81-7物理性质
- 熔点311 °C
- 沸点263.5±19.0°C at 760 mmHg
- 闪点93.8±8.4 °C
- 密度0.9±0.1 g/cm3
- PSA:17.07
- LogP:3.8822
- 折射率1.453
- 蒸汽压0.0±0.5 mmHg at 25°C
- 溶解性Soluble In Chloroform, Methanol
- 敏感性1. 存在于主流烟气中。2. 天然存在于桂花净油以及草莓等水果中。
- 外观形态透明无色油状物
- 储存条件Store at room temperature
- 产品应用二氢-β-紫罗兰酮(17283-81-7)的用途:GB 2760-96规定为暂时允许使用的食用香料.主要用于配制桂花等型香精.
- 性质描述二氢-β-紫罗兰酮(17283-81-7)的性状:无色至淡黄色透明液体.呈木香和桂花似花香,香气清甜,浓郁.沸点236°C或90°C(26.6Pa).溶于乙醇.折射率(褶)1.47～1.48.天然品存在于杏,草莓,黑莓,青豆,桂花,净油等中.
MSDS等安全信息
欧盟法规
REACH注册ECHA物质C&L通报REACH预注册上下游产品
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- 合成目标产物 Dihydro-Beta-Ionone 主要起始原料 2,2-Dimethyl-6-Oxocyclohexanecarboxylic Acid Methyl Ester
- (文献来源)合成步骤主要原料 2,2-Dimethyl-6-Oxocyclohexanecarboxylic Acid Methyl Ester
📜1-<2'-(P-Toluenesulfonyl)Ethyl>-2-Methylene-6,6-Dimethylcyclohexane置于二苯并-18-冠醚-6 盐酸体系中,用 四氢呋喃,乙腈 用作溶剂,化学反应 19.0H,反应生成Beta-二氢紫罗兰酮
参考文献:Total Synthesis Of Dehydroambliol-A And Its Unnatural Z Isomer
标题:Total Synthesis Of Dehydroambliol-A And Its Unnatural Z Isomer
摘要:Convergent Total Syntheses Of Dehydroambliol-A (1A),Its Unnatural Z Isomer 1B,And Ambliofuran (2) Are Described. The Syntheses Utilized 2-(3'-Furyl)-1,3-Dithiane (6) As A Common Intermediate. Analysis Of Their Proton And Carbon Magnetic Resonance Spectra Confirm That In The Natural Product Dehydroambliol-A And In Synthetic Dehydroambliol-A The Delta-7-Bond Possesses The E Geometry,While In The Unnatural Isomer Of Dehydroambliol-A,The Delta-7-Bond Is Of The Z Configuration.
Doi:10.1021/jo00009A033
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2912110000-甲醛
2912120000-乙醛 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:CN-118580327-B
优先权日:2024-08-01
标题 :Application of RcCCD4 gene in the synthesis of dihydro-β-ionone, a fragrance substance of rose
专利号:CN-116375829-B
优先权日:2022-12-15
标 题:Application of Osmanthus fragrans OfWRKY36 gene in enhancement of synthesis of plant dihydro-beta-ionone
专利号:CN-116375829-A
优先权日:2022-12-15
标 题:Application of Osmanthus fragrans OfWRKY36 gene in enhancement of synthesis of plant dihydro-beta-ionone
专利号:EP-3628658-A1
优先权日:2018-09-28
标 题:Synthesis of substituted enones
专利号:CN-118580327-A
优先权日:2024-08-01
标题 :Application of RcCCD gene in synthesis of rose fragrance substance dihydro-beta-ionone
专利号:WO-2025120108-A1
优先权日:2023-12-08
标 题:Isomerization process
发明人：JACOBY DENIS; HENRION MICKAEL; KELLER FABRICE
权利人:FIRMENICH & CIE
摘要:The present invention relates to the field of organic synthesis. More particularly, it provides a process for the preparation of a mixture comprising at least a compound of formula (Ia) and at least one compound of formula (Ib) comprising the step of reacting a compound of formula (II) with a catalyst system comprising palladium (Pd) and molecular hydrogen or a hydrogen source.
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Tchabanenko, K., Science of Synthesis Knowledge Updates, (2013) 1, 67.
摘要:Llopis, Q.; Ayad, T.; Phansavath, P.; Ratovelomanana-Vidal, V., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2018) 2, 100.
摘要:van der Puyl, V.; Shenvi, R. A., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 625.
摘要:van der Puyl, V.; Shenvi, R. A., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 629.
参考文献:10.1073/pnas.69.8.2086
摘要:Shimomura O, Johnson FH, Kohama Y. Reactions Involved in Bioluminescence Systems of Limpet ( Latia neritoides ) and Luminous Bacteria. Proc. Natl. Acad. Sci. U.S.A. 1972 Aug;69(8):2086–9. doi: 10.1073/pnas.69.8.2086.
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