CAS: 19423-76-8; Cerium(Iii) Chloride Hydrate, Reacton
该化合物是一种多用途无机化合物,广泛用于有机合成,催化和材料科学,其主要优点包括:作为刘易斯酸的高度反应性,有利于交叉反应,减少和高温凝聚等变异,水化形式在极地溶剂中提供了更好的处理和溶解能力,而没有水分变异物. 氯化水合物(CeCl3-xH2O)也用于发光材料,并用作以为基础的纳米材料的前体.在环境条件下,其稳定性和持续性能使它成为研究和工业应用的可靠选择.该化合物作为红氧化催化剂的能力进一步增强了其在氧化减少过程中的效用.
- 相似结构搜索
- InChIKey: SMKFCFKIYPLYNY-UHFFFAOYSA-K
- 1S/Ce.3ClH.H2O/h;3*1H;1H2/q+3;;;;/p-3
- 计算化学: 氢键受体数*氢键供体数0可旋转键数0
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hydrogenchloride water hydrazine hydr°Chloridecerium orthophosphate cerium chloride monohydrate 3(triphenylphosphine oxide)3][Ce(III)Cl3(triphenylphosphine oxide)3]合成工艺路线路线简述
📜Cerium(III) Chloride Heptahydrate 反应生成水合氯化铈
参考文献:The Presence Of Water In The Common Cecl3/rli Alkylation System
标题:The Presence Of Water In The Common Cecl3/rli Alkylation System
摘要:Dehydration Of Cecl3(H2O)(7) Following Standard Procedures For Making The Commonly-Used Cecl3/rli Reagent Forms A Material Containing Water And Not Anhydrous Cecl3. Heating Cecl3(H2O)(7) At 150 Degrees C And 0.03 Torr For 12 H Forms A Material Which Has An Elemental Composition Of [cecl3(H2O)](N),Contains Water By Karl Fischer Analysis,Reacts With Meli To Form Methane,And Crystallizes From Thf As [ce(Mu-Cl)(3)(Thf)(H2O)](N),In Space Group With A = 6.691(2) Angstrom,B = 7.433(2) Angstrom,C = 10.092(2) Angstrom,Alpha = 84.46(2)Degrees,Beta = 76.72(2)Degrees,Gamma = 74.76(3)Degrees,V = 471.0(2) Angstrom(3),Rho(Calcd) = 2.37 G/cm(3),And Z = 2 At T = 158 K. [ce(Mu-Cl)(3)(Thf)(H2O)](N) Crystallizes In A Layered Structure In Which Eight-Coordinate Cerium Atoms Are Ligated To Terminal Water And Thf Ligands And Six Bridging Chlorides In A Distorted Square Antiprismatic Geometry. The Thf Ligands Extend Above And Below The Layers Which Contain The Water Molecules. Reactions Of ''Cecl3/rli'' Must Take Into Account The Presence Of 1 Equiv Of Water.
Doi:10.1021/ja954276W
