CAS: 14593-43-2; ((Allyloxy)Methyl)Benzene

相似化合物

75405-55-9 539-30-0 4039-82-1

上下游产品

((Buta-2,3-Dien-1-Yloxy)Methyl)Benzene
顺-1,4-二苄氧基-2-丁烯 (Z)-1,4-Dibenzyloxy-2-Butene 68972-96-3
苄基丙炔基醚 1-Benzyloxyprop-2-Yne 4039-82-1
4-苄氧基-1-丁醇 4-Benzyloxybutanol 4541-14-4
Benzaldehyde Diallyl Acetal 56318-28-6
苄基氯甲基醚 Benzyloxymethyl Chloride 3587-60-8
1-Benzyloxyallene 67515-49-5
烯丙基-2-溴苯甲基醚 Allyl 2-Bromobenzyl Ether 87280-01-1 2-Phenyl-1,3-Dioxolane 936-51-6 Benzyl Alcohol 100-51-6

苄基丙炔基醚置于甲醇,Copper Acetylacetonate,四丁基碘化铵体系中,用 乙腈 用作溶剂,以92 %的收率获得烯丙基苄基醚
参考文献:原位形成的铜纳米颗粒电极上炔烃的无膜选择性半氢化
标题:原位形成的铜纳米颗粒电极上炔烃的无膜选择性半氢化
摘要:炔烃的选择性半氢化是制备官能化烯烃的重要反应.电化学半氢化提供了传统热工艺的可持续替代方案.在这项研究中,采用经济实惠的乙酰丙酮铜作为炔烃电催化氢化的催化剂前体,在未分隔的电池中使用甲醇作为氢源.在恒定电流条件下,芳族和脂族内/端炔烃均获得非常好至优异的收率.值得注意的是,对于各种内炔烃,Z 选择性高达 99%.机理研究揭示了电解过程中在阴极形成铜纳米颗粒(np),充当炔烃选择性半还原的催化剂.铜纳米粒子沉积的阴极被证明可重复用于进一步氢化.
Doi:10.1002/smll.202401107

专利信息

专利号:US-9000209-B2
优先权日:2011-07-22
标题:Method of regioselective synthesis of substituted benzoates
发明人：KRAUS GEORGE A
权利人:KRAUS GEORGE A; UNIV IOWA STATE RES FOUND INC
摘要:A method of synthesis of para-substituted benzoate esters and acids is provided, wherein the para-substituted regioisomer is obtained substantially free of the meta-substituted impurity, the method comprising contacting a coumalate ester or acid and an unactivated alkene at elevated temperature in the presence of a metal oxidation catalyst and an oxidant. The metal oxidation catalyst can be palladium, such as palladium on carbon, and the oxidant can be the oxygen gas in ambient air. The reaction can be carried out without solvent or in high boiling hydrocarbon solvents such as mesitylene. When the unactivated alkene is a monosubstituted alkene, yields of at least about 50 or 60% of para-substituted ester and acid products, respectively, are obtained, substantially free of the regioisomeric meta-substituted impurity.

专利号:US-2023174477-A1
优先权日:2021-12-03
标题:Methods for synthesis of the tricyclic prostaglandin d2 metabolite methyl ester
发明人：DAI MINGJI; SIMS HUNTER
权利人:PURDUE RESEARCH FOUNDATION
摘要:Methods for the synthesis of a tricyclic-prostaglandin D 2 metabolite methyl ester or a pharmaceutically acceptable salt thereof.

专利号:US-9834570-B2
优先权日:2013-06-03
标 题 :One step process for regioselective synthesis of α-acyloxy carbonyls
发明人：SUDALAI ARUMUGAM; REDDI RAMBABU; MALEKAR PUSHPA
权利人:COUNCIL SCIENT IND RES
摘要:A regioselective N-Heterocyclic Carbene (NHC) catalyzed one step process for high yield synthesis of α-acyloxy carbonyl compounds is disclosed.

专利号:US-8202985-B2
优先权日:2005-10-31
标 题:Monomer compositions for the synthesis of polynucleotides, methods of synthesis, and methods of deprotection
发明人：DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H
权利人:DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H; AGILENT TECHNOLOGIES INC; UNIV COLORADO
摘要:Nucleotide monomers, polynucleotides, methods of making each, and methods of deprotecting each, are disclosed. An embodiment of the nucleotide monomer, among others, includes a nucleotide monomer having a heterobase protecting group selected from structures I through III as described herein. An embodiment of the polynucleotide, among others, includes a plurality of nucleotide moieties having a heterobase protecting group selected from one of structures I through III as described herein.

专利号:US-7759471-B2
优先权日:2005-10-31
标题 :Monomer compositions for the synthesis of RNA, methods of synthesis, and methods of deprotection
发明人：DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINE; CARUTHERS MARVIN H
权利人:AGILENT TECHNOLOGIES INC; UNIV COLORADO
摘要:Nucleotide monomers, polynucleotides, methods of making each, methods of deprotecting each, and the like are disclosed herein.

专利号:US-9371334-B2
优先权日:2010-09-22
标题:Synthesis of substituted salicylaldehyde derivatives
发明人：FARMER JAY J; JOB GABRIEL E
权利人:NOVOMER INC
摘要:Among other things, the present invention encompasses methods of synthesizing salicylaldehyde derivatives comprising the steps of: a) providing salicylaldehyde or a derivative thereof, b) forming an anhydro dimer of the provided salicylaldehyde compound, c) performing one or more chemical transformations on the anhydro dimer and d) hydrolyzing the anhydro dimer to provide a salicylaldehyde derivative different from that provided in step (a).