CAS: 94280-72-5; N-Butyl-N-Methyl-Piperidinium Bromide

该化合物是一种四硝基铵盐,可应用于离子液体化学和催化,其稳定的基结构具有低挥发性和高热稳定性,适合用作溶剂或电解剂用于电化学系统,该化合物还因其在有机合成和材料科学方面的潜力而受到重视.

结构式图片

相似化合物

88840-42-0 24307-26-4 77542-18-8

上下游产品

CAS号626-67-5 1-甲基哌啶 | CAS号109-65-9 正溴丁烷

合成工艺路线路线简述

  • 合成目标产物 1-Butyl-1-Methylpiperidinium Bromide 主要起始原料 N-Methylpiperidine And Tributylphosphine
  • 626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Ethyl Acetate; 20 °C; 16 H,30 °C; 3 H,50 °C
    标题:Importance Of Weak Interactions And Conformational Equilibrium In N-Butyl-N-Methylpiperidinium Bis(Trifluromethanesulfonyl) Imide Room Temperature Ionic Liquids: Vibrational And Theoretical Studies
    作者:Shukla,Madhulata; Noothalapati,Hemanth; Shigeto,Shinsuke; Saha,Satyen
    参考文献:Vibrational Spectroscopy 日期:2014 卷标:75 页码:107-117]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Acetonitrile; 48 H,65 °C
    标题:Newly Designed Flow Reactor As An Original Method Of Synthesis Of Ionic Liquids By Ion-Exchange Reactions
    作者:Pawlowska-Zygarowicz,Anna
    参考文献:Tetrahedron Letters 日期:2021 卷标:86]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Acetonitrile; 3 H,50 °C
    标题:Rational Selection Of The Cation Of An Ionic Liquid To Control The Reaction Outcome Of A Substitution Reaction
    作者:Hawker,Rebecca R.; Haines,Ronald S.; Harper,Jason B.
    参考文献:Chemical Communications (Cambridge 日期:2018 卷标:54(18) 页码:2296-2299]

    4945-48-6 + 67-68-5 = 94280-72-5
    反应条件:1.1 Reagents: 1,3-Dibromo-5,5-Dimethylhydantoin,Styrene,Sodium Bicarbonate Solvents: Dimethyl Sulfoxide; 10 H,40 °C
    标题:Oxidative Thioesterification Of Alkenes Mediated By 1,3-Dibromo-5,5-Dimethylhydantoin And Dmso For The Synthesis Of α-Ketothioesters
    作者:Hua,Jiawei; Xu,Jiaqi; Xu,Jia; Zhou,Bochao; Zhang,Dong; Et Al
    参考文献:European Journal Of Organic Chemistry 日期:2019 卷标:2019(25) 页码:4056-4060]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Ethanol; 40 °C; 24 H,40 °C
    标题:In Situ Co2 Capture And Transformation Into Cyclic Carbonates Using Flue Gas
    作者:Ma,Haiying; Liu,Shujuan; Wang,Hongli; Li,Guomin; Zhao,Kang; Et Al
    参考文献:Green Chemistry 日期:2023 卷标:25(6) 页码:2293-2298]

    626-67-5 = 94280-72-5
    反应条件:1.1 48 - 72 H,70 °C
    标题:X-Ray Photoelectron Spectroscopy Of Piperidinium Ionic Liquids: A Comparison To The Charge Delocalised Pyridinium Analogues
    作者:Men,Shuang; Licence,Peter; Do-Thanh,Chi-Linh; Luo,Huimin; Dai,Sheng
    参考文献:Physical Chemistry Chemical Physics 日期:2020 卷标:22(21) 页码:11976-11983]

    626-67-5 = 94280-72-5
    反应条件:1.1 4 D,Rt
    标题:Competing Reactions Of Co2 With Cations And Anions In Azolide Ionic Liquids
    作者:Gohndrone,Thomas R.; Lee,Tae Bum; De Silva,M. Aruni; Quiroz-Guzman,Mauricio; Schneider,William F.; Et Al
    参考文献:Chemsuschem 日期:2014 卷标:7(7) 页码:1970-1975]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Isopropanol; Rt; Rt -> 40 °C; 6 H,40 °C
    标题:Lubricating Greases Containing Two Kinds Of Ionic Liquids As Base Oils
    参考文献:Japan]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Ethyl Acetate; 3 H,70 °C
    标题:Nanoscale Organization In Piperidinium-Based Room Temperature Ionic Liquids
    作者:Triolo,Alessandro; Russina,Olga; Fazio,Barbara; Appetecchi,Giovanni Battista; Carewska,Maria; Et Al
    参考文献:Journal Of Chemical Physics 日期:2009 卷标:130(16)]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Acetone; 48 H,Rt
    标题:Effect Of 1-Alkyl-1-Methylpiperidinium Bromides On Lipids Of Fungal Plasma Membrane And Lung Surfactant
    作者:Dopierala,Katarzyna; Syguda,Anna; Wojcieszak,Marta; Materna,Katarzyna
    参考文献:Chemistry And Physics Of Lipids 日期:2022 卷标:248]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Acetone; Rt; 24 H,Reflux
    标题:Cyclic Quaternary Ammonium Ionic Liquids With Perfluoroalkyltrifluoroborates: Synthesis,Characterization,And Properties
    作者:Zhou,Zhi-Bin; Matsumoto,Hajime; Tatsumi,Kuniaki
    参考文献:Chemistry - A European Journal 日期:2006 卷标:12(8) 页码:2196-2212]

    626-67-5 = 94280-72-5
    反应条件:1.1 2 H,80 °C
    标题:Chemically Stable Piperidinium Cations For Anion Exchange Membranes
    作者:Li,Jinyuan; Yang,Congrong; Wang,Suli; Xia,Zhangxun; Sun,Gongquan
    参考文献:Rsc Advances 日期:2022 卷标:12(41) 页码:26542-26549]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Ethanol; 12 H,60 °C
    标题:Synthesis And Performance Of Piperidinium-Based Ionic Liquids As Catalyst For Alkylation Of P-Xylene With 1-Hexadecene
    作者:Ge,Sujuan; Zhou,Yuming; Sheng,Xiaoli; Mao,Chunfeng; Zhao,Lina; Et Al
    参考文献:Applied Organometallic Chemistry 日期:2021 卷标:35(4)]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Ethyl Acetate; 12 H,363 - 368 K
    标题:Ultrafast Dynamics In Nonaromatic Cation Based Ionic Liquids: A Femtosecond Raman-Induced Kerr Effect Spectroscopic Study
    作者:Shirota,Hideaki; Ando,Masatoshi; Kakinuma,Shohei; Takahashi,Kotaro
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:2020 卷标:93(12) 页码:1520-1539]

    626-67-5 = 94280-72-5
    反应条件:1.1 25 °C; 16 H,50 °C
    标题:Synthesis Of Task-Specific Imidazolium Ionic Liquid As An Efficient Catalyst In Acetylation Of Alcohols,Phenols,And Amines
    作者:Chaubey,Snehkrishn A.; Mishra,Roli
    参考文献:Chemical Papers 日期:2020 卷标:74(10) 页码:3259-3268]

    626-67-5 + 120-94-5 = 94280-72-5
    反应条件:1.1 Solvents: Toluene; 20 Min,Rt; 5 H,343 K
    标题:Solubility And Diffusivity Of Oxygen In Ionic Liquids
    作者:Song,Tangqiumei; Morales-Collazo,Oscar; Brennecke,Joan F.
    参考文献:Journal Of Chemical & Engineering Data 日期:2019 卷标:64(11) 页码:4956-4967]

    626-67-5 = 94280-72-5
    反应条件:1.1 Solvents: Acetonitrile; Rt; Rt -> 70 °C; 48 H,70 °C
    标题:Dissolution Of Oligo(Tetrafluoroethylene) And Preparation Of Poly(Tetrafluoroethylene)-Based Composites By Using Fluorinated Ionic Liquids
    作者:Tsurumaki,Akiko; Ohno,Hiroyuki
    参考文献:Chemical Communications (Cambridge 日期:2018 卷标:54(4) 页码:409-412]

    626-67-5 = 94280-72-5 [标题:Reaction Conditions
    标题:Gelated Ionic Liquid Film-Coated Surfaces And Uses Thereof
    参考文献:World Intellectual Property Organization
📜N-甲基哌啶,正溴丁烷 反应 20.0H,以1.6%的收率获得产物n-丁基-N-甲基哌啶溴盐
参考文献:用于制备离子凝胶薄膜和图案的离子液体的化学气相沉积
标题:用于制备离子凝胶薄膜和图案的离子液体的化学气相沉积
摘要:离子液体的化学气相沉积允许形成高分辨率的离子凝胶薄膜和微滴.通过两种非挥发性前体的反应在表面上形成非挥发性离子液体.广泛的应用将受益于这种新的"il-Cvd"方法,它能够制造微型器件.
DOI:10.1002/anie.202110022

海关参考信息

专利信息


专利号:WO-2024013423-A1
优先权日:2022-07-14
标题:Method for polyurethane depolymerization
发明人:LOZANO RODRÃ?GUEZ PEDRO; VILLA AROCA ROCÃ?O; SALAS VIDAL REBECA; GARCÃ?A-VERDUGO CEPEDA EDUARDO; MACIÃ? DELGADO MARÃ?A
权利人:UNIV MURCIA; UNIV JAUME I; ASOC EMPRESARIAL CENTRO TECNOLOGICO DEL MUEBLE Y LA MADERA DE LA REGION DE MURCIA
摘要:The present invention relates to a method for the depolymerization of a polyurethane mass, preferably thermoset polyurethane. The method comprises four main steps: i) mixing the polyurethane mass with a depolymerization reaction medium comprising an ionic liquid in a proportion equal to or greater than 50% w/w with respect to the total weight of said medium, a superbase as a catalyst, and a nucleophilic agent in a proportion equal to or less than 15% w/w with respect to the total weight of said medium, subjecting said mixture to a temperature between 50-100°C for between 2 minutes and 10 hours; ii) adding a mass of a protic molecular solvent in an amount between 4 and 40 times the weight of the depolymerization reaction medium; iii) subjecting the mixture from step ii) to a temperature between 20-60°C for at least 1 hour; and iv) separating the fractions obtained in step iii), namely, a semisolid fraction comprising at least a polyol mass for reuse in the synthesis of a new polyurethane, and a single-phase liquid fraction comprising at least the ionic liquid and the basic catalyst, for their reuse in a new process for polyurethane depolymerization.

专利号:CN-117660992-A
优先权日:2023-11-29
标题:Synthesis method of organosilicon compound containing Si-O bond

专利号:CN-117887453-A
优先权日:2024-01-22
标题:A kind of AB position co-doped manganese ion halide nanomaterial and its synthesis method

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✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1007/s11581-024-05889-4
摘要:Kyzlasova D, Ulihin A, Uvarov N. Phase behavior and electrochemical properties of lithium-doped N-methyl-N-propyl-piperidinium perchlorate. Ionics. 2024 Oct 18;30(12):8105–15. doi: 10.1007/s11581-024-05889-4.
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