合成目标产物 1-Butyl-1-Methylpiperidinium Bromide 主要起始原料 N-Methylpiperidine And Tributylphosphine
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Ethyl Acetate; 20 °C; 16 H,30 °C; 3 H,50 °C 标题:Importance Of Weak Interactions And Conformational Equilibrium In N-Butyl-N-Methylpiperidinium Bis(Trifluromethanesulfonyl) Imide Room Temperature Ionic Liquids: Vibrational And Theoretical Studies 作者:Shukla,Madhulata; Noothalapati,Hemanth; Shigeto,Shinsuke; Saha,Satyen 参考文献:Vibrational Spectroscopy 日期:2014 卷标:75 页码:107-117]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Acetonitrile; 48 H,65 °C 标题:Newly Designed Flow Reactor As An Original Method Of Synthesis Of Ionic Liquids By Ion-Exchange Reactions 作者:Pawlowska-Zygarowicz,Anna 参考文献:Tetrahedron Letters 日期:2021 卷标:86]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Acetonitrile; 3 H,50 °C 标题:Rational Selection Of The Cation Of An Ionic Liquid To Control The Reaction Outcome Of A Substitution Reaction 作者:Hawker,Rebecca R.; Haines,Ronald S.; Harper,Jason B. 参考文献:Chemical Communications (Cambridge 日期:2018 卷标:54(18) 页码:2296-2299]
4945-48-6 + 67-68-5 = 94280-72-5 反应条件:1.1 Reagents: 1,3-Dibromo-5,5-Dimethylhydantoin,Styrene,Sodium Bicarbonate Solvents: Dimethyl Sulfoxide; 10 H,40 °C 标题:Oxidative Thioesterification Of Alkenes Mediated By 1,3-Dibromo-5,5-Dimethylhydantoin And Dmso For The Synthesis Of α-Ketothioesters 作者:Hua,Jiawei; Xu,Jiaqi; Xu,Jia; Zhou,Bochao; Zhang,Dong; Et Al 参考文献:European Journal Of Organic Chemistry 日期:2019 卷标:2019(25) 页码:4056-4060]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Ethanol; 40 °C; 24 H,40 °C 标题:In Situ Co2 Capture And Transformation Into Cyclic Carbonates Using Flue Gas 作者:Ma,Haiying; Liu,Shujuan; Wang,Hongli; Li,Guomin; Zhao,Kang; Et Al 参考文献:Green Chemistry 日期:2023 卷标:25(6) 页码:2293-2298]
626-67-5 = 94280-72-5 反应条件:1.1 48 - 72 H,70 °C 标题:X-Ray Photoelectron Spectroscopy Of Piperidinium Ionic Liquids: A Comparison To The Charge Delocalised Pyridinium Analogues 作者:Men,Shuang; Licence,Peter; Do-Thanh,Chi-Linh; Luo,Huimin; Dai,Sheng 参考文献:Physical Chemistry Chemical Physics 日期:2020 卷标:22(21) 页码:11976-11983]
626-67-5 = 94280-72-5 反应条件:1.1 4 D,Rt 标题:Competing Reactions Of Co2 With Cations And Anions In Azolide Ionic Liquids 作者:Gohndrone,Thomas R.; Lee,Tae Bum; De Silva,M. Aruni; Quiroz-Guzman,Mauricio; Schneider,William F.; Et Al 参考文献:Chemsuschem 日期:2014 卷标:7(7) 页码:1970-1975]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Isopropanol; Rt; Rt -> 40 °C; 6 H,40 °C 标题:Lubricating Greases Containing Two Kinds Of Ionic Liquids As Base Oils 参考文献:Japan]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Ethyl Acetate; 3 H,70 °C 标题:Nanoscale Organization In Piperidinium-Based Room Temperature Ionic Liquids 作者:Triolo,Alessandro; Russina,Olga; Fazio,Barbara; Appetecchi,Giovanni Battista; Carewska,Maria; Et Al 参考文献:Journal Of Chemical Physics 日期:2009 卷标:130(16)]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Acetone; 48 H,Rt 标题:Effect Of 1-Alkyl-1-Methylpiperidinium Bromides On Lipids Of Fungal Plasma Membrane And Lung Surfactant 作者:Dopierala,Katarzyna; Syguda,Anna; Wojcieszak,Marta; Materna,Katarzyna 参考文献:Chemistry And Physics Of Lipids 日期:2022 卷标:248]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Acetone; Rt; 24 H,Reflux 标题:Cyclic Quaternary Ammonium Ionic Liquids With Perfluoroalkyltrifluoroborates: Synthesis,Characterization,And Properties 作者:Zhou,Zhi-Bin; Matsumoto,Hajime; Tatsumi,Kuniaki 参考文献:Chemistry - A European Journal 日期:2006 卷标:12(8) 页码:2196-2212]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Ethanol; 12 H,60 °C 标题:Synthesis And Performance Of Piperidinium-Based Ionic Liquids As Catalyst For Alkylation Of P-Xylene With 1-Hexadecene 作者:Ge,Sujuan; Zhou,Yuming; Sheng,Xiaoli; Mao,Chunfeng; Zhao,Lina; Et Al 参考文献:Applied Organometallic Chemistry 日期:2021 卷标:35(4)]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Ethyl Acetate; 12 H,363 - 368 K 标题:Ultrafast Dynamics In Nonaromatic Cation Based Ionic Liquids: A Femtosecond Raman-Induced Kerr Effect Spectroscopic Study 作者:Shirota,Hideaki; Ando,Masatoshi; Kakinuma,Shohei; Takahashi,Kotaro 参考文献:Bulletin Of The Chemical Society Of Japan 日期:2020 卷标:93(12) 页码:1520-1539]
626-67-5 = 94280-72-5 反应条件:1.1 25 °C; 16 H,50 °C 标题:Synthesis Of Task-Specific Imidazolium Ionic Liquid As An Efficient Catalyst In Acetylation Of Alcohols,Phenols,And Amines 作者:Chaubey,Snehkrishn A.; Mishra,Roli 参考文献:Chemical Papers 日期:2020 卷标:74(10) 页码:3259-3268]
626-67-5 + 120-94-5 = 94280-72-5 反应条件:1.1 Solvents: Toluene; 20 Min,Rt; 5 H,343 K 标题:Solubility And Diffusivity Of Oxygen In Ionic Liquids 作者:Song,Tangqiumei; Morales-Collazo,Oscar; Brennecke,Joan F. 参考文献:Journal Of Chemical & Engineering Data 日期:2019 卷标:64(11) 页码:4956-4967]
626-67-5 = 94280-72-5 反应条件:1.1 Solvents: Acetonitrile; Rt; Rt -> 70 °C; 48 H,70 °C 标题:Dissolution Of Oligo(Tetrafluoroethylene) And Preparation Of Poly(Tetrafluoroethylene)-Based Composites By Using Fluorinated Ionic Liquids 作者:Tsurumaki,Akiko; Ohno,Hiroyuki 参考文献:Chemical Communications (Cambridge 日期:2018 卷标:54(4) 页码:409-412]
专利号:WO-2024013423-A1 优先权日:2022-07-14 标题:Method for polyurethane depolymerization 发明人:LOZANO RODRÃ?GUEZ PEDRO; VILLA AROCA ROCÃ?O; SALAS VIDAL REBECA; GARCÃ?A-VERDUGO CEPEDA EDUARDO; MACIÃ? DELGADO MARÃ?A 权利人:UNIV MURCIA; UNIV JAUME I; ASOC EMPRESARIAL CENTRO TECNOLOGICO DEL MUEBLE Y LA MADERA DE LA REGION DE MURCIA 摘要:The present invention relates to a method for the depolymerization of a polyurethane mass, preferably thermoset polyurethane. The method comprises four main steps: i) mixing the polyurethane mass with a depolymerization reaction medium comprising an ionic liquid in a proportion equal to or greater than 50% w/w with respect to the total weight of said medium, a superbase as a catalyst, and a nucleophilic agent in a proportion equal to or less than 15% w/w with respect to the total weight of said medium, subjecting said mixture to a temperature between 50-100°C for between 2 minutes and 10 hours; ii) adding a mass of a protic molecular solvent in an amount between 4 and 40 times the weight of the depolymerization reaction medium; iii) subjecting the mixture from step ii) to a temperature between 20-60°C for at least 1 hour; and iv) separating the fractions obtained in step iii), namely, a semisolid fraction comprising at least a polyol mass for reuse in the synthesis of a new polyurethane, and a single-phase liquid fraction comprising at least the ionic liquid and the basic catalyst, for their reuse in a new process for polyurethane depolymerization.
专利号:CN-117660992-A 优先权日:2023-11-29 标题:Synthesis method of organosilicon compound containing Si-O bond
专利号:CN-117887453-A 优先权日:2024-01-22 标题:A kind of AB position co-doped manganese ion halide nanomaterial and its synthesis method
参考文献:10.1007/s11581-024-05889-4 摘要:Kyzlasova D, Ulihin A, Uvarov N. Phase behavior and electrochemical properties of lithium-doped N-methyl-N-propyl-piperidinium perchlorate. Ionics. 2024 Oct 18;30(12):8105–15. doi: 10.1007/s11581-024-05889-4.