CAS: 5525-95-1; (Perfluorophenyl)Diphenylphosphine

该化合物是氟有机磷化合物,其特点是其电子退出的五氟联苯组,这一结构特征增强了其作为过渡性金属催化作用,特别是在需要电脱磷脚手架的反应中.该化合物与非氟模拟相比,在氧化性和高温条件下的稳定性和再活性有所提高.其强烈的接受性特性使其在交叉组合,水成和其他金属中介变异中具有价值.氟代成分还有助于提高有机溶剂的溶解性,促进同质催化应用.这种磷衍生物在精细的化学合成和专门催化系统方面特别有利,因为在这种系统中,对离子环境进行电子调节至关重要.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号392-56-3 六氟苯 | CAS号603-35-0 三苯基膦 | CAS号1206-46-8 三甲基(五氟苯基)硅烷 | CAS号4791-48-4 diphenylphosphi... | CAS号344-04-7 溴五氟苯 | CAS号1079-66-9 氯代二苯基膦

合成工艺路线路线简述

    📜二氯五氟苯基膦置于c6H5Mgx体系中,化学反应生成 五氟苯基二苯基膦
    参考文献:Fild,M.; Glemser,O.; Hollenberg,I.,1965,Vol. 52,P. 590-591
    标题:Fild,M.; Glemser,O.; Hollenberg,I.,1965,Vol. 52,P. 590-591

    专利信息


    专利号:US-3721650-A
    优先权日:1971-03-22
    标题 :Reactive hydroxyalkyl-onium catalysts for synthesis of polyoxazolidones
    发明人:D ALELIO G
    权利人:ALELIO G D
    摘要:A PROCESS FOR PREPARING POLYOXAZOLIDONES IS PROVIDED IN WHICH A POLYEPOXIDE IS REACTED WITH A POLYISOCYANATE IN THE PRESENCE OF CHEMICALLY REACTIVE HYDROXYALKYL-ONIUM CATALYSTS, SELECTED FROM THE CLASS OF AMMONIUM AND PHOSPHONIUM HALIDES HAVING AT LEAST TWO HYDROXYALKYL GROUPS. NOVEL POLYMERS ARE OBTAINED WHEN THESE NEW CATALYSTS CONTAINING TWO OR MORE HYDROXY GROUPS ARE CONDENSED WITH POLYISOCYANATES.

    专利号:WO-2004074295-A1
    优先权日:2003-02-21
    标题:Thiazole cycle polymers, process for producing the same, synthesis intermediates thereof and utilization of the same
    发明人:TOSHIMA KAZUNOBU
    权利人:UNIV KEIO; TOSHIMA KAZUNOBU
    摘要:A novel thiazole cycle polymer represented by the following general formula (I) or its pharmacologically acceptable salt: (I) wherein R’s independently represent each hydrogen, optionally substituted lower alkyl, -CH2SH, formyl or carboxyl; and n is an integer of from 1 to 4. A process for producing the above compound, an intermediate in the synthesis thereof and a telomerase inhibitor and a medicinal composition containing the same. The above compound selectively acts on telomerase (i.e., having a high telomerase inhibitory effect with little inhibitory effects on Taq polymerase and other reverse transcriptases) and has no or little toxicity, which makes it highly useful as a selective telomerase inhibitor.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kaufmann, D. E.; Burmester, C., Science of Synthesis, (2005) 6, 670.
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