专利号:US-9714174-B2 优先权日:2012-07-19 标题:Methods of controlling polymorphism in organic-free synthesis of Na-zeolites and zeolite crystals formed therefrom 发明人:RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D 权利人:RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D; UNIV HOUSTON SYSTEM 摘要:Methods of controlling crystal polymorphism in organic-free synthesis of Na-Zeolites and the zeolite crystals formed using those methods are provided. The methods disclosed herein create certain types of zeolite crystals more efficiently than other previously known methods. The methods also create certain types of zeolite crystals in a form and concentration not previously disclosed. The methods disclosed herein generally comprise using solutions with varying ratios of silicon (Si), aluminum (Al), hydroxide (OH), and water. Some implementations of the invention disclosed include efficient methods of producing nearly pure cancrinite (CAN), methods of obtaining sodalite in solutions with a high Si/Al ratio, and a method of forming thin, platelet-like ANA crystals with a width of less than about 1 μm and a length of at least about 3 μm.
专利号:US-4338166-A 优先权日:1980-12-08 标 题 :Electrochemical synthesis of organophosphorus compounds 发明人:KUCK MARK A; MILLER GARY K 权利人:STAUFFER CHEMICAL CO 摘要:A process for the preparation of organophosphorus derivatives of organic hydroxyl or sulfhydryl compounds which includes the step of electrolyzing said organic hydroxyl or sulfhydryl compounds in an electrochemical cell having an anode comprising ferrophosphorus.
专利号:US-10982047-B2 优先权日:2016-09-28 标 题 :Solvent systems for synthesis of poly(amic acid) and polyimide polymers 发明人:KIM EUNGKYU; HARRIS WILLIAM J; JIANG QI; JIANG XIN; OHBA KAORU 权利人:DOW GLOBAL TECHNOLOGIES LLC 摘要:The process for synthesizing a poly(amic acid) polymer or a polyimide polymer is improved by using a solvent system consisting essentially of: (A) a first component consisting essentially of at least one of a sulfoxide, e.g., DMSO, and an alkyl phosphate, e.g., triethyl phosphate, and (B) optionally, a second component consisting essentially of at least one aprotic glycol ether, e.g., dipropylene glycol dimethyl ether.
专利号:US-8354530-B2 优先权日:2005-07-28 标 题:Process for the synthesis of rosuvastatin calcium 发明人:ZLICAR MARKO 权利人:LEK PHARMACEUTICALS; ZLICAR MARKO 摘要:Present invention represents process for the preparation of HMG-CoA reductase inhibitors, in particular rosuvastatin calcium introducing L-malic acid as the source of chirality for the side chain.
专利号:WO-8602628-A1 优先权日:1984-11-04 标题:Process for removal of hydrogen sulfide from gases 发明人:LYNN SCOTT 权利人:UNIV CALIFORNIA 摘要:Two stage removal of hydrogen sulfide from a gas. In the first stage solutions of hydrogen sulfide and sulfur dioxide in a solvent react to produce sulfur and water. An excess of hydrogen sulfide is maintained in the first stage resulting in a solution containing sulfur, water and the excess hydrogen sulfide, or resulting in a gas containing the excess hydrogen sulfide. The excess hydrogen sulfide in the solution or in the gas is then treated in a second stage with a solution in the same solvent of sulfur dioxide in excess of or closely equal to that required to react with the hydrogen sulfide. Excess sulfur dioxide in the vapor phase from the second stage may be absorbed in neat solvent. The solvent is selected to have a high solvating power for sulfur dioxide, a lesser but substantial solvating power for hydrogen sulfide and to promote the reaction of hydrogen sulfide with sulfur dioxide. Such gases as natural gas, synthesis gas, and the tail gas of a claus plant may be so treated. By appropriate selection of solvents and/or conditions, accompanying minor components of the gas stream being treated may be removed and recovered if of value, e.g., propane from natural gas, carbon dioxide and water from synthesis gas, etc. The process avoids the need to maintain exact stoichiometric ratios of hydrogen sulfide and sulfur dioxide, it avoids the need to use high flow rates of solvent, a liquid phase capacitance for hydrogen sulfide is provided which dampens the effect of fluctuations in hydrogen sulfide content in the gas stream, etc.
专利号:US-7829654-B2 优先权日:2004-05-11 标 题 :Method for producing elastomeric copolyesters 发明人:KAEMPF RUDOLF 权利人:LURGI ZIMMER GMBH 摘要:A process for continuous or discontinuous synthesis of elastomeric copolyesters from polybutylene terephthalate (PBT) and polyoxytetramethylene glycol is described in which the tetrahydrofuran (THF) obtained as a byproduct in synthesis of polybutylene terephthalate from 1,4-butanediol is rectified and then reacted by ring-opening polymerization to form polyoxytetramethylene glycol which condenses with the free or esterified carboxyl groups of PBT to form the copolyester, whereby chain termination and catalyst deactivation are accomplished by adding 1,4-butanediol without separating the catalyst.
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合成参考文献
摘要:S132 | UJIGCAPCICCS | A GC-APCI-IMS-HRMS CCS Library from Izquierdo-Sandoval et al. (2022) | DOI:10.5281/zenodo.15831151 参考文献:10.1007/s00216-011-5092-2 摘要:Harynuk JJ, Rossé AD, McGarvey GB. Study of alkyl phosphates in industrial petroleum mixtures by comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. Analytical and Bioanalytical Chemistry. 2011 May 22;401(8):2415–22. doi: 10.1007/s00216-011-5092-2. 参考文献:10.1007/s00216-004-2760-5 摘要:Isetun S, Nilsson U, Colmsjö A. Evaluation of solid-phase microextraction with PDMS for air sampling of gaseous organophosphate flame-retardants and plasticizers. Analytical and Bioanalytical Chemistry. 2004 Aug 07;380(2):319–24. doi: 10.1007/s00216-004-2760-5.