CAS: 21450-64-6; Magnesium,1,3-Dimethylbenzene-2-Ide,Bromide

上下游产品

2-Bromo-m-xylene rac-1-(2,6-dimethylphenyl)ethan-1-ol (2,6-dimethylphenyl)trimethylsilane bis(2,6-dimethylphenyl)glyoxal 2,6-dimethyliodobenzene

📜2,6-二甲基溴苯置于magnesium体系中,用 四氢呋喃 用作溶剂,化学反应 4.0H,反应生成2,6-二甲基苯基溴化镁
参考文献:双(芳基)膦配体的环金属铱配合物:催化ch-H / C-D交换和cc偶联反应
标题:双(芳基)膦配体的环金属铱配合物:催化ch-H / C-D交换和cc偶联反应
摘要:这项工作详细说明了合成和一系列的(η的复合物的结构鉴定5-C 5我5配位环金属化二(芳基)膦配位体)的ir(III)单元,Pr'(ar)的2,为r'=我和ar = 2,4,6-箱3 C ^ 6 ħ 2,1B ; 2,6-Me 2-4-Ome-C 6 H ^ 2,1C ; 2,6-Me 2-4-Fc 6 H ^ 2,1D ; R'=的et中,Ar = 2,6-Me 2 ç 6 ħ 3,1E.分别描述了含氯化物和氢化物的化合物2B-2E和3B-3E.氯化物2与nabar F(bar F = B(3,5-C 6 H 3(cf 3)2)4)在co存在下的反应形成阳离子羰基配合物4 +,且ν(co)值在窄间隔2030-2040 Cm-1,表明这些配合物的ir(III)中心具有相似的π碱度.在不存在的co,Nabar ˚f力κ 4-P,ç,ç ',ç "的金属化臂的协调(研究了所选
Doi:10.1021/ic400759R

专利信息

专利号:US-2014303333-A1
优先权日:2011-10-14
标题:Iron bisphenolate complexes and methods of use and synthesis thereof
发明人：SHAVER MICHAEL P; KOZAK CHRISTOPHER M
权利人:UNIV PRINCE EDWARD ISLAND; GENESIS GROUP INC
摘要:The present application, relates to iron bisphenolate complexes and methods of use and synthesis thereof. The iron complexes are prepared from tridentate or tetradentate ligands of Formula I: wherein R 1 and R 2 are as defined herein. Also provided are methods and processes of using the iron bisphenolate complexes as catalysts in cross-coupling reactions and in controlled radical polymerizations.

专利号:US-4124751-A
优先权日:1976-09-03
标题 :Process for preparing acrylic acid or methacrylic acid ester polymer having a high isotacticity and a narrow molecular weight distribution
发明人：FISCHER JOHANN P; CAVAGNA FRIEDRICH; DUCH EDUARD; MUCK KARL-FRIEDRICH
权利人:HOECHST AG
摘要:Esters of acrylic acid and methacrylic acid may be polymerized with the aid of either free radical forming or ionically effective initiators. The stereospecificy of the polymers may be influenced by the selection of specific initiators; magnesium-organic compounds are suitable for the synthesis of isotactic polymers. Acrylic acid and methacrylic acid esters having a high degree of isotacticity and a narrow molecular weight distribution are obtained with the aid of substituted phenylmagnesium halides. They are suitable as gauge and as test substances.

专利号:CA-2183714-C
优先权日:1995-09-14
标 题:Synthesis of 1,3-oxathiolane sulfoxide compounds

专利号:JP-6351511-B2
优先权日:2013-01-07
标 题:Synthesis of asymmetric Si rhodamine and rhodol

专利号:WO-2013053046-A1
优先权日:2011-10-14
标 题 :Iron bisphenolate complexes and methods of use and synthesis thereof

专利号:US-6291699-B1
优先权日:1999-08-24
标题 :2-alkyl-4-(2,6-dialkylphenyl) indenes
发明人：BIRMINGHAM JOHN M; RUSSO-RODRIGUEZ SANDRA
权利人:BOULDER SCIENT CO
摘要:2-alkyl-4-(2,6-dialkylphenyl) indenes, methods for the synthesis thereof, methods for converting such indenes to bridged metallocene ligands, methods for converting such ligands to bridged metallocenes and olefin polymerization processes in which such metallocenes are used as a catalyst or as a component of a catalyst system are described.