CAS: 18031-40-8; (S)-4-(Prop-1-En-2-yl)Cyclohex-1-Ene-1-Carbaldehyde

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30950-27-7 18457-55-1 23635-14-5

上下游产品

CAS号536-59-4 L-紫苏醇 | CAS号1361023-90-6 (S)-1-phenyl-N-... | CAS号18172-67-3 β-蒎烯 | CAS号7785-70-8 蒎烯 | CAS号127-91-3 beta-蒎烯 | CAS号852920-51-5 Spiro[bicyclo[3... | CAS号6931-54-0 6,6-二甲基螺[二环[3.1... | CAS号15111-96-3 4-(1-甲基乙烯基)-1-环... | CAS号875-08-1 (-)-β-Pinenoxide | CAS号22451-48-5 (4-prop-1-en-2-... | CAS号536-59-4 L-紫苏醇 | CAS号194937-75-2 (5As,7s)-7-异丙烯基... | CAS号26460-67-3 紫苏酸甲酯 | CAS号68480-28-4 3-甲基-2-丁烯甲酸盐 | CAS号76675-48-4 (S)-4-((R)-2-hy... | CAS号76675-46-2 (S)-4-((S)-2-hy... | CAS号138-91-0 1-Cyclohexene-1...

(S)-(-)-紫苏醇置于溶剂黄146,2-碘酰基苯甲酸体系中,用 乙腈 用作溶剂,化学反应 2.0H,以90%的收率获得(S)-(-)-紫苏醛
参考文献:一种在乙酸存在下用邻碘氧苯甲酸(ibx)氧化伯醇的简单方法
标题:一种在乙酸存在下用邻碘氧苯甲酸(ibx)氧化伯醇的简单方法
摘要:已开发出一种简单的方法,可使用邻碘氧苯甲酸(ibx)和化学计量的乙酸,将伯醇氧化为醛.加入乙酸显着加快了反应速度.在这些条件下,脂族,苄基和烯丙基伯醇可以高收率(90-97%)平稳地转化为醛.
Doi:10.1016/j.Tet.2010.10.053

专利信息

专利号:US-2022356139-A1
优先权日:2019-09-03
标 题:Synthesis of deuterated aldehydes
发明人：WANG WEI
权利人:ARIZONA BOARD OF REGENTS ON BEHALF OF ATHE UNIV OF ARIZONA
摘要:Described are methods for preparing a deuterated aldehyde using N-heterocyclic carbene catalysts in a solvent comprising D 2 O. The methods may be used to convert a wide variety of aldehydes (e.g., aryl, alkyl, or alkenyl aldehydes) to C-1 deuterated aldehydes under mild reaction conditions without functionality manipulation.

专利号:US-11117893-B2
优先权日:2018-09-24
标题 :Methods for preparation of substituted pyridines and related novel compounds
发明人：WATKINS EDMOND BLAKE; UREDI DILIPKUMAR; MOTATI DAMODER REDDY
权利人:WATKINS EDMOND BLAKE; UREDI DILIPKUMAR; MOTATI DAMODER REDDY; UNION UNIV
摘要:The present invention relates to novel methods of preparation of substituted pyridines and the compounds produced therefrom. In particular, the present invention provides efficient methods for the construction of diversely substituted pyridines, with varying substitution patterns under simple and metal-free conditions with high atom- and pot-economy and excellent functional group tolerance, and which are useful for the synthesis of natural products.

专利号:WO-8911536-A1
优先权日:1988-05-27
标题:Microbial biocatalyst for production of terpenic aldehydes
发明人：DAVIS KAREN JOHANNA; BEST DAVID JOHN; BURFIELD ANTHONY GRAHAM; TAYLOR FRANK; TALBOT JANE STELLA
权利人:NOVALAL LTD
摘要:An active biocatalyst for converting alpha-pinene epoxide to terpenic aldehydes useful in perfumery, e.g. formula (I), is produced by growing a microorganism, preferably Pseudomonas fluorescens NCIB 40043, to late log phase in a medium containing carbohydrate (e.g. glucose) as the carbon source, and adding alpha-pinene. The resulting culture comprises active biocatalyst which is brought into contact with alpha-pinene epoxide for aldehyde synthesis.

专利号:US-2023250042-A1
优先权日:2020-09-29
标 题 :Curcusone diterpenoids and uses thereof
发明人：DAI MINGJI; CUI CHENGSEN; CAI ZHONGJIAN; ADIBEKIAN ALEXANDER; DWYER BRENDAN
权利人:PURDUE RESEARCH FOUNDATION
摘要:The present disclosure provides the first asymmetric total synthesis and target identification of the curcusone natural products. The novel convergent synthesis is built upon a cheap and abundant chiral pool molecule (8) and features a thermal [3,3]-sigmatropic rearrangement and an FeCl3-promoted global hydrolysis/adol condensation cascade to rapidly construct the critical cycloheptadienone core. By performing chemoproteomics with the alkyne probe 37, we identified the previously “undruggableâ€? oncogenic protein BRAT1 as a key cellular target of 1d. Furthermore, 1d inhibits BRAT1 in cancer cells, thereby reducing cancer cell migration, increasing susceptibility to DNA damage, and inducing chemosensitization to the approved drug etoposide. Compound 1d is the first known small-molecule inhibitor for BRAT1, a master regulator of the DDR and DNA repair. Composition matters and methods of uses are within the scope of this disclosure.

专利号:CN-107266410-B
优先权日:2017-07-29
标 题 :Synthesis method of 8-epi-puupehedione

专利号:US-10647942-B2
优先权日:2016-12-22
标题:Fragrance and flavor materials
发明人：BLANDINO MAUREEN; LANKIN MICHAEL E
权利人:TAKASAGO PERFUMERY CO LTD
摘要:The present disclosure is directed to the synthesis and application of undecavertol derivatives having unique and desired flavor and/or fragrant characteristics. The compounds of the present disclosure can be employed alone or incorporated as fragrance or flavor ingredients in fragrance or flavor compositions. The present disclosure is also directed to consumer products comprising such derivatives and/or fragrance or flavor compositions.