📜五氟化硫置于氯体系中,用 Neat (No Solvent) 用作溶剂,化学反应生成硫氯五氟化物 参考文献:George,J. W.; Cotton,F. A.,Proceedings Of The Chemical Society,London 标题:George,J. W.; Cotton,F. A.,Proceedings Of The Chemical Society,London
专利信息
专利号:US-9896336-B2 优先权日:2008-06-11 标 题:Bromine-facilitated synthesis of fluoro-sulfur compounds 发明人:WINTER ROLF 权利人:AVANTBIO CORP 摘要:Described herein are methods for the bromine-facilitated synthesis of fluoro-sulfur compounds, that include SF 4 , SF 5 Cl, SF 5 Br and SF 6 . The methods described herein generally require lower temperature and pressure, produce higher yields, require less time, do not use corrosive or costly reactants and solvents that are commonly used in the synthesis of the fluoro-sulfur compounds, and do not produce deleterious waste products when compared to previously-used methods.
专利号:US-2009093641-A1 优先权日:2006-03-13 标题:Synthesis of Pentafluorosulfanyl (SF5)-Substituted Heterocycles and Alkynes 发明人:DOLBIER JR WILLIAM R; MITANI AKIRA 权利人:UNIV FLORIDA 摘要:The subject invention pertains to pentafluorosulfanyl (—SF 5 ) substituted compounds and methods of their synthesis. The subject invention provides convenient methods to incorporate the —SF 5 substituent into compounds such as heterocycles and alkynes.
专利号:US-6958415-B2 优先权日:2003-11-14 标 题 :Synthesis of pentafluorosulfuranyl arylenes 发明人:LAL GAURI SANKAR; MINNICH KRISTEN ELAINE 权利人:AIR PROD & CHEM 摘要:A new route has been found leading to the formation of pentafluorosulfuranyl arylenes. In its broadest aspect the process comprises:n effecting dehydrohalogenation or dehydrogenation of a pentafluorosulfuranyl cycloaliphatic compound represented by either of the structures: n n wherein R 1-5 are H, halogen, C 1-10 alkyl, C 1-10 alkoxy, C 1-10 thionyl, C 1-10 alkyl ether, aryl and substituted aryl, thioether, sulfonyl, carboalkoxy, alkylamino, arylamino, alkylphosphoryl, alkylphosphonyl, arylphosphonyl, arylphosphoryl, and mixtures thereof and X is a halogen atom to form the pentafluorosufuranyl arylene represented by the structures: n n wherein R 1 -R 5 are as represented above.
专利号:US-6870068-B1 优先权日:2003-11-14 标 题:Synthesis of pentafluorosulfuranyl substituted alkanes 发明人:LAL GAURI SANKAR; MINNICH KRISTEN ELAINE 权利人:AIR PROD & CHEM 摘要:Addition of an SF 5 group to organic compounds such as alkyl-substituted terminal alkenes, internal alkenes and cycloalkenes via the reaction with SF 5 Br is effected under liquid phase conditions and generally in the presence of a free radical initiator, preferably triethyl borane.
专利号:US-2019359485-A1 优先权日:2008-06-11 标 题:Bromine-Facilitated Synthesis of Fluoro-Sulfur Compounds
专利号:US-2018134555-A1 优先权日:2008-06-11 标 题:Bromine-Facilitated Synthesis of Fluoro-Sulfur Compounds
摘要:Kwiecień, H. U., Science of Synthesis: Knowledge Updates, (2024) 3, 78. 摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 37. 摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 15. 摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 29. 摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 23.