CAS: 13780-57-9; Pentafluorosulfanyl Chloride

该化合物是一个高度专业化的无机化合物,其特点是其八面分子几何学,其硫与五氟原子和一氯原子集中协调,该化合物在受控制条件下具有很强的氧化特性和稳定性,使其在选择性氟化反应和先进化学合成中有用.它与有机和无机子体的高度反应性可以精确地改变分子结构. SClF5由于其腐蚀性和毒性性质,通常在专门环境中处理,其独特的结合结构和再活性特征使它成为需要受控制的氟化的研究和工业应用中有价值的试剂.

结构式图片

上下游产品

chlorine trifluoride sulfur tetrafluoride chlorine monofluoride disulfur decafluoridesulfuryl dichloride fluorosulfonyl fluoride disulfur decafluoride pentafluorosulfur fluorosulfonate

合成工艺路线路线简述

    📜五氟化硫置于氯体系中,用 Neat (No Solvent) 用作溶剂,化学反应生成硫氯五氟化物
    参考文献:George,J. W.; Cotton,F. A.,Proceedings Of The Chemical Society,London
    标题:George,J. W.; Cotton,F. A.,Proceedings Of The Chemical Society,London

    专利信息


    专利号:US-9896336-B2
    优先权日:2008-06-11
    标 题:Bromine-facilitated synthesis of fluoro-sulfur compounds
    发明人:WINTER ROLF
    权利人:AVANTBIO CORP
    摘要:Described herein are methods for the bromine-facilitated synthesis of fluoro-sulfur compounds, that include SF 4 , SF 5 Cl, SF 5 Br and SF 6 . The methods described herein generally require lower temperature and pressure, produce higher yields, require less time, do not use corrosive or costly reactants and solvents that are commonly used in the synthesis of the fluoro-sulfur compounds, and do not produce deleterious waste products when compared to previously-used methods.

    专利号:US-2009093641-A1
    优先权日:2006-03-13
    标题:Synthesis of Pentafluorosulfanyl (SF5)-Substituted Heterocycles and Alkynes
    发明人:DOLBIER JR WILLIAM R; MITANI AKIRA
    权利人:UNIV FLORIDA
    摘要:The subject invention pertains to pentafluorosulfanyl (—SF 5 ) substituted compounds and methods of their synthesis. The subject invention provides convenient methods to incorporate the —SF 5 substituent into compounds such as heterocycles and alkynes.

    专利号:US-6958415-B2
    优先权日:2003-11-14
    标 题 :Synthesis of pentafluorosulfuranyl arylenes
    发明人:LAL GAURI SANKAR; MINNICH KRISTEN ELAINE
    权利人:AIR PROD & CHEM
    摘要:A new route has been found leading to the formation of pentafluorosulfuranyl arylenes. In its broadest aspect the process comprises:n effecting dehydrohalogenation or dehydrogenation of a pentafluorosulfuranyl cycloaliphatic compound represented by either of the structures: n n wherein R 1-5 are H, halogen, C 1-10 alkyl, C 1-10 alkoxy, C 1-10 thionyl, C 1-10 alkyl ether, aryl and substituted aryl, thioether, sulfonyl, carboalkoxy, alkylamino, arylamino, alkylphosphoryl, alkylphosphonyl, arylphosphonyl, arylphosphoryl, and mixtures thereof and X is a halogen atom to form the pentafluorosufuranyl arylene represented by the structures: n n wherein R 1 -R 5 are as represented above.

    专利号:US-6870068-B1
    优先权日:2003-11-14
    标 题:Synthesis of pentafluorosulfuranyl substituted alkanes
    发明人:LAL GAURI SANKAR; MINNICH KRISTEN ELAINE
    权利人:AIR PROD & CHEM
    摘要:Addition of an SF 5 group to organic compounds such as alkyl-substituted terminal alkenes, internal alkenes and cycloalkenes via the reaction with SF 5 Br is effected under liquid phase conditions and generally in the presence of a free radical initiator, preferably triethyl borane.

    专利号:US-2019359485-A1
    优先权日:2008-06-11
    标 题:Bromine-Facilitated Synthesis of Fluoro-Sulfur Compounds

    专利号:US-2018134555-A1
    优先权日:2008-06-11
    标 题:Bromine-Facilitated Synthesis of Fluoro-Sulfur Compounds

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kwiecień, H. U., Science of Synthesis: Knowledge Updates, (2024) 3, 78.
    摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 37.
    摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 15.
    摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 29.
    摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 23.
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