CAS: 10298-80-3; 4-Chloro-3-Nitroanisole

相似化合物

2401-24-3 85006-21-9 3970-39-6

上下游产品

CAS号96-96-8 冰染重氮组分 1 | CAS号555-03-3 3-硝基苯甲醚 | CAS号562-54-9 甲基硫酸钾 | CAS号124-41-4 甲醇钠 | CAS号10565-15-8 diethyl 2-(4-me... | CAS号55690-60-3 2-巯基-5-甲氧基苯并噻唑 | CAS号3189-13-7 6-甲氧基吲哚 | CAS号3416-18-0 5-羟基吲哚-2-酮 | CAS号149457-03-4 N-[5-羟基-4-(2-甲酰... | CAS号14371-84-7 4-methoxy-1-[(4... | CAS号14371-80-3 3-nitro-4-merca... | CAS号14371-81-4 4-methoxy-2-nit... | CAS号149456-98-4 甲酰胺基甲基-2-甲氧基-4-... | CAS号14482-32-7 2-amino-4-metho...

3-硝基苯甲醚置于oxone,氯化铵体系中,用 乙腈 用作溶剂,化学反应 48.0H,以31%的收率获得4-氯-3-硝基苯甲醚
参考文献:Narender; Mohan,K.V.V. Krishna; Srinivasu,Indian Journal Of Chemistry-Section B Organic And Medicinal Chemistry,2004,Vol. 43,# 6,P. 1335-1338
标题:Narender; Mohan,K.V.V. Krishna; Srinivasu,Indian Journal Of Chemistry-Section B Organic And Medicinal Chemistry,2004,Vol. 43,# 6,P. 1335-1338

专利信息

专利号:US-8188282-B2
优先权日:2006-07-15
标 题:Regioselective palladium catalyzed synthesis of benzimidazoles and azabenzimidazoles
发明人：ALONSO JORGE; LINDENSCHMIDT ANDREAS; NAZARE MARC; HALLAND NIS; RKYEK OMAR; URMANN MATTHIAS
权利人:ALONSO JORGE; LINDENSCHMIDT ANDREAS; NAZARE MARC; HALLAND NIS; RKYEK OMAR; URMANN MATTHIAS; SANOFI AVENTIS
摘要:The present invention relates to a process for the regioselective synthesis of compounds of the formula I, n nwherein R0; R1; R2; R3; R4; R5; A1; A2; A3; A4, Q and J have the meanings indicated in the claims. The present invention provides a direct palladium catalyzed, regioselective process to a wide variety of unsymmetrical, multifunctional N-substituted benzimidazoles or azabenzimidazoles of formula I starting from 2-halo-nitroarenes and N-substituted amides useful for the production of pharmaceuticals, diagnostic agents, liquid crystals, polymers, herbicides, fungicidals, nematicidals, parasiticides, insecticides, acaricides and arthropodicides.

专利号:AU-2007276514-A1
优先权日:2006-07-15
标题:A regioselective palladium catalyzed synthesis of benzimidazoles and azabenzimidazoles

专利号:CA-2657717-A1
优先权日:2006-07-15
标 题 :A regioselective palladium catalyzed synthesis of benzimidazoles and azabenzimidazoles

专利号:CN-101490014-B
优先权日:2006-07-15
标 题:Regioselective palladium-catalyzed synthesis of benzimidazoles and azabenzimidazoles

专利号:CN-109400507-A
优先权日:2018-10-09
标 题 :Synthesis of Impurities in Iilamod Intermediates

专利号:CN-101490014-A
优先权日:2006-07-15
标题:Regioselective palladium-catalyzed synthesis of benzimidazoles and azabenzimidazoles