CAS: 612-60-2; 7-Methylquinoline

上下游产品

CAS号58960-03-5 7-甲基-1,2,3,4-四氢喹啉 | CAS号99-08-1 3-硝基甲苯 | CAS号156-87-6 3-氨基丙醇 | CAS号56-81-5 甘油 | CAS号108-44-1 3-甲基苯胺 | CAS号14002-34-7 三(3-羟基丙基)胺 | CAS号1504-75-2 3-(对甲苯基)丙烯醛 | CAS号23545-77-9 N-[3-m-tolylami... | CAS号107-18-6 烯丙醇 | CAS号49573-30-0 7-喹啉甲醛 | CAS号5470-82-6 7-甲基-8-氨基喹啉 | CAS号14061-25-7 Quinolinium,1,7... | CAS号27356-39-4 7-甲基-2-苯基喹啉 | CAS号7471-63-8 7-甲基-8-硝基喹啉 | CAS号1078-30-4 7-喹啉甲酸 | CAS号75434-10-5 7-甲基喹啉-2-羧酸 | CAS号769100-08-5 7-(溴甲基)喹啉 | CAS号854864-06-5 Cinchoninonitri... | CAS号4295-12-9 2-氯-7-甲基喹啉

7-甲基-1,2,3,4-四氢喹啉置于十二羰基三钌,2-碘-1,3,5-三甲基苯,N,N'-1,2-Tetrakis(4-Fluorophenyl)Ethane-1,2-Diimine,Caesium Carbonate体系中,用 氯苯 作为反应溶剂,化学反应 16.0H,以70%的收率获得产物7-甲基喹啉
参考文献:通过分子间氢原子转移机制的钌催化脱氢
标题:通过分子间氢原子转移机制的钌催化脱氢
摘要:烷烃直接脱氢是获得有价值的烯烃产品的最有效方法之一.尽管已经设计了几种催化剂来促进这种转变,但不幸的是它们在精细化学合成中的应用有限.在这里,我们报告了一种使用钌催化剂催化烷烃分子间脱氢的概念新颖的策略.氧化还原活性配体和空间位阻芳基自由基中间体的组合释放了这种新策略.重要的是,已经进行了机理研究,为进一步开发这种新型催化脱氢系统提供了概念框架.
DOI:10.1002/anie.202015837

专利信息

专利号:WO-2024137329-A1
优先权日:2022-12-20
标 题:Methods for the synthesis of complement factor d inhibitors and intermediates thereof
发明人：HASHIMOTO AKIHIRO; TIPPARAJU SURESH KUMAR
权利人:ALEXION PHARMA INC
摘要:The present disclosure provides methods for the synthesis of complement factor D inhibitors and intermediates thereof.

专利号:US-9982005-B2
优先权日:2013-04-04
标 题 :Macrolides and methods of their preparation and use
发明人：MYERS ANDREW G; SEIPLE IAN BASS; ZHANG ZIYANG
权利人:HARVARD COLLEGE
摘要:Provided herein are methods of preparing macrolides by the coupling of an eastern and western half, followed by macrocyclization, to provide macrolides, including both known and novel macrolides. Intermediates in the synthesis of macrolides including the eastern and western halves are also provided. Pharmaceutical compositions and methods of treating infectious diseases and inflammatory conditions using the inventive macrolides are also provided. A general diastereoselective aldol methodology used in the synthesis of the western half is further provided.

专利号:US-7470792-B2
优先权日:2002-09-13
标题:Process for the preparation of epothilone derivatives, new epothilone derivatives as well as new intermediate products for the process and the methods of preparing same
发明人：KOCH GUIDO; LOISELEUR OLIVIER
权利人:NOVARTIS AG
摘要:The present invention provides a synthesis for the preparation of epothilone derivatives of formula 9 n nwherein R1 is methyl, and R2 is an unsubstituted or substituted aryl; an unsubstituted or substituted heteroaryl; or an unsubstituted or substituted heterocyclic radical fused to a benzene nucleus; and salts thereof, and intermediates for the synthesis of a compound of formula 9.

专利号:US-3943142-A
优先权日:1969-01-24
标 题:Dye intermediates and their preparation and use in the synthesis of methine dyes
发明人：OWEN JOHN R
权利人:EASTMAN KODAK CO
摘要:Compositions of matter are provided comprising a stable, non-vaporous monomeric methylene base selected from a 2-methylenethiazoline; a 2-methylenebenzothiazoline; a 2-methylenenaphthothiazoline; a 2-methylenebenzoselenazoline; and a 2-methylenenaphthoselenazoline. The compositions of the invention are prepared by reacting the parent 2-methyl quaternary salt with a non-hydroxylic base which removes a proton of the heterocyclic salt together with a proton acceptor which inhibits build-up of the hydro salt of the non-hydroxylic base, the reaction being conducted under anhydrous conditions in a non-hydroxylic liquid in which the heterocyclic quaternary salt is sufficiently insoluble to inhibit dimer formation. The compositions of the invention are employed in the preparation of methine dyes.

专利号:US-7935827-B2
优先权日:2003-12-31
标题 :Optically active, heteroaromatic β-hydroxy esters and processes for their preparation from β-keto esters and processes for the preparation of these β-keto esters
发明人：PLATZEK JOHANNES; ZORN LUDWIG; BUCHMANN BERND; SKUBALLA WERNER; PETROV ORLIN
权利人:BAYER SCHERING PHARMA AG
摘要:The present invention relates to new optically active heteroaromatic β-hydroxy esters useful in the synthesis of epothilone derivatives, to certain compounds used to produce these intermediates, as well as to processes for their production.

专利号:WO-2023114200-A2
优先权日:2021-12-14
标题 :Methods for the synthesis of complement factor d inhibitors and intermediates thereof