CAS: 558-17-8; 2-Iodo-2-Methylpropane

该化合物是一种有机化合物,其分子式为C5H11I. 它的特性是三碳原子,与碘原子和三组甲基相连接,形成独特的反应力和特性.该化合物一般没有色素,可粉黄,具有独特的气味;它相对非极性,在有机溶剂中溶解,但在水中无法溶解. 2-Iodo-2-甲基丙烷,因其在有机合成中作为试剂的作用而著称,特别是由于碘原子的存在,它是一个良好的离子组,在核生殖反应中尤其如此.它的沸点与类似的烷基卤化物相比相对较高,反映了大基丁基组的影响力.此外,必须谨慎处理这一化合物,因为它可能很危险,并被归类为潜在的环境污染物.在实验室与该物质打交道时,应采取适当的安全措施.

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ECHA物质ECHA物质C&L通报REACH预注册

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CAS号75-65-0 叔丁醇 | CAS号507-20-0 氯代叔丁烷 | CAS号917-95-3 Propane,2-methy... | CAS号594-70-7 2-甲基-2-硝基丙烷 | CAS号1605-73-8 2-methylpropane | CAS号659-86-9 1-Propyne, 3-io... | CAS号1450-14-2 六甲基二硅烷 | CAS号40269-44-1 tert-butyl 2,3,... | CAS号79-29-8 2,3-二甲基丁烷 | CAS号507-19-7 溴代叔丁烷 | CAS号3282-56-2 1-叔丁基-4-硝基苯 | CAS号937-33-7 N-叔丁基苯胺 | CAS号769-92-6 4-叔丁基苯胺 | CAS号1127-42-0 N-phenyl-N-tert... | CAS号1105707-49-0 N-tert-butoxybe... | CAS号1227476-15-4 1,2-diphenyldiazene | CAS号495-48-7 氧化偶氮苯 | CAS号66596-82-5 (Z)-2-(4-(tert-... | CAS号598-98-1 特戊酸甲酯

合成工艺路线路线简述

    📜乙基,1,1-二甲基-(9CI)置于2-碘丁烷,三苯胂体系中,用 异辛烷 作为反应溶剂,化学反应生成 碘代叔丁烷
    参考文献:Heats Of Formation Of Some Simple Alkyl Radicals
    标题:Heats Of Formation Of Some Simple Alkyl Radicals
    摘要:
    DOI:10.1021/ja00377A018

    专利信息


    专利号:US-2021107859-A1
    优先权日:2018-04-06
    标题 :A process for the synthesis of carbon labeled organic compounds
    发明人:AUDISIO DAVIDE; CANTAT THIBAULT; DESTRO GIANLUCA
    权利人:COMMISSARIAT ENERGIE ATOMIQUE
    摘要:A process for the synthesis of a carbon labeled organic compound containing a carbon labeled carboxyl group is described. A method of using carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; a process for manufacturing labeled pharmaceuticals and agrochemicals comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; and a process for producing tracers comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure are also described.

    专利号:US-2006128930-A1
    优先权日:2004-12-03
    标题 :Synthesis of sterically hindered phenol based macromolecular antioxidants
    发明人:DHAWAN ASHISH; CHOLLI ASHOK L
    权利人:DHAWAN ASHISH; CHOLLI ASHOK L
    摘要:Disclosed is a method for the synthesis of sterically hindered polymeric antioxidants based on phenol type antioxidant monomers. The method includes polymerizing and alkylating a phenol containing monomer represented by the following structural formula: n n nto produce a sterically hindered polymeric macromolecular antioxidant. X, R 10 and q are as defined herein. The disclosed method is a simple, direct and economical process for the synthesis of sterically hindered polymeric macromolecular antioxidants.

    专利号:US-7678877-B2
    优先权日:2004-12-03
    标题 :Process for the synthesis of polyalkylphenol antioxidants
    发明人:YANG SUIZHOU; CHOLLI ASHOK L
    权利人:POLNOX CORP
    摘要:Disclosed is a method for the synthesis of sterically hindered polymeric antioxidants based on phenol type antioxidant monomers. The method includes partially etherifying, polymerizing and thermally rearranging a phenol containing monomer represented by the following structural formula: n nto produce a sterically hindered polymeric macromolecular antioxidant. X, R 10 and q are as defined herein. The disclosed method is a simple, direct and economical process for the synthesis of sterically hindered polymeric macromolecular antioxidants.

    专利号:US-9512250-B2
    优先权日:2012-02-23
    标 题 :Manganese catalyzed photopolymerization of fluorinated monomers
    发明人:ASANDEI ALEXANDRU D
    权利人:UNIV CONNECTICUT
    摘要:The disclosure discloses initiating systems for the radical polymerization of alkenes, and especially fluorine substituted alkenes. The polymerization is catalyzed by a metal carbonyl, preferably manganese carbonyl. The polymerization is initiated directly from alkyl halides at room temperature under visible white light. The polymers also allow the synthesis of block copolymers. The process comprises polymerizing at least one alkene monomer in the presence of a halide radical initiator, carbonyl catalyst and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one alkene monomer to form a polymer. The present disclosure provides a method for living polymerization of alkene monomers which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products. This disclosure also provides a method for activating any halide (Cl, Br, I) chain ends of such polymers for the synthesis of block copolymerizations.

    专利号:US-9346851-B2
    优先权日:2008-02-22
    标 题 :Chemical modification of proteins
    发明人:BERNARDES GONCALO; CHALKER JUSTIN; DAVIS BENJAMIN
    权利人:BERNARDES GONCALO; CHALKER JUSTIN; DAVIS BENJAMIN; RP SCHERER TECHNOLOGIES LLC
    摘要:The invention relates to methods for selectively converting a cysteine residue in a peptide or protein to the dehydroalanine (Dha) residue. The method also works on selenocysteine and substituted cysteine and selenocysteine residues, resulting in the Dha residue which may be converted to any natural or unnatural amino acid residue desired without the alteration of the remainder of the peptide or protein. The invention also allows ligation of a desired peptide at any point rather than at a point where there should be a naturally occurring cysteine, thereby allowing native chemical ligation to be used in the synthesis of peptides that do not contain cysteine. The methodology allows for the synthesis of very large peptides.

    专利号:US-4033949-A
    优先权日:1976-04-14
    标 题:Analogs of thromboxane B2 and processes for their synthesis
    发明人:KELLY ROBERT C; NELSON NORMAN A
    权利人:UPJOHN CO
    摘要:The present specification provides novel intermediates and novel processes for the synthesis of various side chain and skeletal analogs of Thromboxane B 2 (11β-homo-11a-oxa-PGF 2 .sub.α). These analogs are particularly and especially useful as reproductive cycle control agents.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 87.
    摘要:Weibel, J.-M.; Blanc, A.; Pale, P., Science of Synthesis Knowledge Updates, (2018) 1, 31.
    摘要:Hagen, T. J.; Helgren, T. R., Science of Synthesis Knowledge Updates, (2015) 2, 149.
    摘要:Singh, F. V.; Wirth, T., Science of Synthesis Knowledge Updates, (2015) 2, 415.
    摘要:Hennecke, U., Science of Synthesis Knowledge Updates, (2015) 2, 440.
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