CAS: 5089-33-8; N-(4-Bromophenyl)-1,1,1-Trimethyl-N-(Trimethylsilyl)Silanamine

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chloro-trimethyl-silane 4-bromo-aniline N-(trimethylsilyl)-4-bromoaniline trimethylsilyl trifluoromethanesulfonate 4-aminophenyl diphenyl methanol 4,4'-Diaminotriphenylmethanol N-(4-aminophenethyl)benzamide -p-aminobenzoic acid-p-aminobenzoic acid

📜4-溴苯胺置于三乙胺,碘甲烷体系中,用 正己烷 作为反应溶剂,化学反应 10.0H,反应生成 4-溴-N,N-双(三甲基甲硅烷基)苯胺
参考文献:通过用三甲基甲硅烷基胺和碘甲烷处理制备双(三甲基甲硅烷基)胺的新方法
标题:通过用三甲基甲硅烷基胺和碘甲烷处理制备双(三甲基甲硅烷基)胺的新方法
摘要:已经报道了一种方便的合成n,N-双(三甲基甲硅烷基)烷基胺的方法.掺入化学计量的甲基碘的n-(三甲基甲硅烷基)二乙胺可有效地以高收率将伯胺,尤其是芳族胺及其单三甲基甲硅烷基衍生物转化为相应的n,N-双(三甲基甲硅烷基)胺衍生物.在脂族伯胺的n-三甲基甲硅烷基衍生物的情况下,在0.5当量的甲基碘存在下,一半的甲硅烷基胺用作甲硅烷化剂,而另一半的甲硅烷基胺用作甲硅烷基化剂,得到n,N-双(三甲基甲硅烷基)烷基胺,收率高.烯丙基碘,烯丙基溴和苄基溴也有效地促进了甲硅烷基胺的甲硅烷基化活性.
DOI:10.1016/0022-328X(95)05821-6

专利信息

专利号:US-6235871-B1
优先权日:1997-12-03
标题:Synthesis of oligoarylamines, and uses and reagents related thereto
发明人：SINGER ROBERT A; SADIGHI JOSEPH P; BUCHWALD STEPHEN L; MACKEWITZ THOMAS
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:The transition metal-catalyzed amination of aryl halides, in conjunction with an orthogonal protective group scheme, forms the basis of two routes to oligoaniline precursors. The oligoaniline precursors are soluble in a variety of common organic solvents, and are easily converted to the deprotected oligoanilines. The method allows the preparation of oligoanilines of even or odd chain lengths, and the incorporation of a variety of functional groups into the oligomers. Polyanilines of low polydispersity can also be prepared by this method.

专利号:US-9464171-B2
优先权日:2010-08-18
标 题 :Peripherally aromatic silsesquioxanes featuring reactive functionality: synthesis and application thereof
发明人：HADDAD TIMOTHY S; MABRY JOSEPH M; YANDEK GREGORY R
权利人:US AIR FORCE
摘要:Methods of synthesis and application thereof for peripherally aromatic silsesquioxanes featuring reactive functionality. A method, according to one embodiment of the invention, includes reacting a polyhedral oligomeric silsesquioxane with an anhydride. The polyhedral oligomeric silsesquioxane has an inorganic core, a phenyl moiety or an anlyine moiety covalently coupled to the at least one T-type silicon atom; and a metal-aniline group or a para-aniline group covalently coupled to the at least one D-type or M-type silicon atom. The inorganic core includes 6-14 silicon atoms, at least one of the silicon atoms being an M-type silicon atom or a D-type silicon atom, and at least one of the silicon atoms being a T-type silicon atom, and 9-20 oxygen atoms.

专利号:WO-9928290-A1
优先权日:1997-12-03
标 题:Synthesis of oligoarylamines, and uses and reagents related thereto