CAS: 4142-85-2; Bis(Trichlorosilyl)Methane

上下游产品

Methyltrichlorosilane dichloromethane chloroform (chloromethyl)trichlorosilanebis(trimethylsilyl)methane 1,1,1,3,3,3-hexaethoxy-1,3-disilapropane bis(chlorodimethylsilyl)methane methyl(dichlorosilyl)(trichlorosilyl)methane

📜氯仿置于三正丁胺,三氯硅烷体系中,用 乙腈 作为反应溶剂,化学反应生成 二(三氯甲硅烷基)甲烷
参考文献:双(三乙氧基甲硅烷基)甲烷,三(三乙氧基甲硅烷基)甲烷及其衍生物的合成和反应性1
标题:双(三乙氧基甲硅烷基)甲烷,三(三乙氧基甲硅烷基)甲烷及其衍生物的合成和反应性1
摘要:新的聚(三官能甲硅烷基)烷烃是有机-无机杂化材料的有效偶联剂,其合成已得到全面研究.在使用benkeser反应氯仿,三氯硅烷的优化和三-ñ丁胺(各自的比例1:4.5:3)纯化,得到双(三氯甲硅烷基)甲烷分离为双(三乙氧基)乙醇解后(总产率60%)的甲烷.用九当量的三氯硅烷,优先形成三(三氯甲硅烷基)甲烷,将其分离为三(三乙氧基甲硅烷基)甲烷(收率30%).在α-碳金属化并用相应的烷基卤化物进行捕集实验后,获得了c取代的双(三乙氧基甲硅烷基)甲烷.如果是三(三乙氧基甲硅烷基)氨基甲酸酯,则只有mei和br 2能够提供预期的产品.出乎意料的是,Co 2插入,得到稳定烯酮,[(eto)3的si] 2 Cco.
DOI:10.1016/s0022-328X(98)00365-9

专利信息

专利号:US-5233069-A
优先权日:1991-12-24
标题:Bis(silyl)methanes and their direct synthesis
发明人：JUNG IL N; YEON SEUNG H; HAN JOON S
权利人:KOREA INST SCI & TECH
摘要:The present invention relates to bis(silyl)methanes and their preparation methods in high hields by directly reacting α-chloromethylsilanes represented by formula I incorporated with hydrogen chloride or alkylchlorides represented by the general formula II, with silicon metal to give the bis(silyl)methane compound having dichlorosily group (formula III) as the major products and the bis(silyl)methane compounds having trichlorosilyl group (formula IV) in moderately high yields in the presence of copper catalyst at a temperature from 250° C. to 350° C. The different major product is obtained depending upon the chloride incorporated. n-Butyl chloride, t-butyl chloride, propyl chloride, and hydrogen chloride gave bissilylmethane with hydrogen substituted on the silicon atom as the major product. When 1,2-dichloroethane is incorporated, bis(silyl)methanes having trichlorosilyl group is the major product. ##STR1## In formulae (I), (III), (IV), R 1 , R 2 , and R 3 are independently methyl group or chlorine atome; and R is hydrogen, alkyl(C 1 -C 4 ), CH 2 CH 2 Cl.