CAS: 16718-12-0; 2-(Phenylthio)Thiophene

该化合物是一种有机化合物,其特点是其硫苯环,这是一个五人组成的含有硫磺的芳香热循环环.该化合物具有联苯硫环第二位置所附联苯基组,有助于其独特的化学特性.它通常是在室内温度下黄到褐的固体,以其在有机电子系统中的潜在应用为名,特别是在有机半导体和光伏设备中.硫磺和苯基组的存在加强了其电子特性,使其成为材料科学的一个主题.此外,2-(phenthio)thiophene可能表现出有趣的再活动,因为硫苯环具有丰富的电子特性,允许各种替代反应.有机溶剂的溶解性促进了其在各种化学合成和应用中的使用.与许多硫苯衍生物一样,它也可能显示出有趣的光学特性,可以在染料和感应感应应用中加以利用.应当查阅安全数据,以便处理和储存所有化学物质.

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5324-81-2 139120-68-6 649665-46-3

欧盟法规

ECHA物质C&L通报

上下游产品

2-bromothiophene tetra-N-butylammonium benzenethiolate methyl iodide 2-Iodothiophene 2-(benzenesulfonyl)thiophene 2-(phenylsulfinyl)thiophene 3-allyl-2-(phenylthio)thiophene

合成工艺路线路线简述

    📜甲基苯基亚砜置于1,8-二氮杂双环[5.4.0]十一碳-7-烯体系中,用 二氯甲烷 用作溶剂,化学反应 5.25H,反应生成2-硫苯基噻吩
    参考文献:使用亚砜的芳烃的无金属ch硫芳基化反应:直接的,一般的二芳基硫醚合成
    标题:使用亚砜的芳烃的无金属ch硫芳基化反应:直接的,一般的二芳基硫醚合成
    摘要:使用甲基亚砜的芳烃和杂芳烃的无金属ch硫芳基化反应,构成了合成高价值二芳基硫醚的一般无金属方案.芳烃和杂芳烃与...的偶联
    Doi:10.1039/c6Cc07627K

    海关参考信息

    专利信息


    专利号:EP-0951464-B1
    优先权日:1996-11-22
    标题:N-(aryl/heteroarylacetyl) amino acid esters, pharmaceutical compositions comprising same, and methods for inhibiting beta-amyloid peptide release and/or its synthesis by use of such compounds
    发明人:WU JING; THORSETT EUGENE D; NISSEN JEFFREY S; MABRY THOMAS E; LATIMER LEE H; JOHN VARGHESE; FANG LAWRENCE Y; AUDIA JAMES E
    权利人:ELAN PHARM INC; LILLY CO ELI
    摘要:Disclosed are compounds which inhibit beta -amyloid peptide release and/or its synthesis, and, accordingly, have utility in treating Alzheimer's disease. Also disclosed are pharmaceutical compositions comprising a compound which inhibits beta -amyloid peptide release and/or its synthesis as well as methods for treating Alzheimer's disease both prophylactically and therapeutically with such pharmaceutical compositions.

    专利号:US-6333351-B1
    优先权日:1996-11-22
    标题:N-(aryl/heteroarylacetyl) amino acid esters, pharmaceutical compositions comprising same, and methods for inhibiting β-amyloid peptide release and/or its synthesis by use of such compounds
    发明人:WU JING; THORSETT EUGENE D; NISSEN JEFFREY S; MABRY THOMAS E; LATIMER LEE H; JOHN VARGHESE; FANG LAWRENCE Y; AUDIA JAMES E
    权利人:ATHENA NEUROSCIENCES INC; LILLY CO ELI
    摘要:Disclosed are compounds which inhibit beta-amyloid peptide release and/or its synthesis, and, accordingly, have utility in treating Alzheimer's disease. Also disclosed pharmaceutical compositions comprising a compound which inhibits beta-amyloid peptide release and/or its synthesis as well as methods for treating Alzheimer's disease both prophylactically and therapeutically with such pharmaceutical compositions.

    专利号:US-6767918-B2
    优先权日:1996-11-22
    标 题 :N-(aryl/heteroarylacetyl) amino acid esters, pharmaceutical compositions comprising same, and methods for inhibiting β-amyloid peptide release and/or its synthesis by use of such compounds
    发明人:WU JING; THORSETT EUGENE D; NISSEN JEFFREY S; MABRY THOMAS E; LATIMER LEE H; JOHN VARGHESE; FANG LAWRENCE Y; AUDIA JAMES E
    权利人:ATHENA NEUROSCIENCES INC; LILLY CO ELI
    摘要:Disclosed are compounds which inhibit beta-amyloid peptide release and/or its synthesis, and, accordingly, have utility in treating Alzheimer's disease. Also disclosed pharmaceutical compositions comprising a compound which inhibits beta-amyloid peptide release and/or its synthesis as well as methods for treating Alzheimer's disease both prophylactically and therapeutically with such pharmaceutical compositions.

    专利号:US-6486350-B1
    优先权日:1998-09-30
    标 题:Biological reagents and methods for determining the mechanism in the generation of β-amyloid peptide
    发明人:AUDIA JAMES E; HYSLOP PAUL A; NISSEN JEFFREY S; THOMPSON RICHARD C; TUNG JAY S; TANNER LAURA I
    权利人:ELAN PHARM INC; LILLY CO ELI
    摘要:Disclosed are biological reagents which comprise compounds that inhibit beta-amyloid peptide release and/or its synthesis, and, accordingly, have utility in determining the cellular mechanism involved in the generation of beta-amyloid peptide.

    专利号:US-9917260-B2
    优先权日:2013-08-23
    标题 :Compounds with terminal heteroarylcyanovinylene groups and their use in organic solar cells
    发明人:SUNDARRAJ SUDHAKAR; EICKHOFF CHRISTIAN; BAHULAYAN SHEEJA; SEND ROBERT; NISHIMAE YUICHI; REICHELT HELMUT; TANABE JUNICHI; ERK PETER
    权利人:BASF SE
    摘要:The present invention relates to a photoactive material comprising a donor substance and an acceptor substance, wherein the donor substance comprises or consists of one or more compounds of formula (I) described herein, or the acceptor substance comprises or consists of one or more compounds of formula (I) described herein, or the donor substance comprises or consists of a first compound of formula (I) described herein and the acceptor substance comprises a second compound of formula (I) described herein with the proviso that the first and second compound are not the same, as well as to an organic solar cell comprising said photoactive material. The present invention also relates to a photoelectric conversion device comprising or consisting of two or more organic solar cells comprising said photoactive material and to compounds of formula (I) as described herein for use as donor substance or as acceptor substance in a photoactive material, Further, the present invention relates to the use of a compound of formula (III) as described herein in the synthesis of a compound of formula (I)as described herein.

    专利号:US-2003191119-A1
    优先权日:1996-11-22
    标 题 :N-(aryl/heteroarylacetyl) amino acid esters, pharmaceutical compositions comprising same, and methods for inhibiting beta-amyloid peptide release and/or its synthesis by use of such compounds

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Efficient Copper(I)-Catalyzed C-S Cross-Coupling Of Thiols With Aryl Halides In An Aqueous Two-Phase System
    作者:Xin-Yan Zhang,Xiao-Yan Zhang,Sheng-Rong Guo |发布日期:2011.2.1
    摘要:A Mild And Convenient C-S Bond Formation Reaction Catalyzed By Cui/l-Proline In An Aqueous Two-Phase System Was Achieved, Providing A Simple Method For The Synthesis Of Aryl Sulfides In Good Yields.

    合成参考文献


    摘要:Ronson, T. O.; Fairlamb, I. J. S., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 1, 187.
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