专利号:US-6596884-B2 优先权日:1998-06-29 标 题:Synthesis of hydrogen peroxide 发明人:BECKMAN ERIC J; HANCU DAN 权利人:UNIV PITTSBURGH 摘要:A method for synthesizing hydrogen peroxide comprises the steps of: synthesizing an analog of anthraquinone that is miscible or soluble in carbon dioxide; reacting the analog of anthraquinone with hydrogen in carbon dioxide to produce a corresponding analog of tetrahydroquinone; and reacting the analog of tetrahydroquinone with oxygen to produce the hydrogen peroxide and regenerate the analog of anthraquinone. A chemical compound having the formula: n wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 are independently, the same or different, H, R C , or R S R C , wherein R S is a spacer group and R C is a fluoroalkyl group, a fluoroether group, a silicone group, an alkylene oxide group, a fluorinated acrylate group, or a phosphazine group, and wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 is not H.
专利号:US-6656446-B1 优先权日:1999-04-29 标题:Synthesis of hydrogen peroxide 发明人:BECKMAN ERIC J; HANCU DAN 权利人:UNIV PITTSBURGH 摘要:A method for synthesizing hydrogen peroxide comprises the step of: mixing an analog of a secondary alcohol that is soluble with carbon dioxide with a free radical initiator and oxygen in carbon dioxide to generate hydrogen peroxide. Another method of synthesizing hydrogen peroxide comprises the step of: mixing hydrogen, oxygen and a CO 2 -philic catalyst in carbon dioxide phase. The CO 2 -philic catalyst is soluble or miscible in carbon dioxide and is suitable to catalyze the reaction of hydrogen and oxygen to produce hydrogen peroxide. The method also comprises the step of reacting the hydrogen and oxygen to produce hydrogen peroxide.
专利号:US-2009227701-A1 优先权日:2004-08-19 标题:Water-soluble, radiation-curable products and use thereof 发明人:KRUEGER CHRISTIAN; BRUCHMANN BERND; HEES ULRIKE; KLUGE MICHAEL; DIELEMAN CEDRIC; WEISER JUERGEN 权利人:BASF AG 摘要:Water soluble radiation curable products (A) obtainable by mixingn mixing with or without reaction of at least one hyperbranched polyurethane (a) with at least one photoinitiator (b) or by synthesis of at least one hyperbranched polyurethane (a) in the presence of at least one photoinitiator (b),n nare used to produce aqueous inks for the ink jet process.
专利号:US-3998936-A 优先权日:1975-04-23 标题:Process for regenerating hydrogenation catalyst activity in hydrogen peroxide synthesis 发明人:ERNST RICHARD EDWARD; AMINI BIJAN; BAREFORD WILLIAM JOHN 权利人:DU PONT 摘要:Catalytic activity of a platinum group metal catalyst used in catalyzing the hydrogenation of a working solution of an alkylanthraquinone in a water-immiscible solvent in the manufacture of hydrogen peroxide, said catalyst having become at least partially inactivated, is regenerated by a process comprising contacting the catalyst in the presence of the working solution and in the absence of hydrogen with an oxidizing agent selected from the group consisting of an oxygen-containing gas and hydrogen peroxide. n When the process of the invention is made an integral part of the cyclic anthraquinone process for producing hydrogen peroxide, there results an improvement in the latter process whereby the activity of the catalyst can be maintained at a high level.
专利号:US-6342196-B2 优先权日:1998-06-29 标题 :Synthesis of hydrogen peroxide
专利号:CA-2506422-A1 优先权日:2002-11-22 标题 :Enzymatic synthesis of polyol acrylates
参考文献:10.1007/s11356-022-21354-z 摘要:Ingle AA, Ansari SZ, Shende DZ, Wasewar KL, Pandit AB. Progress and prospective of heterogeneous catalysts for H2O2 production via anthraquinone process. Environmental Science and Pollution Research. 2022 Jun 16;29(57):86468–84. doi: 10.1007/s11356-022-21354-z.