CAS: 1118-58-7; 1,3-Dimethyl-1,3-Butadiene

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2-甲基-2-戊烯 2-Methyl-2-Pentene 625-27-4

合成工艺路线路线简述

    📜2-甲基-2-戊烯置于喹啉,氯仿,溴体系中,化学反应生成2-甲基-1,3-戊二烯
    参考文献:Diels; Alder,Justus Liebigs Annalen Der Chemie,1929,Vol. 470,P. 103
    标题:Diels; Alder,Justus Liebigs Annalen Der Chemie,1929,Vol. 470,P. 103

    海关参考信息

    专利信息


    专利号:US-7829624-B2
    优先权日:2007-06-29
    标题:One-pot synthesis of nanoparticles and liquid polymer for rubber applications
    发明人:WARREN SANDRA
    权利人:BRIDGESTONE CORP
    摘要:A method for performing a one-batch synthesis of a blend of nanoparticles and liquid polymer includes polymerizing a first monomer and optionally a second monomer in a hydrocarbon solvent to form the liquid polymer. The polymerization is terminated before completion with a quenching agent. Then a charge of polymerization initiator, and a mixture of multiple-vinyl aromatic monomer and mono-vinyl aromatic monomer are added. This causes further polymerization whereby nanoparticles are formed in situ having a core including the multiple-vinyl aromatic monomer, and a shell including the first monomer or the first monomer and the second monomer. Liquid polymer/nanoparticle blends resulting from the method and rubber compositions incorporating the blends are also disclosed.

    专利号:US-8629288-B2
    优先权日:2008-02-25
    标题:Method for the regioselective synthesis of 1-alky1-3-haloalkyl-pyrazole-4-carboxylic acid derivatives
    发明人:PAZENOK SERGII; LUI NORBERT; HEINRICH JENS-DIETMAR; WOLLNER THOMAS
    权利人:PAZENOK SERGII; LUI NORBERT; HEINRICH JENS-DIETMAR; WOLLNER THOMAS; BAYER IP GMBH
    摘要:The present invention relates to a process for the regioselective synthesis of 1-alkyl-3-halo-alkylpyrazole-4-carboxylic acid derivatives by cyclization of 2,3-disubstituted acrylic acid derivatives, and to the hydrazones formed as intermediates in the process.

    专利号:US-5373053-A
    优先权日:1988-09-01
    标 题:Peptide synthesis method and solid support for use in the method
    发明人:BERG ROLF H; ALMDAL KRISTOFFER; PEDERSEN WALTHER B; HOLM ARNE; TAM JAMES P; MERRIFIELD ROBERT B
    权利人:RISO NAT LAB
    摘要:A method for the solid-phase synthesis of peptides or proteins in high yield and high purity uses a solid support consisting of a functionalized polystyrene-grafted polymer substrate, the grafted polystyrene chains being substantially non-cross-linked and having a chain molecular weight, not including optional non-reactive substituents, of at least 200,000, preferably in the range of 600,000-1,200,000. Particularly suitable polymer substrates are substrates of a polyolefin such as polyethylene. The method is particularly well-suited to the compartmentalized synthesis of a multitude of peptides or proteins in a parallel and substantially simultaneous fashion. n Preferred embodiments of a solid support for performing the synthesis are prepared from thin polyethylene sheet or film which has been grafted with polystyrene chains in a radical-initiated process in which the polyethylene sheet or film is immersed in a solution of optionally substituted styrene monomer in an alcohol such as methanol, the volume percentage of styrene in the solution preferably being about 30% v/v, and subjected to gamma irradiation.

    专利号:EP-0433345-B1
    优先权日:1988-09-01
    标题:Peptide synthesis method and solid support for use in the method
    发明人:BERG ROLF H; ALMDAL KRISTOFFER; PEDERSEN WALTHER BATSBERG; HOLM ARNE; TAM JAMES P; MERRIFIELD ROBERT BRUCE
    权利人:RISOE FORSKNINGSCENTER
    摘要:A method for the solid-phase synthesis of peptides or proteins in high yield and high purity uses a solid support consisting of a functionalized polystyrene-grafted polymer substrate, the grafted polystyrene chains being substantially non-cross-linked and having a chain molecular weight, not including optional non-reactive substituents, of at least 200,000, preferably in the range of 600,000-1,200,000. Particularly suitable polymer substrates are substrates of a polyolefin such as polyethylene. The method is particularly well-suited to the compartmentalized synthesis of a multitude of peptides or proteins in a parallel and substantially simultaneous fashion. Preferred embodiments of a solid support for performing the synthesis are prepared from thin polyethylene sheet or film which has been grafted with polystyrene chains in a radical-initiated process in which the polyethylene sheet or film is immersed in a solution of optionally substituted styrene monomer in an alcohol such as methanol, the volume percentage of styrene in the solution preferably being about 30 % v/v, and subjected to gamma irradiation.

    专利号:US-8933181-B2
    优先权日:2006-10-06
    标题:Branched polymers and methods for their synthesis and use
    发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
    权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
    摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

    专利号:US-10669160-B2
    优先权日:2018-04-30
    标题:Heterogeneous wet synthesis process for preparation of high purity tungsten pentahalide
    发明人:LIU YUMIN; LI FENG; WAN ZHIWEN; FAFARD CLAUDIA; WIESE STEFAN; HUSSON GUILLAUME; NIKIFOROV GRIGORY; SUI BIN; GIRARD JEAN-MARC
    权利人:AIR LIQUIDE; AIR LIQUIDE AMERICAN
    摘要:Synthesis of tungsten pentahalide compositions having low impurity profiles are disclosed. The specific impurity profile permits deposition of high purity tungsten-containing films using vapor deposition processes or other semiconductor manufacturing processes without introduction of performance-impacting contaminants.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 704.
    摘要:Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 47, 1030.
    摘要:Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 47, 1028.
    摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 697.
    摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 715.
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