CAS: 871-92-1; N-Octylsilane

上下游产品

CAS号5283-66-9 辛基三氯硅烷 | CAS号2943-75-1 正辛基三乙氧基硅烷 | CAS号7440-21-3 硅 | CAS号111-87-5 正辛醇 | CAS号111-83-1 1-溴代正辛烷

📜正辛基三乙氧基硅烷置于lithium Aluminium Tetrahydride体系中,用 乙醚 作为反应溶剂,化学反应生成 正辛基硅
参考文献:Carbon-silicon Bond Cleavage Of Organotrialkoxysilanes And Organosilatranes Withm-Chloroperbenzoic Acid Andn-Bromosuccinimide. New Route To Phenols,Primary Alcohols And Bromides
标题:Carbon-silicon Bond Cleavage Of Organotrialkoxysilanes And Organosilatranes Withm-Chloroperbenzoic Acid Andn-Bromosuccinimide. New Route To Phenols,Primary Alcohols And Bromides
摘要:烷基和芳基三乙氧基硅烷能够顺利地通过间氯过氧苯甲酸(m-氯过氧苯甲酸)进行氧化碳硅键断裂,得到相应的醇.类似地,硅拉烷分别与m-氯过氧苯甲酸和n-溴代丁二酰亚胺反应,分别得到醇和溴化物.
DOI:10.1246/cl.1981.243

专利信息

专利号:US-11951457-B2
优先权日:2021-01-04
标题 :Metal-silica nanocomposites prepared through a single step solution combustion synthesis (SCS)
发明人：ALI SARDAR; KUMAR DHARMESH; GAMAL AHMED; KHADER MAHMOUD M; EL-NAAS MUFTAH
权利人:UNIV QATAR
摘要:Provided herein is a novel silica-supported nickel nanocomposite and a novel one-pot solution combustion synthesis of that nanocomposite. The method allows the synthesis of small size nickel nanoparticles (e.g., 3 nm to 40 nm) for which a considerable percentage of nickel is inserted into silica, experiencing strong metal-support interaction. These exceptional physicochemical properties make them desirable for various industrial applications, such as electronic, heterogeneous catalysis as well as conversion and storage of energy.

专利号:US-7825268-B2
优先权日:2003-12-23
标 题:Alkoxylactones, alkoxylactams and alkoxythiolactams for controlling processes based on microbial interaction
发明人：STUMPE STEFAN; BREVES ROLAND; HUCHEL URSULA; JANSSEN FRANK; HAETZELT ANDRE
权利人:HENKEL AG & CO KGAA
摘要:Compounds of the Formula I, n nwherein A 1 is O or NH; A 2 is O or S; each of R 1 and R 2 is independently hydrogen, a methyl or C 2 -C 8 -saturated or mono- or doubly unsaturated, branched or linear hydrocarbon group; and R 3 is a C 1 -C 18 -saturated or mono- or doubly unsaturated, branched or linear hydrocarbon group wherein, each of R 1 , R 2 and R 3 comprises a heteroatom selected from the group consisting of O and S in the chain and/or is mono- or multiply-substituted by a substituent selected from the group consisting of halogen, hydroxy, C 1 -C 6 -alkyl, trifluoromethyl, C 1 -C 6 -alkoxy, C 6 -C 10 -aryl, and C 1 -C 6 -alkyl-C 6 -C 10 -aryl are useful for controlling the interaction process between microorganisms such as in the development and/or maturation of biofilms; multicellular swarm behavior; the concerted development of antibiotic resistances; the concerted synthesis of antibiotics; the concerted synthesis of pigments; the concerted production of extracellular enzymes; or the concerted production of virulence factors.

专利号:US-9371339-B2
优先权日:2013-05-06
标题 :Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
发明人：LEWIS KENRICK MARTIN; ATIENZA CRISITA CARMEN HOJILLA; BOYER JULIE L; CHIRIK PAUL J; DELIS JOHANNES G P; ROY AROOP KUMAR
权利人:LEWIS KENRICK MARTIN; ATIENZA CRISITA CARMEN HOJILLA; BOYER JULIE L; CHIRIK PAUL J; DELIS JOHANNES G P; ROY AROOP KUMAR; MOMENTIVE PERFORMANCE MAT INC; UNIV PRINCETON
摘要:The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.

专利号:US-9421532-B2
优先权日:2013-03-01
标 题:Mononuclear iron complex and organic synthesis reaction using same
发明人：NAGASHIMA HIDEO; SUNADA YUSUKE; TSUTSUMI HIRONORI; HASHIMOTO TORU; SAKUTA KOJI
权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO
摘要:Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. n n n n n n n n n n In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.

专利号:US-9884316-B2
优先权日:2014-03-10
标题:Mononuclear ruthenium complex and organic synthesis reaction using same
发明人：NAGASHIMA HIDEO; SUNADA YUSUKE; OGUSHI HAJIME; SAKUTA KOJI
权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO
摘要:A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. n n(In the formula, R 1 -R 6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R 1 -R 3 and any of R 4 -R 6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)

专利号:US-10363551-B2
优先权日:2015-03-09
标 题:Mononuclear iron complex and organic synthesis reaction using same
发明人：NAGASHIMA HIDEO; SUNADA YUSUKE; SAWANO Mina; NODA DAISUKE; SAKUTA KOJI
权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO
摘要:A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound. n n n n n n n n n n (In the formula, R 1 to R 6 independently represent a hydrogen atom, an alkyl group which may be substituted by X, or the like; X represents a halogen atom, or the like; L 1 represents at least one two-electron ligand selected from an isonitrile ligand, an amine ligand, an imine ligand, a nitrogenated heterocyclic ring, a phosphine ligand, a phosphite ligand and a sulfide ligand, wherein, when multiple L 1 's are present, two L 1 's may be bonded to each other; L 2 represents a two-electron ligand that is different from a CO ligand or the above-mentioned L 1 , wherein, when multiple L 2 's are present, two L 2 's may be bonded to each other; and m 1 represents an integer of 1 to 4 and m 2 represents an integer of 0 to 3, wherein the sum total of m 1 and m 2 (i.e., m 1 +m 2 ) satisfies 3 or 4.)