专利号:US-9266915-B2 优先权日:2012-09-24 标题 :Synthesis of open metal carbonyl clusters 发明人:KATZ ALEXANDER S; KUPERMAN ALEXANDER; OKRUT ALEXANDER; RUNNEBAUM RON C; OUYANG XIAOYING 权利人:CHEVRON USA INC; UNIV CALIFORNIA 摘要:The present invention is directed to the synthesis of novel stable open metal clusters by selective oxidation of bound ligands. The synthesis comprises, for example, using an amine based oxidant for decarbonylation of specific carbonyl ligands. The synthesis can also comprise further removal of a bound amine group by an acid. The resulting metal cluster contains a coordinatively unsaturated site comprising a carbonyl vacancy. The resulting metal cluster can be used as a catalyst in a variety of chemical transformations.
专利号:US-2015266912-A1 优先权日:2012-09-24 标题 :Synthesis of Open Metal Carbonyl Clusters
专利号:CA-2884564-A1 优先权日:2012-09-24 标题:Synthesis of open metal carbonyl clusters
专利号:CN-104936968-A 优先权日:2012-09-24 标 题 :Synthesis of open metal carbonyl clusters
专利号:US-2014088318-A1 优先权日:2012-09-24 标题 :Synthesis and Characterization of Open Metal Clusters