CAS: 193197-68-1; Tris[4-(1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluorohexyl)Phenyl]Phosphane

上下游产品

4-(tridecafluoro-n-hexyl)bromobenzene n-perfluorohexyl iodide tris(4-bromophenyl)phosphane oxide 1,4-bromoiodobenzene

📜Tris(4-Bromophenyl)Phosphine Oxide置于2,2'-联吡啶,三氯硅烷,铜,三乙胺体系中,用 二甲基亚砜,甲苯 用作溶剂,化学反应 42.0H,反应生成三[4-(十三氟己基)苯基]膦
参考文献:新型高效合成全氟烷基化芳基膦
标题:新型高效合成全氟烷基化芳基膦
摘要:已经开发出新颖的高产率途径来合成全氟烷基化的芳基膦,包括简单地,铜介导的卤代芳基膦氧化物与全氟烷基碘的简单偶联,然后用三氯硅烷还原.
Doi:10.1016/s0040-4039(00)00445-7

专利信息

专利号:US-6656446-B1
优先权日:1999-04-29
标题:Synthesis of hydrogen peroxide
发明人：BECKMAN ERIC J; HANCU DAN
权利人:UNIV PITTSBURGH
摘要:A method for synthesizing hydrogen peroxide comprises the step of: mixing an analog of a secondary alcohol that is soluble with carbon dioxide with a free radical initiator and oxygen in carbon dioxide to generate hydrogen peroxide. Another method of synthesizing hydrogen peroxide comprises the step of: mixing hydrogen, oxygen and a CO 2 -philic catalyst in carbon dioxide phase. The CO 2 -philic catalyst is soluble or miscible in carbon dioxide and is suitable to catalyze the reaction of hydrogen and oxygen to produce hydrogen peroxide. The method also comprises the step of reacting the hydrogen and oxygen to produce hydrogen peroxide.

专利号:WO-0066489-A1
优先权日:1999-04-29
标 题:Synthesis of hydrogen peroxide