CAS: 92-94-4; P-Terphenyl

• 英文名称P-Terphenyl
• 中文名称对三联苯
• IUPAC名称1,1':4',1''-terphenyl
• 其它别名P-Terphenyl; 1,4-Diphenylbenzene; 1,1':4',1''-Terphenyl; P-Diphenylbenzene; P-Triphenyl; 4-Phenylbiphenyl; 4-Phenyldiphenyl; Para-Terphenyl; Biphenyl, 4-Phenyl-; 1,1'-Biphenyl, 4-Phenyl-; Ptp; 4-Phenyl-1,1'-Biphenyl
• CAS编号92-94-4
• MFCD编号:MFCD00003061
• EINECS号:202-205-2
• FDA UNII编号:GWP218ZY6F
• 分子式:C18H14
• 分子量:230.3
• 产品CID: 1968300
• 产品分类有机原料 → 烃类化合物及其衍生物 → 芳香烃

• 相似结构搜索
• 产品信息参考
• InChIKey: XJKSTNDFUHDPQJ-UHFFFAOYSA-N
• InChI=1S/C18H14/c1-3-7-15(8-4-1)17-11-13-18(14-12-17)16-9-5-2-6-10-16/h1-14H…
• 计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数2.0

物理性质

• 熔点212-213  °C(文献)
• 沸点400.0±12.0 °C at 760 mmHg
• 闪点188.1±13.7 °C
• 密度1.0±0.1 g/cm3
• PSA:0.0
• LogP:5.63
• 折射率1.602
• 蒸汽压0.0±0.4 mmHg at 25°C
• 溶解性氯仿(微溶),DMSO(微溶,加热,超声处理)
• 敏感性Stable. Combustible. Incompatible with strong oxidizing agents.
• 外观形态白色固体
• 储存条件本品应密封保存避光保存。
• 产品应用用作导热体及原子反应堆冷却液.
• 性质描述白色片状结晶.熔点213°C,沸点383°C,250°C(6kPa),闪点207°C,相对密度1.234(0°C).溶于热苯,微溶于醚和二硫化碳,极难溶于乙醇和乙酸.427°C升华.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07 & GHS09;
  注释: Exclamation mark & Environment
• 危险类别急性毒性 类别4(经口)
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  特定目标器官毒性 - 单次接触 类别3
  水生急性毒性 类别1
  水生慢性毒性 类别4
  皮肤致敏 类别1
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H335 |可能引起呼吸道刺激.
  H400 |对水生生物毒性极大.
  H413 |可能对水生生物造成长期有害影响.
  H317 |可能引起皮肤过敏反应.
• 防范说明P264-P273-P280-P305+P351+P338-P337+P313-P501
• UN编号3077
• 危险品标志Xi:Irritant
• 安全声明S26-S37-S61-S60
• 危险类别码R36/37/38
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 P-Terphenyl 主要起始原料 1-Bromo-4-Iodobenzene And Phenylboronic Acid
• 21113-62-2 = 92-94-4
  反应条件:1.1 Reagents: Ceric Ammonium Nitrate,Tetrabutylammonium Hydrogen Sulfate Solvents: Chloroform
  标题:Generation Of The 1,4-Diphenylcyclohexane-1,4-Diyl Radical Cation By Cerium(Iv) Catalyzed Denitrogenation Of The Azoalkane 1,4-Diphenyl-2,3-Diazabicyclo[2.2.2]Oct-2-Ene And Its Reluctance To Undergo Cope Rearrangement
  作者:Adam,Waldemar; Grabowski,Sven; Miranda,Miguel A.; Ruebenacker,Martin
  参考文献:Journal Of The Chemical Society 日期:1988 卷标:(2) 页码:142-3]
  
  98-80-6 + 106-39-8 = 92-94-4
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Palladium Chloride,N2,N2,N6,N6-Tetrakis[(Diphenylphosphino)Methyl]-2,6-Pyridinediamine Solvents: Dimethylacetamide; 1 H,100 °C1.2 Solvents: O-Xylene; 2 H,90 °C
  标题:N,N,N',N'-Tetra(Diphenylphosphinomethyl)Pyridine-2,6-Diamine/palladium Catalyzed Suzuki-Miyaura Coupling Of Aryl And Heteroaryl Halides
  作者:Guo,Fei-Chen; Zhou,Rong; Jiang,Zhi-Jie; Wang,Wei; Fu,Hai-Yan; Et Al
  参考文献:Catalysis Communications 日期:2015 卷标:66 页码:87-90]
  
  98-80-6 = 92-94-4
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: (Sp-4-4)-[1,3-Bis[2,6-Bis(1-Methylethyl)Phenyl]-1,3-Dihydro-2H-Imidazol-2-Yliden... Solvents: Ethanol; 6 H,60 °C
  标题:Cyclometalated 2-Phenylimidazole Palladium Carbene Complexes In The Catalytic Suzuki-Miyaura Cross-Coupling Reaction
  作者:Micksch,Maik; Tenne,Mario; Strassner,Thomas
  参考文献:Organometallics 日期:2014 卷标:33(15) 页码:3966-3976]
  
  98-80-6 + 106-46-7 = 92-94-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 18-Crown-6,Palladium Trifluoroacetate,2-Dicyclohexylphosphino-2′,6′-Dimethoxybiphenyl Solvents: Carbon Dioxide; 18 H,110 Bar,120 °C
  标题:The Suzuki-Miyaura Cross-Coupling Of Bromo- And Chloroarenes With Arylboronic Acids In Supercritical Carbon Dioxide
  作者:Kuchurov,Ilya V.; Vasil'Ev,Andrei A.; Zlotin,Sergei G.
  参考文献:Mendeleev Communications 日期:2010 卷标:20(3) 页码:140-142]
  
  98-80-6 + 92-66-0 = 92-94-4
  反应条件:1.1 Catalysts: [1,1′-Binaphthalene]-4,4′-Diamine (Complexes With Palladium Dichloride),Palladium Chloride (Complexes With Naphthidine) Solvents: 1,4-Dioxane; 2 H,Rt1.2 Reagents: Tripotassium Phosphate Solvents: 1,4-Dioxane; 5 Min,Rt1.3 5 H,80 °C
  标题:Naphthidine Di(Radical Cation)S-Stabilized Palladium Nanoparticles For Efficient Catalytic Suzuki-Miyaura Cross-Coupling Reactions
  作者:Desmarets,Christophe; Omar-Amrani,Rafik; Walcarius,Alain; Lambert,Jacques; Champagne,Benoit; Et Al
  参考文献:Tetrahedron 日期:2008 卷标:64(2) 页码:372-381]
  
  98-80-6 = 92-94-4
  反应条件:1.1 Reagents: Tripotassium Phosphate,Potassium Fluoride Catalysts: Disodium Tetrachloropalladate Solvents: Dimethyl Sulfoxide,Water; 55 H,Rt -> 80 °C; 18 H,80 °C; 80 °C -> Rt
  标题:Homogeneous Catalysts Supported On Soluble Polymers: Biphasic Suzuki-Miyaura Coupling Of Aryl Chlorides Using Phase-Tagged Palladium-Phosphine Catalysts
  作者:An Der Heiden,Markus; Plenio,Herbert
  参考文献:Chemistry - A European Journal 日期:2004 卷标:10(7) 页码:1789-1797]
  
  98-80-6 + 624-38-4 = 92-94-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Palladium,Copper Solvents: Dimethylformamide1.2 -
  标题:Copper-Catalyzed Suzuki Cross-Coupling Using Mixed Nanocluster Catalysts
  作者:Thathagar,Mehul B.; Beckers,Jurriaan; Rothenberg,Gadi
  参考文献:Journal Of The American Chemical Society 日期:2002 卷标:124(40) 页码:11858-11859]
  
  98-80-6 + 624-38-4 = 92-94-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Chitosan,N-2-Propyn-1-Yl (Propargylated-Chitosan Functionalized Iron Oxide Supported; Post-Treated With Pd(Oac)2) Solvents: Ethanol,Water; 2 H,80 °C
  标题:Triazole Framework: A Strategic Structure For C-H...X Hydrogen Bonding And Practical Design Of An Effective Pd-Catalyst For Carbonylation And Carbon-Carbon Bond Formation
  作者:Mohammadsaleh,Fatemeh; Jahromi,Maryam Dehdashti; Hajipour,Abdol Reza; Hosseini,Seyed Mostafa; Niknam,Khodabakhsh
  参考文献:Rsc Advances 日期:2021 卷标:11(34) 页码:20812-20823]
  
  98-80-6 + 106-46-7 = 92-94-4
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: Palladium Diacetate,2′-(Dicyclohexylphosphino)-N,N-Dimethyl[1,1′-Biphenyl]-2-Amine Solvents: Toluene; 7 - 8 H,90 °C
  标题:Buchwald Ligand-Assisted Suzuki Cross-Coupling Of Polychlorobenzenes
  作者:Vasil'Ev,Andrei A.; Burukin,Alexander S.; Zhdankina,Galina M.; Zlotin,Sergei G.
  参考文献:Mendeleev Communications 日期:2021 卷标:31(3) 页码:400-402]
  
  98-80-6 + 106-37-6 = 92-94-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Palladium,Silica,N4-[3-(Triethoxysilyl)Propyl]-2,4,6-Pyrimidinetriamine (Palladium Complexes) Solvents: Ethanol,Water; 15 Min,100 °C
  标题:The Synthesis Of Sba-Pr-3Ap@pd And Its Application As A Highly Dynamic,Eco-Friendly Heterogeneous Catalyst For Suzuki-Miyaura Cross-Coupling Reaction
  作者:Mohajer,Fatemeh; Mohammadi Ziarani,Ghodsi; Badiei,Alireza
  参考文献:Research On Chemical Intermediates 日期:2020 卷标:46(11) 页码:4909-4922]
  
  591-50-4 + 5122-94-1 = 92-94-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Palladium Solvents: Ethanol; 10 Min; 3 Min,80 °C1.2 Solvents: Ethanol; 30 Min,80 °C
  标题:Minimalization Of Metallic Pd Formation In Suzuki Reaction With A Solid-State Organometallic Catalyst
  作者:Li,Bowen; Zeng,Hua Chun
  参考文献:Acs Applied Materials & Interfaces 日期:2020 卷标:12(30) 页码:33827-33837]
  
  98-80-6 + 106-37-6 = 92-94-4
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Palladium Solvents: Ethanol,Water; 6 H,80 °C
  标题:Spatially Isolated Palladium In Porous Organic Polymers By Direct Knitting For Versatile Organic Transformations
  作者:Wang,Xinbo; Min,Shixiong; Das,Swapan K.; Fan,Wei; Huang,Kuo-Wei; Et Al
  参考文献:Journal Of Catalysis 日期:2017 卷标:355 页码:101-109]
  
  591-50-4 + 5122-94-1 = 92-94-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Palladium,Graphene Solvents: Dimethylformamide,Water; 6 Min,90 °C
  标题:3D Graphene/nylon Rope As A Skeleton For Noble Metal Nanocatalysts For Highly Efficient Heterogeneous Continuous-Flow Reactions
  作者:Zhang,Sai; Shen,Xuetao; Zheng,Zhiping; Ma,Yuanyuan; Qu,Yongquan
  参考文献:Journal Of Materials Chemistry A: Materials For Energy And Sustainability 日期:2015 卷标:3(19) 页码:10504-10511]
  
  98-80-6 + 106-37-6 = 92-94-4
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: (Sp-4-3)-[2,6-Bis[(Di-1-Piperidinylphosphino-Kp)Amino]Phenyl-Kc]Chloropalladium Solvents: 1-Butanol,1,4-Dioxane,Water; 25 °C; 0.5 H,25 °C -> 100 °C1.2 Reagents: Water; 100 °C; 100 °C -> Rt
  标题:The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {c6H3[nhp(Piperidinyl)2]2Pd(Cl)} - A Highly Active Suzuki-Miyaura Catalyst With Excellent Functional Group Tolerance
  作者:Bolliger,Jeanne L.; Frech,Christian M.
  参考文献:Advanced Synthesis & Catalysis 日期:2010 卷标:352(6) 页码:1075-1080]
  
  591-50-4 + 99770-93-1 = 92-94-4
  反应条件:1.1 Reagents: Silver Carbonate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran
  标题:Efficient Synthesis Of Substituted Terphenyls By Suzuki Coupling Reaction
  作者:Chaumeil,Helene; Le Drian,Claude; Defoin,Albert
  参考文献:Synthesis 日期:2002 卷标:(6) 页码:757-760]
  
  98-80-6 + 92-66-0 = 92-94-4
  反应条件:1.1 Reagents: Tetrabutylammonium Bromide,Tripotassium Phosphate Catalysts: Palladium Diacetate Solvents: Dimethylformamide
  标题:Pdcl2(Set2)2 And Pd(Oac)2: Simple And Efficient Catalyst Precursors For The Suzuki Cross-Coupling Reaction
  作者:Zim,Danilo; Monteiro,Adriano L.; Dupont,Jairton
  参考文献:Tetrahedron Letters 日期:2000 卷标:41(43) 页码:8199-8202]
  
  98-80-6 + 92-66-0 = 92-94-4
  反应条件:1.1 Reagents: Tripotassium Phosphate Solvents: Ethanol,Water; 1 H,Rt
  标题:Palladium-Anchored N-Heterocyclic Carbenes In A Porous Organic Polymer: A Heterogeneous Composite Catalyst For Eco-Friendly C-C Coupling
  作者:Let,Sumanta; Dam,Gourab K.; Samanta,Partha; Fajal,Sahel; Dutta,Subhajit; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2022 卷标:87(24) 页码:16655-16664]
  
  98-80-6 + 589-87-7 = 92-94-4
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: 2721440-87-3 Solvents: Methanol; 3 H,Reflux
  标题:Synthesis Of Tetranuclear Complex Of Pd(Ii) With Thiosemicarbazone Ligands Derived From 2-Quinolone And Its Catalytic Evaluation In Suzuki-Miyaura-Type Coupling Reactions And Alkoxylation Of Chloroquinolines
  作者:Nandhini,Sundar; Dharani,Sivadasan; Elamathi,Chennakrishnan; Dallemer,Frederic; Prabhakaran,Rathinasabapathi
  参考文献:Applied Organometallic Chemistry 日期:2021 卷标:35(12)]
  
  98-80-6 + 92-66-0 = 92-94-4
  反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: [9-(Amino-Kn)-2,3,5,6,14,15-Hexafluoro-9,10-Dihydro-9,10[1′,2′]-Benzenoanthracen... Solvents: Isopropanol; 2 H,80 °C
  标题:Triptycene Ring Metal Palladium Compound And Use Thereof
  参考文献:China]
  
  324-74-3 = 92-94-4
  反应条件:1.1 Catalysts: Palladium Diacetate,2′-(Dicyclohexylphosphino)-N,N-Dimethyl[1,1′-Biphenyl]-2-Amine Solvents: Tetrahydrofuran; Rt; 16 H,80 °C
  标题:Aryl Fluoride Activation Through Palladium-Magnesium Bimetallic Cooperation: A Mechanistic And Computational Study
  作者:Wu,Chen; Mccollom,Samuel P.; Zheng,Zhipeng; Zhang,Jiadi; Sha,Sheng-Chun; Et Al
  参考文献:Acs Catalysis 日期:2020 卷标:10(14) 页码:7934-7944

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