CAS: 5337-72-4; 2,6-Dimethylcyclohexanol

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2816-57-1 1502-24-5 69542-91-2

上下游产品

CAS号576-26-1 2,6-二甲基苯酚 | CAS号2816-57-1 2,6-二甲基环己酮 (异构体的混合物) | CAS号75-09-2 二氯甲烷 | CAS号7647-01-0 盐酸 | CAS号64-19-7 冰醋酸 | CAS号60-29-7 乙醚 | CAS号7732-18-5 水 | CAS号576-26-1 2,6-二甲基苯酚 | CAS号2816-57-1 2,6-二甲基环己酮 (异构体的混合物) | CAS号2808-76-6 1,3-dimethylcyc... | CAS号69814-56-8 2-亚甲基-1,3-二氧杂环庚烷

📜二甲基环已酮置于sodium Tetrahydroborate体系中,化学反应生成 2,6-二甲基环己醇
参考文献:廉价,及时可用的亚胺基铁络合物催化的 H2O 2醇氧化†
标题:廉价,及时可用的亚胺基铁络合物催化的 H2O 2醇氧化†
摘要:我们之前曾报道过,亚氨基吡啶铁(II)配合物1可以原位容易定量获得,可以激活H2O 2.形成强大的氧化剂,能够进行脂肪族c-h键羟基化.在本研究中,我们将这种催化剂的应用范围扩大到将一系列醇氧化为相应的羰基化合物.脂族醇的氧化过程顺利进行,而苄醇的氧化则显示出挑战性.一些收集的证据表明,该氧化物种更倾向于芳环而不是醇部分.芳族环中电子密度的降低将氧化从芳族移向醇部分.出乎意料的是,环己醇相对于苄醇的优先氧化得以实现,显示出前所未有的选择性.
DOI:10.1039/c6Ob01984F

专利信息

专利号:US-5637757-A
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds
发明人：HILL JOHN E; FAVSTRITSKY NICOLAI A; MAMUZIC RASTKO I; BHATTACHARYA BHABATOSH
权利人:GREAT LAKES CHEMICAL CORP
摘要:A method of preparing tetrabromobenzoate compounds from tetrabromophthalic anhydride by reacting tetrabromophthalic anhydride with alcohol in the presence of a decarboxylation catalyst. The reaction may be carried out in an excess of alcohol, or with a near stoichiometric amount of alcohol by performing the reaction in an inert solvent.

专利号:WO-9632368-A1
优先权日:1995-04-11
标题:One-pot synthesis of ring-brominated benzoate compounds

专利号:EP-0825974-A1
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds

专利号:CA-2217760-A1
优先权日:1995-04-11
标题:One-pot synthesis of ring-brominated benzoate compounds

专利号:EP-0825974-A4
优先权日:1995-04-11
标题:SYNTHESIS IN A SINGLE CONTAINER OF BROMINATED BENZOATE CYCLIC COMPOUNDS

专利号:US-5455361-A
优先权日:1992-09-17
标 题 :Process for preparing ketene acetals
发明人：FLEISCHMANN GERALD; ECK HERBERT; PETERSEN HERMANN; PFLAUM SIEGFRIED
权利人:WACKER CHEMIE GMBH
摘要:The invention relates to a process for preparing ketene acetals by dehydrohalogenation of 2-haloaldehyde acetals. If the 2-haloaldehyde acetal is open chain, the dehydrohalogenation is carried out in the presence of an alkali metal hydroxide or alkaline earth metal hydroxide and a phase transfer catalyst and/or a secondary or tertiary alcohol or a secondary or tertiary diol. If the 2-haloaldehyde acetals is cyclic, the dehydrohalogenation is carried out in the presence of an alkali metal hydroxide or alkaline earth metal hydroxide and a phase transfer catalyst and with or without a secondary or tertiary alcohol or a secondary or tertiary diol, or carried out in the presence of an alkali metal hydroxide or alkaline earth metal hydroxide and a secondary or tertiary diol. The ketene acetals which can be prepared by the process of the invention serve as intermediates in organic synthesis and are suitable as monomers or comonomers in free radical polymerization for the production of biodegradable plastics.