CAS: 46331-50-4; 5-Methoxyisophthalic Acid

上下游产品

3,5-dimethylmethoxybenzene 3-ethyl-5-methyl-anisole dimethylsulfone 5-Hydroxyisophthalic acid dimethyl 5-methoxyisophthalate 4-methoxy-1,3-benzenedicarbonyl dichloride -5-methoxybenzene1,3-bis(succinimidooxy)carbonyl-5-methoxybenzene 5-methoxy-1,3-cyclohexanedicarboxylic acid

5-羟基间苯二甲酸置于硫酸,Potassium Carbonate,Sodium Hydroxide体系中,用 甲醇,乙腈 作为反应溶剂,化学反应 4.0H,反应生成 5-甲氧基间苯二甲酸
参考文献:双吡咯基苯阴离子受体:从超分子开关到分子逻辑门
标题:双吡咯基苯阴离子受体:从超分子开关到分子逻辑门
摘要:我们设计了基于构象不稳定的双吡咯基苯骨架的阴离子受体4,其构象可以通过适当的阴离子刺激来改变.在不存在氟阴离子的情况下,吡咯部分在室温下自由旋转.但是,当氟阴离子的浓度超过2个当量时,吡咯单元的旋转变慢,受体的构型变为anti-Anti.dft计算表明,这种变化是由于第三个氟化物阴离子通过ch相互作用而引起的.阴离子受体4也可以用作分子逻辑门.阴离子输入(例如氟化物和磷酸二氢盐)允许实现inhibit和nand逻辑门功能,分别以吸收和荧光作为读数.
DOI:10.1002/chem.201403116

专利信息

专利号:US-9951095-B2
优先权日:2014-05-16
标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
发明人：ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
权利人:TEXAS A & M UNIV SYS
摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

专利号:WO-2025052716-A1
优先权日:2023-09-06
标 题:Method for producing mof membrane composite, and mof membrane composite
发明人：AKAHIRA TOMOYO; KAZAOKA DAIKI; MIYAHARA MAKOTO; NODA KENICHI
权利人:NGK INSULATORS LTD
摘要:This method for producing an MOF membrane composite involves: adhering a seed crystal of a CAU-10-type MOF onto a support (step S12); preparing an Al source solution, which is an aqueous solution containing an Al ion source (step S13a); preparing a ligand solution in which an organic ligand used for the synthesis of the CAU-10 type MOF is dissolved in a solvent (step S13b); preparing a raw material solution by mixing, at a speed at which turbidity is not generated, the ligand solution with the Al source solution (step S14); and forming an MOF film, that is, a CAU-10-type MOF, on the support through solvothermal synthesis by immersing the support in the raw material solution (step S15).

专利号:US-2017050995-A1
优先权日:2014-05-16
标题:Chromium Metal Organic Frameworks and Synthesis of Metal Organic Frameworks

专利号:EP-3143033-B1
优先权日:2014-05-16
标题 :Chromium metal organic frameworks and synthesis of metal organic frameworks

专利号:WO-2015173553-A1
优先权日:2014-05-16
标 题 :Chromium Metal Organic Frameworks and Synthesis of Metal Organic Frameworks

专利号:US-12037347-B1
优先权日:2018-12-19
标题 :Multivariate carboxylate derivatized phenyl-based metal-organic frameworks
发明人：PETERSON GREGORY W; EPPS III THOMAS H
权利人:U S ARMY COMBAT CAPABILITIES DEV COMMAND CHEMICAL BIOLOGICAL CENTER APG MD; US ARMY
摘要:is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C1-C4 alkyl secondary amine, C1-C4 alkyl oxy, Br—(C1-C4 alkyl), NO2—(C1-C4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH3(CH2)mC(O)Cl, or CH3(CH(C1-C4 alkyl)CH2)mC(O)Cl, or CH3(CH2)m-Ph-(CH2)pC(O)Cl, where Ph is a C6 phenyl or C6 phenyl with one or more hydrogens replaced with F, C1-C4 fluoroalkyl, or C1-C4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>×>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.