CAS: 4245-37-8; Vinyl Methacrylate(Stabilizedwithmehq)

该化合物是一种多功能单体,其特征是其两功能组:一个乙烯组和一个甲基丙烯酸酯组,这种结构能够参与自由激进和添加聚合反应,使其对生产具有定制特性的交叉关联聚合物具有价值;该复合物具有高度的回活动性,促进与其他单体高效共聚以提高材料性能;其应用包括涂层,粘合剂和特殊树脂,它有助于改进耐久性,化学抗药性和热稳定性;乙烯丙烯酸酯建立密集交叉连接网络的能力也使其适合高性能复合物和牙科材料;处理要求反应单体的标准安全防范措施,包括防止过早聚合.

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CAS号79-41-4 甲基丙烯酸 | CAS号74-86-2 乙炔 | CAS号760-93-0 甲基丙烯酸酐 | CAS号108-05-4 乙酸乙烯酯 | CAS号75-07-0 乙醛 | CAS号920-46-7 甲基丙烯酰氯 | CAS号108-24-7 乙酸酐 | CAS号2157-01-9 2-甲基-2-丙烯酸辛酯 | CAS号1445-91-6 (S)-(-)-1-苯基乙醇 | CAS号33795-49-2 11-溴甲基丙烯酸十一酯 | CAS号142-09-6 甲基丙烯酸己酯 | CAS号130224-95-2 甲基丙烯酸5-氧代四氢呋喃-3-基酯 | CAS号2210-28-8 甲基丙烯酸丙酯

合成工艺路线路线简述

    乙醛,甲基丙烯酰氯置于吡啶体系中,化学反应生成 甲基丙烯酸乙烯酯
    参考文献:Sladkow; Petrow,Zhurnal Obshchei Khimii,1954,Vol. 24,P. 450,452;Engl.Ausg.S.459,460
    标题:Sladkow; Petrow,Zhurnal Obshchei Khimii,1954,Vol. 24,P. 450,452;Engl.Ausg.S.459,460

    海关参考信息

    专利信息


    专利号:WO-2019202038-A3
    优先权日:2018-04-19
    标 题:Synthesis and polymerization of isosorbide-based monomethacrylates
    发明人:PARVE JAAN; Vares Lauri; PEHK TÕNIS; GATHERGOOD NICHOLAS; PARVE OMAR; JANNASCH PATRIC; MATT LIVIA
    权利人:UNIV TARTU; TALLINN UNIV OF TECHNOLOGY; NAT INSTITUTE OF CHEMICAL PHYSICS AND BIOPHYSICS
    摘要:Isosorbide-5-methacrylate was obtained by enzymatic catalysis with Lipozyme RM IM in a highly regioselective manner in up to 87% yield. The process uses readily available acyl donors (methacrylic anydride or vinyl methacrylate), is easily scalable and chromatography free. Simple extractive workup followed by decoloration and filtration affords the monomer with up to > 99% purity. In addition, the developed enzymatic strategy was applied for the synthesis of a series of isosorbide 5- and 2-methacrylate derivatives. All the sythesized isosorbide monomethacrylates were radically polymerized with AIBN. The properties of these polymers with different side groups in either endo or exo configuration in the isosorbide structure was examined. The methacrylic isosorbide derivatives with OH-group were found to have very high glass transition temperature (Tg = 167 °C) and good thermal stability (at 5% weight loss under N2, Td,95 = 240 °C). The highest molecular weight (Mn = 80.6 kg/mol) was determined for the polymethacrylate with Ac-substitute.

    专利号:US-2023212107-A1
    优先权日:2021-12-30
    标 题:Synthesis of para-alkylated syringyl (meth)acrylate derivatives and photopolymerizable compositions for additive manufacturing in dental applications
    发明人:CHOUDHARY UMESH UPENDRA; SU JESSICA KALAY
    权利人:ALIGN TECHNOLOGY INC
    摘要:The present disclosure provides polymerizable monomers which may be used as reactive diluents in additive manufacturing. The polymerizable monomers may have low vapor pressures and may be compatible with a range of low glass transition temperature oligomers.

    专利号:US-10336912-B2
    优先权日:2014-08-01
    标 题 :Methods for producing and using aqueous polyurethane/polyacrylate hybrid dispersions and use of said aqueous polyurethane/polyacrylate hybrid dispersions in coating agents
    发明人:JAHNS EKKEHARD; MANGEL TIMO; ROESCH CHRISTINE; ROMANATO PAOLA; BURK YENI; PAKUSCH JOACHIM
    权利人:BASF SE
    摘要:The present invention provides an aqueous polyurethane (PU)-polyacrylate hybrid dispersion obtainable by free radical polymerization of at least one acrylate polymer (A1) in the presence of at least one polyurethane (P1), a process for preparing these aqueous polyurethane-polyacrylate hybrid dispersions, wherein said process comprises a) preparing an aqueous polyurethane dispersion and b) using the polyurethane dispersion thus prepared as raw material for the further synthesis of a polyacrylate dispersion, and the use of the hybrid dispersion thus obtained as binder in filled coating materials, particularly as a binder for flexible roof coatings.

    专利号:US-8541524-B2
    优先权日:2006-07-04
    标 题 :Free-radical polymerization process in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer
    发明人:FRINGANT CHRISTOPHE; VANDERVEKEN YVES; LACROIX-DESMAZES PATRICK; TONNAR JEFF
    权利人:FRINGANT CHRISTOPHE; VANDERVEKEN YVES; LACROIX-DESMAZES PATRICK; TONNAR JEFF; SOLVAY
    摘要:Process of controlled free-radical polymerization in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer using molecular iodine and at least one oxidant whose solubility in water is at least 10 g/l for the synthesis of the first block of the block copolymer.

    专利号:EP-2647639-A1
    优先权日:2012-04-06
    标题:ß-boration of alkene and alkyne intermediates
    权利人:LEK PHARMACEUTICALS
    摘要:The present invention relates to the field of organic chemistry, and in particular to the preparation of β-borated compounds. These β-borated compounds can be used as intermediates in the synthesis of pharmaceutically active agents such as Sitagliptin.

    专利号:US-2002004548-A1
    优先权日:1996-09-24
    标题 :Synthesis of matte beads containing carboxylic acid and their use in photographic elements
    发明人:SMITH DENNIS EDWARD; MUEHLBAUER JOHN LEONARD; WANG YONGCAI
    摘要:The present invention is a process for making polymeric particles by reacting an ethylenically unsaturated monomer as a dispersed phase suspended in an aqueous phase. The aqueous phase contains a water-insoluble particulate stabilizer having a size less than 100 nanometers in an effective amount of water-soluble inorganic salt to allow formation of stable monomer droplets in the aqueous phase, the monomer droplets include at least 20% of a carboxylic acid-containing monomer. The present invention also provides an imaging element comprising a support and at least one layer containing polymer particles of the formula: (A) x (B) y , where A is ethylenically unsaturated monomer containing carboxylic acid groups, B is a water insoluble ethylenically unsaturated monomer, x is greater than 20% and y is equal to 100% minus x. The polymer particles are covered with a layer of water-insoluble solid particulate stabilizer having a size less than 100 nanometers.
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    合成参考文献


    摘要:Compound: Vinyl methacrylate polymer
    参考文献:10.1385/abab:129:1:265
    摘要:Jeong GT, Lee HJ, Kim HS, Park DH. Enzymatic synthesis of sorbitan methacrylate according to acyl donors. Appl Biochem Biotechnol. 2006;129-132():265–77. doi: 10.1385/abab:129:1:265.
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