2-Butyl-3-Hydroxy-Acrylaldehyde置于盐酸,Sodium Hydroxide,Sodium Methylate,铜体系中,用 喹啉,甲醇 用作溶剂,化学反应 1.75H,反应生成3-丁基噻吩 参考文献:3-Alkyl Or Aryl Thiophenes From Malonaldehyde Derivatives 标题:3-Alkyl Or Aryl Thiophenes From Malonaldehyde Derivatives 摘要:A Synthesis Of 3-Alkyl Or Aryl Thiophenes Is Described Starting From Malonaldehydes. Doi:10.1080/00397919408010175
专利号:US-7247230-B2 优先权日:2003-08-08 标 题:Electrochemical synthesis and processing of conducting polymers in supercritical media 发明人:MABROUK PATRICIA ANN 权利人:UNIV NORTHEASTERN 摘要:The present invention deals with the electrochemical synthesis of electrically conductive polymers in supercritical fluids, for example supercritical CO 2 . The use of the supercritical fluid as a solvent results in the reduction or elimination of hazardous reagents and environmentally hazardous waste, which was generated in the prior chemical synthesis techniques. The electrochemical approach eliminates the need to add a charge transfer agent as the electrode serves this purpose. The resulting polymers are characterized by high conductivities and distinctive surface morphology, which suggests that they may be more appropriate than the previous materials for certain applications (e.g., corrosion inhibition, optical applications, etc.).
专利号:US-5855819-A 优先权日:1997-03-27 标 题:Synthesis of conductive polymers in liquid and supercritical CO2 发明人:DESIMONE JOSEPH M; NI YIZENG 权利人:UNIV NORTH CAROLINA 摘要:A method of forming an electrically conductive polymer comprises providing a reaction mixture in carbon dioxide, the reaction mixture comprising at least one monomer and a charge transfer agent. The monomer is then polymerized in the carbon dioxide to form a polymer, and the polymer is doped with the charge transfer agent so that the polymer is an electrically conductive polymer.
专利号:WO-2007007735-A1 优先权日:2005-07-12 标 题 :Synthesis of organic conductive polymerizable material onto metal oxide surface through light irradiation 发明人:TACHIBANA YASUHIRO 权利人:UNIV OSAKA; KANSAI TECH LICENSING ORG CO; TACHIBANA YASUHIRO 摘要:Disclosed is a composite material having a nanostructure containing metal oxide fine particles and an organic conductive polymerizable material. In this composite material, the metal oxide fine particles are joined with one another and the organic conductive polymerizable material is contained in the spaces between the fine particles. In this connection, the organic conductive polymerizable material is a copolymer which is composed of a polythiophene derivative, a thiophene or a derivative thereof and pyrrole, aniline, fluorene, furan or a derivative thereof. Also disclosed is a method for producing such a composite material. This composite material is useful for display elements such as electronic paper.
专利号:US-2015273737-A1 优先权日:2014-04-01 标题 :Flexible and stretchable graphene film and preparing method of the same 发明人:CHEN YANG-FANG; LAI YING-CHIH 权利人:UNIV NAT TAIWAN 摘要:The present invention relates to a flexible and stretchable graphene film, comprising a graphene layer and a functional layer formed on the graphene layer; a preparing method of the graphene film. The present invention further relates to a method of producing a graphene film, comprising: (a) providing a carrier, and a graphene layer is formed on the surface of the carrier, (b) forming a functional layer containing an insulating polymer and a conductive material on a top portion of the graphene film; and (c) dissolving the carrier by an etchant. Without harsh synthesis and complicated fabrication steps, the graphene film of the present invention is able to transfer onto various substrates, and is largely beneficial to various electronic applications.
专利号:US-7838624-B2 优先权日:2007-05-15 标题:Mixed halogen polymerization 发明人:LAIRD DARIN; SHEINA ELENA 权利人:PLEXTRONICS INC 摘要:Synthesis of regioregular thiophene-based polymers (PTs) and their functionalized counterparts via metal assisted cross-coupling polymerizations utilizing mixed halogen substituted aryl halide monomer precursors. The described method provides a means to control structural homogeneity and regioregularity and the electronic/spectroscopic properties of functionalized PTs, and leads to improved performance of organic semiconductor devices such as OPVs and/or OFETs. Asymmetrical monomers can be used.
专利号:WO-9843250-A1 优先权日:1997-03-27 标 题 :Synthesis of conductive polymers in liquid and supercritical co¿2?
参考标题:Metal-Free Oxidative Coupling Reactions Via σ-Iodonium Intermediates: The Efficient Synthesis Of Bithiophenes Using Hypervalent Iodine Reagents 作者:Koji Morimoto,Tomofumi Nakae,Nobutaka Yamaoka,Toshifumi Dohi,Yasuyuki Kita |发布日期:2011.11 摘要:The Direct Oxidative Biaryl Coupling Reaction Is An Attractive Tool For Environmentally Benign Green Chemistry. A Novel Direct Method For The Synthesis Of Bithiophene Using A Hypervalent Iodine Reagent Has Been Developed. The Reaction Mechanism Has Also Been Investigated, Casting Light On The Reaction Intermediate And Revealing The Reactivity With Iodonium Salts.
合成参考文献
摘要:Compound: Thiophene, 3-butyl-, homopolymer 摘要:Logeswaran, R.; Aravindan, N.; Jeganmohan, M., Science of Synthesis: Cross-Dehydrogenative Coupling, (2023) nan, 30.