CAS: 7726-20-7; 1,1'-Sulfonylbis[octane]

相似化合物

598-04-9 40390-85-0 154619-11-1

上下游产品

CAS号2690-08-6 二正辛基硫醚 | CAS号111-83-1 1-溴代正辛烷 | CAS号1986-89-6 二正辛基亚砜 | CAS号64-19-7 冰醋酸 | CAS号7697-37-2 硝酸 | CAS号111-66-0 1-辛烯 | CAS号3944-71-6 1-°Ctanesulfini...

📜二正辛基亚砜置于air,二氧化氯体系中,化学反应 10.0H,反应生成 二正辛砜
参考文献:Kuchin; Rubtsova; Loginova,Russian Journal Of Organic Chemistry,2000,Vol. 36,# 12,P. 1819-1820
标题:Kuchin; Rubtsova; Loginova,Russian Journal Of Organic Chemistry,2000,Vol. 36,# 12,P. 1819-1820

专利信息

专利号:US-3876689-A
优先权日:1972-08-28
标题:One-step synthesis of alpha, beta-unsaturated sulfonate salts by the reaction of carbon tetrahalides with certain sulfones
发明人：MEYERS CAL Y; HO LAURENCE L
权利人:UNIV SOUTHERN ILLINOIS
摘要:.alpha.,.beta.-Unsaturated sulfonic acid salts are prepared by a one step synthesis involving reaction of a di-primary alkyl sulfone, an arylmethyl primary alkyl sulfone, an .alpha.-halo diprimary alkyl sulfone, or an .alpha.-haloarylmethyl primary alkyl sulfone with a carbon tetrahalide and a strong base. The sulfone substrate is reacted with a carbon tetrahalide represented by the formula CBr.sub.m Cl.sub.n F.sub.p where m and n are integers between 0 and 4 inclusive, p is an integer between 0 and 2 inclusive and m+n+p = 4 in the presence of the strong base to form a geminally .alpha.-dihalogenated intermediate and dihalocarbene. The geminally .beta.-dihalogenated intermediate reacts rapidly in situ with the strong base to form an .alpha.,.beta.-unsaturated sulfonic acid salt and a halide salt. The unsaturated sulfonic acid salt may be acidified to form the corresponding acid or reacted with a halogenating agent to form the corresponding acid halide. .alpha.,.beta.-Unsaturated sulfonic acid salts are useful detergents.

专利号:US-6762329-B2
优先权日:1997-10-06
标题 :Diaryl ether condensation reactions
发明人：MARCOUX JEAN-FRANCOIS; DOYE SVEN; BUCHWALD STEPHEN
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:One aspect of the present invention relates to novel reaction conditions that allow the efficient synthesis of diaryl ethers from arenes bearing a leaving group and arenols under relatively mild conditions. Another aspect of the present invention relates to the dramatic effects of acidic activators on Ullmann-type couplings involving electron-poor and/or relatively insoluble substrates.