CAS: 14040-11-0; Tungsten Hexacarbonyl

该化合物是由钨和碳基离子体组成的化学化合物,其特点是分子式W(CO)6,表明含有一个与六种一氧化碳(CO)分子相协调的钨原子,该化合物在室内温度上是一种无色,挥发性强的固体,在惰性条件下以其高度稳定性而闻名. 东氏六碳基物展示一种三角双极基碳基几何法,这是金属碳基复合体的典型特征.它溶于苯和甲苯等有机溶剂中,但对水和空气敏感,导致分解.该化合物主要用于有机金属化学,并作为含有钨材料的前体.该化合物的活性允许它参与各种化学反应,包括替代和减少过程.由于其独特的特性,六碳基碳基锡在催化和材料科学中很受关注,尽管处理需要谨慎,因为其毒性和环境危害.

结构式图片

相似化合物

13939-06-5 13007-92-6 14516-54-2

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上下游产品

CAS号54099-82-0 | CAS号124-38-9 二氧化碳 | CAS号37823-96-4 pentacarbonyl[(... | CAS号71771-28-3 [bis(triphenylp... | CAS号15096-68-1 acetonitrile (p... | CAS号201230-82-2 carbon monoxide | CAS号144299-40-1 trans-{Me3P}(°C... | CAS号2170-09-4 N-甲基邻甲苯酰胺 | CAS号130250-61-2 2,N-二甲基-N-甲氧基苯甲酰胺 | CAS号7440-33-7 钨粉 | CAS号33505-53-2 W(CO)3(η6-Me6C6) | CAS号120120-97-0 | CAS号114221-42-0 fac,fac-(tungst... | CAS号7440-44-0 活性炭 | CAS号75-44-5 光气 | CAS号29743-03-1 Tungsten,pentac... | CAS号88070-48-8 Benzenecarboxim...

合成工艺路线路线简述

    📜[bis(Triphenylphosphine)Nitrogen][w(Co)5(Sh)]置于ch3Hgcl,Agbf4体系中,用 二氯甲烷 用作溶剂,以64%的收率获得六羰基钨
    参考文献:Angelici,Robert J.; Gingerich,Richard G. W.,Organometallics,1983,Vol. 2,# 1,P. 89-95
    标题:Angelici,Robert J.; Gingerich,Richard G. W.,Organometallics,1983,Vol. 2,# 1,P. 89-95

    专利信息


    专利号:US-7273509-B1
    优先权日:2001-12-10
    标 题 :Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds
    发明人:KELLER TEDDY M; QADRI SYED B
    权利人:US OF AMERICA AS OF OF AMERICA
    摘要:A process of making metal nanoparticles comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or a solid at room temperature; and heating the precursor composition under conditions effective to produce metal nanoparticles. A metal nanoparticle composition comprising metal nanoparticles dispersed homogenously in a matrix selected from the group consisting of ethynyl polymer, crosslinked ethynyl polymer, amorphous carbon, carbon nanotubes, carbon nanoparticles, graphite, and combinations thereof.

    专利号:US-11958751-B2
    优先权日:2022-06-27
    标 题:Method of synthesizing materials integrating supernatant recycle
    发明人:HODGKINS ROBERT P; KOSEOGLU OMER REFA
    权利人:SAUDI ARABIAN OIL CO
    摘要:Methods are disclosed for synthesizing materials, including an initial synthesis in the presence of WS-ODSO (which can include a pH-modified WS-ODSO composition, in certain embodiments a neutralized WS-ODSO composition), and one or more subsequent syntheses using supernatant (“mother liquorâ€?) from a previous synthesis of the same or different materials. The synthesized materials in the initial synthesis and in subsequent synthesis can be the same or different inorganic oxide materials including amorphous oxides, crystalline oxides or oxides of metals. The methods advantageously reduce the amount of utility water required for synthesizing a material and reduce the water waste, and reduce the DSO waste from a refinery and discharge into the environment. In certain embodiments the methods reduce the requirements to procure an alkaline reagent required for synthesizing materials. In certain embodiments, supernatant can be recycled over multiple synthesis batches of the same or different type of materia.

    专利号:US-2010102700-A1
    优先权日:2008-10-24
    标题:Flame spray pyrolysis with versatile precursors for metal oxide nanoparticle synthesis and applications of submicron inorganic oxide compositions for transparent electrodes
    发明人:JAISWAL ABHISHEK; ERNST FRANK O; CHIRUVOLU SHIVKUMAR; LEE JIA X; BUCHEL ROBERT; PRATSINIS SOTIRIS E
    权利人:JAISWAL ABHISHEK; ERNST FRANK O; CHIRUVOLU SHIVKUMAR; LEE JIA X; BUCHEL ROBERT; PRATSINIS SOTIRIS E
    摘要:Flame spray pyrolysis can be performed using aqueous solvents for the delivery of metal and/or metalloid oxide precursors while obtaining desirably high flame temperatures for the synthesis of uniform submicron inorganic oxide particles. A multiple liquid channel nozzle can be used to deliver liquid for the formation of the aerosol that is combusted in the flame. One or both channels can deliver liquid with metal/metalloid precursors and/or organic fuels. Flame spray pyrolysis can be used to form metal tungsten oxide submicron particles. Metal tungsten oxide compositions can be used in the formation of transparent electrodes. If the transparent electrodes are formed from polymer inorganic particle composites, the composites can further comprise electrically conductive nanoparticles to improve the electrical conductivity.

    专利号:US-6409851-B1
    优先权日:1996-11-04
    标题 :Microwave plasma chemical synthesis of ultrafine powders
    发明人:SETHURAM KRUPASHANKARA M; KALYANARAMAN RAJA
    权利人:MATERIALS MODIFCIATION INC
    摘要:The present invention relates to the production of ultrafine powders using a microwave plasma apparatus and chemical synthesis technique. Microwaves generated by a magnetron ( 1 ) are passed through waveguides ( 2 ) before they arrive at the head of a plasmatron ( 3 ). These high energy microwaves ionize a plasma gas, thus releasing large amounts of energy. The energy thus released is utilized to initiate and sustain chemical reactions between the desired elements being pumped in a spiral pattern into the plasmatron ( 3 ). The reaction products are quenched rapidly in a reactor column ( 4 ) into ultrafine powders.

    专利号:US-7722851-B2
    优先权日:2001-12-10
    标题 :Bulk synthesis of carbon nanotubes from metallic and ethynyl compounds
    发明人:KELLER TEDDY M; QADRI SYED B
    权利人:US NAVY
    摘要:A process of making carbon nanotubes comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or solid at room temperature; and heating the precursor composition under conditions effective to produce carbon nanotubes. A carbon nanotube composition comprising carbon nanotubes and a metal component selected from the group consisting of metal nanoparticles and elemental metal; wherein the carbon nanotube composition is rigid.

    专利号:US-9303046-B2
    优先权日:2012-08-07
    标 题:Process for the preparation of heterocyclic ester derivatives
    发明人:BONGARTZ JEAN-PIERRE ANDRÉ MARC; STAPPERS ALFRED ELISABETH; TELEHA CHRISTOPHER A; WEERTS KOEN JOHAN HERMAN; WILSON KENNETH J
    权利人:JANSSEN PHARMACEUTICA NV
    摘要:The present invention is directed to a process for the preparation of heterocyclic ester derivatives of formula I n nwherein A 1 , SEM, and W 1 are as defined herein. Such compounds are useful as intermediates in the synthesis of derivatives useful as protein tyrosine kinase inhibitors, more particularly inhibitors of c-fms kinase.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Camille Cau, Et Al. Mechanism Of W(Co)6 Sonolysis In Diphenylmethane. Ultrason Sonochem. 2012 May;19(3):498-502.
    [参考文献]: F Porrati, Et Al. The Transient Electrical Conductivity Of W-Based Electron-Beam-Induced Deposits During Growth, Irradiation And Exposure To Air. Nanotechnology. 2009 May 13;20(19):195301.
    [参考文献]: J Feldmann, Et Al. Determination Of Ni(Co)4, Fe(Co)5, Mo(Co)6, And W(Co)6 In Sewage Gas By Using Cryotrapping Gas Chromatography Inductively Coupled Plasma Mass Spectrometry. J Environ Monit. 1999 Feb;1(1):33-7.
    [参考文献]: Keisha-Gay Hylton, Et Al. Catalytic Carbonylation Of Functionalized Diamines: Application To The Core Structure Of Dmp 323 And Dmp 450. J Org Chem. 2003 Feb 21;68(4):1615-7.
    [参考文献]: Lei Li, Et Al. Millisecond Pulsed Radio Frequency Glow Discharge Time Of Flight Mass Spectrometry: Temporal And Spatial Variations In Molecular Energetics. J Am Soc Mass Spectrom. 2004 Jan;15(1):87-102.

    合成参考文献


    摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 753.
    摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1426.
    摘要:Ogasawara, M., Science of Synthesis, (2008) 44, 59.
    摘要:Aguilar, E.; López, L. A., Science of Synthesis Knowledge Updates, (2014) 2, 2.
    摘要:Luh, T.-Y.; Leung, M.-k., Science of Synthesis Knowledge Updates, (2018) 2, 369.
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