📜[bis(Triphenylphosphine)Nitrogen][w(Co)5(Sh)]置于ch3Hgcl,Agbf4体系中,用 二氯甲烷 用作溶剂,以64%的收率获得六羰基钨 参考文献:Angelici,Robert J.; Gingerich,Richard G. W.,Organometallics,1983,Vol. 2,# 1,P. 89-95 标题:Angelici,Robert J.; Gingerich,Richard G. W.,Organometallics,1983,Vol. 2,# 1,P. 89-95
专利信息
专利号:US-7273509-B1 优先权日:2001-12-10 标 题 :Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds 发明人:KELLER TEDDY M; QADRI SYED B 权利人:US OF AMERICA AS OF OF AMERICA 摘要:A process of making metal nanoparticles comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or a solid at room temperature; and heating the precursor composition under conditions effective to produce metal nanoparticles. A metal nanoparticle composition comprising metal nanoparticles dispersed homogenously in a matrix selected from the group consisting of ethynyl polymer, crosslinked ethynyl polymer, amorphous carbon, carbon nanotubes, carbon nanoparticles, graphite, and combinations thereof.
专利号:US-11958751-B2 优先权日:2022-06-27 标 题:Method of synthesizing materials integrating supernatant recycle 发明人:HODGKINS ROBERT P; KOSEOGLU OMER REFA 权利人:SAUDI ARABIAN OIL CO 摘要:Methods are disclosed for synthesizing materials, including an initial synthesis in the presence of WS-ODSO (which can include a pH-modified WS-ODSO composition, in certain embodiments a neutralized WS-ODSO composition), and one or more subsequent syntheses using supernatant (“mother liquorâ€?) from a previous synthesis of the same or different materials. The synthesized materials in the initial synthesis and in subsequent synthesis can be the same or different inorganic oxide materials including amorphous oxides, crystalline oxides or oxides of metals. The methods advantageously reduce the amount of utility water required for synthesizing a material and reduce the water waste, and reduce the DSO waste from a refinery and discharge into the environment. In certain embodiments the methods reduce the requirements to procure an alkaline reagent required for synthesizing materials. In certain embodiments, supernatant can be recycled over multiple synthesis batches of the same or different type of materia.
专利号:US-2010102700-A1 优先权日:2008-10-24 标题:Flame spray pyrolysis with versatile precursors for metal oxide nanoparticle synthesis and applications of submicron inorganic oxide compositions for transparent electrodes 发明人:JAISWAL ABHISHEK; ERNST FRANK O; CHIRUVOLU SHIVKUMAR; LEE JIA X; BUCHEL ROBERT; PRATSINIS SOTIRIS E 权利人:JAISWAL ABHISHEK; ERNST FRANK O; CHIRUVOLU SHIVKUMAR; LEE JIA X; BUCHEL ROBERT; PRATSINIS SOTIRIS E 摘要:Flame spray pyrolysis can be performed using aqueous solvents for the delivery of metal and/or metalloid oxide precursors while obtaining desirably high flame temperatures for the synthesis of uniform submicron inorganic oxide particles. A multiple liquid channel nozzle can be used to deliver liquid for the formation of the aerosol that is combusted in the flame. One or both channels can deliver liquid with metal/metalloid precursors and/or organic fuels. Flame spray pyrolysis can be used to form metal tungsten oxide submicron particles. Metal tungsten oxide compositions can be used in the formation of transparent electrodes. If the transparent electrodes are formed from polymer inorganic particle composites, the composites can further comprise electrically conductive nanoparticles to improve the electrical conductivity.
专利号:US-6409851-B1 优先权日:1996-11-04 标题 :Microwave plasma chemical synthesis of ultrafine powders 发明人:SETHURAM KRUPASHANKARA M; KALYANARAMAN RAJA 权利人:MATERIALS MODIFCIATION INC 摘要:The present invention relates to the production of ultrafine powders using a microwave plasma apparatus and chemical synthesis technique. Microwaves generated by a magnetron ( 1 ) are passed through waveguides ( 2 ) before they arrive at the head of a plasmatron ( 3 ). These high energy microwaves ionize a plasma gas, thus releasing large amounts of energy. The energy thus released is utilized to initiate and sustain chemical reactions between the desired elements being pumped in a spiral pattern into the plasmatron ( 3 ). The reaction products are quenched rapidly in a reactor column ( 4 ) into ultrafine powders.
专利号:US-7722851-B2 优先权日:2001-12-10 标题 :Bulk synthesis of carbon nanotubes from metallic and ethynyl compounds 发明人:KELLER TEDDY M; QADRI SYED B 权利人:US NAVY 摘要:A process of making carbon nanotubes comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or solid at room temperature; and heating the precursor composition under conditions effective to produce carbon nanotubes. A carbon nanotube composition comprising carbon nanotubes and a metal component selected from the group consisting of metal nanoparticles and elemental metal; wherein the carbon nanotube composition is rigid.
专利号:US-9303046-B2 优先权日:2012-08-07 标 题:Process for the preparation of heterocyclic ester derivatives 发明人:BONGARTZ JEAN-PIERRE ANDRÉ MARC; STAPPERS ALFRED ELISABETH; TELEHA CHRISTOPHER A; WEERTS KOEN JOHAN HERMAN; WILSON KENNETH J 权利人:JANSSEN PHARMACEUTICA NV 摘要:The present invention is directed to a process for the preparation of heterocyclic ester derivatives of formula I n nwherein A 1 , SEM, and W 1 are as defined herein. Such compounds are useful as intermediates in the synthesis of derivatives useful as protein tyrosine kinase inhibitors, more particularly inhibitors of c-fms kinase.
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合成参考文献
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 753. 摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1426. 摘要:Ogasawara, M., Science of Synthesis, (2008) 44, 59. 摘要:Aguilar, E.; López, L. A., Science of Synthesis Knowledge Updates, (2014) 2, 2. 摘要:Luh, T.-Y.; Leung, M.-k., Science of Synthesis Knowledge Updates, (2018) 2, 369.