CAS: 10075-62-4; 1,4-Dimethoxynaphthalene

该化合物是一种有机化合物,其特征是:其1和4个位置的两种甲氧基(-OCH3)基质为1和4个位置的氯化萘基质,该化合物一般是白色的,黄色的晶状体结晶,有不同的芳香味,在水中相对不溶,但在乙醇,乙醚和氯仿等有机溶剂中可溶解.存在甲氧基组,会增强其电子施用特性,使其成为有机合成中的有用中间体,并可能成为材料科学和制药中各种应用的候选体.1,4-二甲基氧甲苯可进行典型的芳香反应,包括电用替代和氧化.其化学稳定性和再活性受甲氧基亚体的影响,这可能影响化合物的电子特性和消毒阻力.在处理该物质时,应当采取安全防范措施,因为若吸入或浸入,可能会对健康造成危害.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

methanol 1,4-Dihydroxynaphthalene b]naphthalene4,7-dimethoxy-2a,3,8,8a-tetrahydro-3,8-etheno-cyclobuta[b]naphthalene 2-chloro-5,8-dimethoxy-1,4-dihydro-naphthalene 5,8-dimethoxy-1,4-dihydronaphthalene (S)-1,4-dimethoxy-2-p-tolylsulfinylnaphthalene azulenonaphtho-azulene-7,16-dione6,8,15,16b,16c,17-Hexahydro-5,9,14,18-tetramethoxy-16b,16c-diphenyl-7H,16H-6a,7a,15a,16a-tetraazanaphtho5,6azuleno2,1,8-ijanaphtho-azulene-7,16-dione [1,4]naphthoquinone

合成工艺路线路线简述

    📜1,4-二羟基萘置于potassium Carbonate,硫酸二甲酯体系中,用 水,丙酮 用作溶剂,化学反应生成1,4-二甲氧基萘
    参考文献:Ring-Substituted 2-Amino-1,2,3,4-Tetrahydronaphthalenes
    标题:Ring-Substituted 2-Amino-1,2,3,4-Tetrahydronaphthalenes
    摘要:这项发明提供了环取代的2-氨基-1,2,3,4-四氢萘烯衍生物,它们是选择性的血清素再摄取抑制剂.

    专利信息


    专利号:US-7071145-B2
    优先权日:2001-09-25
    标 题:Thermosensitive recording material, and synthesis method of oligomer composition for the recording material
    发明人:MORITA MITSUNOBU; HAYAKAWA KUNIO; TORII MASAFUMI; NARUSE MITSURU
    权利人:RICOH KK
    摘要:A thermosensitive recording material comprising a thermosensitive layer provided on a substrate, and the thermosensitive layer comprises as main ingredients a leuco dye and a developer to make colored state of said leuco dye when heated, wherein the developer is an oligomer composition obtained from the reaction of a polyvalent isocyanate compound represented by following Formula (I) with an aromatic amine represented by following Formula (II); n nwhere X represents a try- or more-valent group, a represents an integer numeral of 3 or more, b and c represent respectively integer numerals in the range of 0 to 5 and they satisfy a relation of b+c=1 to 5, Z represents hydrogen atom, alkyl group, allyl group or aryl group, and the aryl group may include condensed ling structure thereof, and d represents an integer numeral in the range of 0 to 4. This developer shows excellent reliabilities of both image and background area, and also shows an excellent color-developing characteristics (color developing sensitivity and image density).

    专利号:RU-2014330-C1
    优先权日:1988-05-23
    标题:Method of synthesis of 1,2,3,4-tetrahydronaphthalene derivatives or their pharmaceutically acceptable acid-additive salt

    专利号:US-2003153460-A1
    优先权日:2001-09-25
    标 题:Thermosensitive recording material, and synthesis method of oligomer composition for the recording material

    专利号:US-2005079976-A1
    优先权日:2001-09-25
    标题 :Thermosensitive recording material, and synthesis method of oligomer composition for the recording material

    专利号:US-2004242414-A1
    优先权日:2001-09-25
    标题:Thermosensitive recording material, and synthesis method of oligomer compositon for the recording material

    专利号:US-6878671-B2
    优先权日:2001-09-25
    标题 :Thermosensitive recording material, and synthesis method of oligomer composition for the recording material

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Cécile Pégurier, Et Al. Synthesis Of New Arylalkoxy Amido Derivatives As Melatoninergic Ligands. Bioorg Med Chem. 2003 Mar 6;11(5):789-800.
    [参考文献]: William Williams, Et Al. Synthetic Studies On The Kinamycin Family Of Antibiotics: Synthesis Of 2-(Diazobenzyl)-P-Naphthoquinone, 1,7-Dideoxy-3-Demethylprekinamycin, And 1-Deoxy-3-Demethylprekinamycin. J Org Chem. 1997 Jun 27;62(13):4364-4369.

    合成参考文献


    摘要:Couladouros, E. A.; Strongilos, A. T., Science of Synthesis, (2006) 28, 261.
    摘要:Pfeiffer, W. D., Science of Synthesis, (2007) 35, 409.
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