CAS: 67107-87-3; 12-Amino-1-Dodecanol

该化合物是一种双功能有机化合物,由氨基氨基化合物和12-碳脂链上的氢氧基化合物组成.这一结构使该化合物成为有机合成的多功能中间体,特别是用于制备表面活性剂,腐蚀抑制剂和聚合物修饰剂.其长长的碳氢化合物链具有疏水特性,而极地功能组则在水媒介和有机媒介中增强溶解性和反应性.该化合物还有助于开发特殊化学品,如碳基表面活性剂和染色剂,因为它能够形成稳定的氨化物或酯联系.其平衡的水益性和脂性在需要受控表面活动的配方中具有价值.

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4271-86-7 693-57-2 23160-46-5

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CAS号3344-77-2 12-溴-1-十二烷醇 | CAS号73782-16-8 12-hydroxydodec... | CAS号53005-24-6 methyl 12-amino... | CAS号693-57-2 12-氨基十二酸 | CAS号1611-56-9 11-溴十一醇 | CAS号52162-19-3 ethyl 11-cyanou... | CAS号141546-90-9 6-chloro-N-(12-... | CAS号67341-03-1 12-(t-B°C-amino... | CAS号82583-84-4 2-(12-bromodode...

合成工艺路线路线简述

    📜11-溴-1-十一醇置于sodium Cyanide,Ammonium Hydroxide,氢气体系中,用 乙醇,二甲基亚砜 作为反应溶剂,化学反应 44.0H,反应生成 12-氨基-1-十二烷醇
    参考文献:具有可调节电荷-载流子迁移率的液晶二酯聚合物
    标题:具有可调节电荷-载流子迁移率的液晶二酯聚合物
    摘要:报道了基于per二酯苯并咪唑和per二酰亚胺酰亚胺液晶元的新型液晶半导体聚合物.通过氮氧化物介导的自由基聚合(NMRp)合成了两种高度可溶的侧链聚合物,即聚对苯二甲酸二苯并咪唑丙烯酸酯(ppdb)和聚对苯二甲酸二亚胺酰亚胺丙烯酸酯(ppdi).ppdb通过根据mott-gurney方程拟合空间电荷限制电流(sclc),显示出在二极管配置中获得的电子迁移率为3.2x10-4 Cm 2 V-1 S-1的n型半导体性能.有趣的是,Ppdi优先作为ap型材料,其空穴迁移率为1.5x10-4 Cm 2 V-1 S-1,这归因于与ppdb相比,Ppdi的电子不足的ylene二烯核.通过紫外可见光谱和荧光光谱研究光学性质.与ppdi相比,由于ppdb的苯并咪唑单元而扩展的π共轭体系导致在可见光区域的吸收范围大大扩大.聚合物的homo和lumo含量也通过循环伏安法测定.ppdb的能量带隙为1.86
    DOI:10.1002/adfm.201101694

    海关参考信息

    专利信息


    专利号:US-8877977-B2
    优先权日:2011-11-25
    标题 :Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
    发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
    权利人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO; BASF SE
    摘要:Process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, in which aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas. Polyalkylenepolyamines obtainable by such processes and polyalkylenepolyamines comprising hydroxy groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.

    专利号:WO-2013076053-A1
    优先权日:2011-11-25
    标题:Synthesis of polyalkylene polyamines with low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
    发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
    权利人:BASF SE; STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
    摘要:The invention relates to a method for the production of polyalkylene polyamines by homogeneously catalyzed alcohol amination, wherein aliphatic alkanolamines are reacted with each other or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols in the presence of a homogeneous catalyst while eliminating water and in the presence of hydrogen gas. The invention further relates to polyalkylene polyamines, which can be obtained by said methods, and to polyalkylene polyamines which contain hydroxyl groups, secondary amines or tertiary amines. The invention finally relates to uses of said polyalkylene polyamines as adhesion promoters in inks, adhesion promoters in composite films, cohesion promoters in adhesives, cross-linkers/hardeners for resins, primers for paints, wet adhesion promoters for dispersion paints, complexing agents and flocculants, penetration auxiliaries for use in wood preservation, corrosion inhibitors, and immobilization agents of proteins and enzymes.

    专利号:EP-2782949-A1
    优先权日:2011-11-25
    标题 :Synthesis of polyalkylene polyamines with low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen

    专利号:US-2013137901-A1
    优先权日:2011-11-25
    标题 :Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen

    专利号:WO-2004008550-A2
    优先权日:2002-07-15
    标 题 :Rapid low-temperature synthesis of quantum dots

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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Macrolide Synthesis Through Intramolecular Oxidative Cross-Coupling Of Alkenes
    作者:Bing Jiang,Meng Zhao,Shu-Sen Li,Yun-He Xu,Teck-Peng Loh |发布日期:2018.1.8
    摘要:A Rhiii‐catalyzed Intramolecular Oxidative Cross‐coupling Between Double Bonds For The Synthesis Of Macrolides Is Described. Under The Optimized Reaction Conditions, Macrocycles Containing A Diene Moiety Can Be Formed In Reasonable Yields And With Excellent Chemo‐ And Stereoselectivity. This Method Provides An Efficient Approach To Synthesize Macrocyclic Compounds Containing A 1,3‐conjugated Diene

    合成参考文献


    摘要:Moratti, S. C.; Charalambides, Y. C., Science of Synthesis, (2005) 18, 654.
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