CAS: 615-42-9; 1,2-Diiodobenzene

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CAS号615-43-0 2-碘苯胺 | CAS号88284-48-4 2-(三甲基硅)苯基三氟甲烷磺酸盐 | CAS号591-50-4 碘苯 | CAS号1614-12-6 1-氨基苯并三唑 | CAS号71-43-2 苯 | CAS号118-92-3 邻氨基苯甲酸 | CAS号88-67-5 邻碘苯甲酸 | CAS号95-54-5 邻苯二胺(OPD) | CAS号19591-17-4 N-(2-碘苯基)乙酰胺 | CAS号6247-55-8 2,3-二氢-1,4-苯并二噻嗪 | CAS号100-68-5 茴香硫醚 | CAS号56160-67-9 2-(methylthio)e... | CAS号106139-97-3 1-iodo-2-(2-met... | CAS号110166-78-4 2-hex-1-ynylben... | CAS号5851-43-4 2-异丙基苯并咪唑 | CAS号4387-36-4 2-碘氰基苯 | CAS号91-15-6 邻苯二甲腈 | CAS号59376-64-6 反式-3-(三甲基硅基)烯丙醇

2-碘乙酰苯胺置于亚硝酰氯体系中,用 苯 作为反应溶剂,化学反应生成 1,2-二碘苯
参考文献:从芳香族碘化物中自由基提取碘
标题:从芳香族碘化物中自由基提取碘
摘要:异构的分解ø-,米-,和p-碘ñ-Nitrosoacetanilides苯给予ø-,米-和p-二碘-苯以及预期的2-,3-,和4-Iodobiphenyls,分别.芳酰过氧化物[(arco 2)2的分解在碘苯中,甚至在用苯稀释的碘苯中,芳基碘化物(arl)以及由碘苯均质苯酚化形成的2-,3-和4-碘联苯的异构体混合物,都能得到非常好的收率.这些结果表明由芳基碘化物中的芳基基团非常快速地使碘自由基基团抽象.与芳基溴化物的相应反应没有发生.首次通过涉及亚磷酸三乙酯还原未反应的过氧化物的新途径,首次测量了碘苯中过氧化二苯甲酰的分解动力学,该动力学类似于溴苯中的分解动力学.
DOI:10.1039/j39680000819

专利信息

专利号:EP-2103609-A1
优先权日:2008-03-20
标 题:Catalyzed carbonylation in the synthesis of angiotensin ii antagonists
权利人:LEK PHARMACEUTICALS
摘要:One embodiment disclosed in the invention is the efficient synthesis of halogenated biaryl starting material via Grignard chemistry and the use thereof. Another embodiment of the invention is the reaction of catalyzed carbonylation of the 3'-(2'-halo-biphenyl-4-ylmethyl)-1,7'-dimethyl-2'-propyl-1H,3'H-[2,5']bibenzoimidazolyl (TLMH) using either gaseous carbon monoxide in a solvent mixture containing water; or formic acid salts optionally together with acetic acid in anhydrous solvent.

专利号:US-4788354-A
优先权日:1984-10-16
标 题 :Method for the synthesis of iodobenzene
发明人：PAPARATTO GIUSEPPE; SAETTI MARCO
权利人:MONTEDIPE SPA
摘要:A method for the synthesis of iodobenzene by iodination, in the gaseous phase, of benzene with iodine, in the presence of a zeolitic catalyst, selected from the group comprising the zeolites of X type or of Y type, characterized in that said iodination is an oxidative one and that said zeolites are in a form different from the acid (H) form.

专利号:US-8445693-B2
优先权日:2008-03-20
标 题 :Catalyzed carbonylation in the synthesis of angiotensin II antagonists
发明人：CASAR ZDENKO; COPAR ANTON; CLUZEAU JEROME; PREMRL ANDREJ
权利人:CASAR ZDENKO; COPAR ANTON; CLUZEAU JEROME; PREMRL ANDREJ; LEK PHARMACEUTICALS
摘要:One embodiment disclosed in the invention is the efficient synthesis of halogenated biaryl starting material via Grignard chemistry and the use thereof. Another embodiment of the invention is the reaction of catalyzed carbonylation of the 3′-(2′-halo-biphenyl-4-ylmethyl)-1,7′-dimethyl-2′-propyl-1H,3′H-[2,5′]bibenzoimidazolyl (TLMH) using either gaseous carbon monoxide in a solvent mixture containing water; or formic acid salts optionally together with acetic acid in anhydrous solvent.

专利号:US-10487099-B2
优先权日:2017-06-30
标 题:Synthesis of hypervalent iodine reagents with dioxygen
发明人：POWERS DAVID CHARLES; MAITY ASIM; HYUN SUNG-MIN
权利人:TEXAS A & M UNIV SYS
摘要:Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.

专利号:US-5484883-A
优先权日:1990-06-25
标题 :Lithium/HMPA-promoted synthesis of poly(phenylenes)
发明人：TOUR JAMES M; STEPHENS ERIC B
权利人:UNIV SOUTH CAROLINA
摘要:Poly(phenylene) that is substantially free of insoluble material is prepared by the polymerization of a lithioarylhalide compound in the presence of a polar aprotic compound such as hexamethylphosphoramide, N,N,N',N'-tetramethylethylenediamine or hexamethylphosphorous triamide. The preferred reaction involves the polymerization of 1-bromo-4-lithiobenzene in the presence of hexamethylphosphoramide. The 1-bromo-4-1ithiobenzene may be synthesized by reacting 1,4-dibromobenzene with t-butyllithium. These same types of reactions can also be used to synthesis other benzenoid polymers.

专利号:US-10865163-B2
优先权日:2017-12-20
标题:Carbon dioxide as a directing group for C—H functionalization reactions involving Lewis basic amines, alcohols, thiols, and phosphines for the synthesis of compounds
发明人：YOUNG MICHAEL C; KAPOOR MOHIT
权利人:UNIV TOLEDO
摘要:Methods of synthesizing compounds using CO 2 as a directing group for C—H functionalization, and compounds made thereby, are described.