CAS: 89-05-4; 1,2,4,5-Benzenetetracarboxylic Acid

该化合物是一种反应性很强的二恶英酸,用作生产聚酰胺和其他先进的聚合物的中间体,其高反应性能使得与各种二胺的高效反应能够形成高温抗药性材料,而其酸性能则有利于形成非酸性联系.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

2,4,5-trimethylbenzaldehyde tetrachloromethane 4,5-dimethylphthalic anhydride 2,3-dibromo-glutaric acid tetramethyl 1,2,4,5-benzenetetracarboxylate fluorescein Pyromellitic dianhydride benzene-1,2,4,5-tetracarbonyl chloride

合成工艺路线路线简述

  • 合成目标产物 Pyromellitic Acid 主要起始原料 Pyromellitic Dianhydride
  • (文献来源)合成步骤主要原料 Pyromellitic Dianhydride
1,3-二甲基-4-乙基苯置于二硫化碳,三氯化铝,硝酸体系中,化学反应生成 均苯四甲酸
参考文献:Philippi,Justus Liebigs Annalen Der Chemie,1922,Vol. 428,P. 304
标题:Philippi,Justus Liebigs Annalen Der Chemie,1922,Vol. 428,P. 304

海关参考信息

专利信息


专利号:US-4895922-A
优先权日:1988-05-05
标 题 :Low temperature synthesis of polyesteramides
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention disclosed a process for the synthesis of polyesteramides. By utilizing the phosphorus containing catalyst systems of the present invention, such polyesteramides can be synthesized at relatively low temperatures. The present invention specifically discloses a process for the synthesis of a polyesteramide which comprises polymerizing at least one diamine, at least one diol, and at least one dicarboxylic acid in the presence of (1) at least one acid acceptor; (2) at least one halogenated organic compound; and (3) at least one phosphorus containing compound selected from the group consisting of (a) triphenylphosphine, (b) triphenylphosphine oxide, (c) triphenylphosphine sulfide, (d) polymeric agents having pendant diphenylphosphine groups, (e) silicon-phosphorus compositions which contain at least one divalent oxygen atom which is bonded directly to a tetravalent silicon atom and a trivalent or pentavalent phosphorus atom; (f) compounds with the structural formula (C 6 H 5 ) 3 P=N-R, wherein R is a hydrogen atom or an alkyl group containing from 1 to 10 carbon atoms; and (g) compounds with the structural formula (C 6 H 5 )PR 1 R 2 wherein R 1 and R 2 can be the same or different, wherein R 1 is selected from the group consisting of alkyl groups containing from 1 to 10 carbon atoms and phenyl groups, and wherein R 2 is an alkyl group containing from 1 to 10 carbon atoms.

专利号:US-12146136-B2
优先权日:2020-03-26
标题:Synthesis of modified oligonucleotides with increased stability
发明人:KHVOROVA ANASTASIA; ROUX LOà C MAURICE RENÉ JEAN; YAMADA KEN
权利人:UNIV MASSACHUSETTS
摘要:This disclosure relates to the synthesis of novel modified oligonucleotides. The synthesis of novel phosphoramidites are also provided.

专利号:US-11780952-B2
优先权日:2016-08-08
标题:Process for the synthesis of silylated polyurethanes and silylated polyurethane composition
发明人:LAFERTE OLIVIER
权利人:BOSTIK SA
摘要:The present invention provides a process for the synthesis of silylated polyurethanes, comprising three sequential steps, a step (i) of preparing NCO-terminated polyurethane, a step (ii) of partial grafting of the NCO functions with silane functions and a step (iii) of total grafting of the residual NCO functions with functions that react with the NCO functions by means of polyfunctional compounds. The present invention also provides a silylated polyurethane composition that can be obtained by means of the process according to the invention, an adhesive composition comprising said silylated polyurethane composition and a self-adhesive item obtained from the adhesive composition according to the invention.

专利号:US-4843053-A
优先权日:1987-02-05
标 题 :Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4996178-A
优先权日:1987-02-05
标题 :Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-12145127-B2
优先权日:2017-03-23
标 题 :Porous co-polymeric gel compositions, porous carbon compositions, and methods for synthesis thereof
发明人:LEVENTIS NICHOLAS; SOTIRIOU-LEVENTIS CHARIKLIA; SAEED MALIK ADNAN
权利人:ASPEN AEROGELS INC
摘要:The present invention discloses novel porous polymeric compositions comprising random copolymers of amides, imides, ureas, and carbamic-anhydrides, useful for the synthesis of monolithic bimodal microporous/macroporous carbon aerogels. It also discloses methods for producing said microporous/macroporous carbon aerogels by the reaction of a polyisocyanate compound and a polycarboxylic acid compound, followed by pyrolytic carbonization, and by reactive etching with CO2 at elevated temperatures. Also disclosed are methods for using the microporous/macroporous carbon aerogels in the selective capture and sequestration of carbon dioxide.
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合成参考文献

参考DOI号:10.1021/jo00158a020
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