CAS: 6917-76-6; Chlorodimethylethylsilane

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CAS号2344-80-1 氯甲基三甲基硅烷 | CAS号1066-35-9 二甲基一氯硅烷 | CAS号54509-73-8 ethene | CAS号925-90-6 乙基溴化镁 | CAS号75-78-5 二甲基二氯硅烷 | CAS号1719-58-0 二甲基乙烯基氯硅烷 | CAS号75-76-3 四甲基硅烷 | CAS号1719-57-9 氯甲基二甲基氯硅烷 | CAS号75-00-3 氯乙烷 | CAS号3439-38-1 乙基三甲基硅烷 | CAS号10132-71-5 Ethylfluorodime... | CAS号18036-81-2 Benzene,1-(trim... | CAS号18415-47-9 ethyl-[4-(ethyl... | CAS号3439-38-1 乙基三甲基硅烷 | CAS号758-21-4 二甲基乙基硅烷 | CAS号1529-17-5 三甲基苯氧基硅 | CAS号2295-17-2 1,3-二乙基-1,1,3,3... | CAS号756-81-0 二甲基二乙基硅烷 | CAS号67176-41-4 2-tert-butylper... | CAS号5906-73-0 ethyl-hydroxy-d...

📜氯甲基三甲基硅烷置于三氯化铝体系中,用 二氯甲烷 作为反应溶剂,化学反应生成 乙基二甲基氯硅烷
参考文献:有机硅化合物的重排i.氯化铝催化的(氯甲基)三有机硅烷的重排中各种有机基团的迁移能力
标题:有机硅化合物的重排i.氯化铝催化的(氯甲基)三有机硅烷的重排中各种有机基团的迁移能力
摘要:已经确定了氯化铝催化的(氯甲基)三有机硅烷的各种有机基团的迁移能力:Me,1.00; Me,1.00; Me,1.00; Me,1.00; Me,1.00.等等,2.07;n-Pr 2.97;iso-Pr约1.00; Clch 2约1.00.电子释放促进了有机基团从硅向碳的迁移,并且相对于甲基,有机基团在α-碳上的分支被抑制了.根据涉及有机基团和氯离子的同步分子内迁移的机理,讨论了本研究中确定的和其他工作人员获得的迁徙倾向.
DOI:10.1016/s0022-328X(00)91311-1

专利信息

专利号:US-6756199-B1
优先权日:1994-02-23
标题:Peptide nucleic acid combinatorial libraries and improved methods of synthesis
发明人：COOK PHILLIP DAN; KIELY JOHN; SPRANKLE KELLY
权利人:ISIS PHARMACEUTICALS INC
摘要:New sub-monomer synthetic methods for the preparation of peptide nucleic acid oligomeric structures are disclosed that provide for the synthesis of both predefined sequence peptide nucleic acid oligomers as well as random sequence peptide nucleic acid oligomers. Further these methods also provide for the incorporation of peptide nucleic acid units or strings of such units with amino acids or strings of amino acids in chimeric peptide nucleic acid-amino acid compounds. Further disclosed are method of making random libraries of peptide nucleic acids using the fully preformed monomers. Chimeric oligomers and libraries of the same are also disclosed.

专利号:US-11033507-B2
优先权日:2013-12-19
标 题 :Method of synthesis of silica vesicles and use thereof
发明人：YU CHENGZHONG; MITTER NEENA; ZHANG JUN
权利人:UNIV QUEENSLAND
摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.

专利号:US-5538618-A
优先权日:1993-06-17
标 题:Process for the electrochemical synthesis of organosilicon compounds, and an appliance for carrying out the process, and use thereof for preparing organosilicon compounds
发明人：HENGGE EDWIN; JAMMEGG CHRISTA; KALCHAUER WILFRIED
权利人:WACKER CHEMIE GMBH
摘要:A process is described for the electrochemical preparation of organosilicon compounds having at least one SiC-bound organic radical, a solution which contains at least one halosilane being subjected to an electrochemical reaction, an anode which contains a noble metal or an alloy consisting essentially of one or more noble metals having a halogen scavenger flowing around said anode.

专利号:US-7951895-B2
优先权日:2005-12-23
标题 :Process for preparing a silicone resin
发明人：RAMDANI KAMEL; BOSSY HELENE; LOMEL SEBASTIEN; DURAND NICOLAS
权利人:BLUESTAR SILICONES FRANCE
摘要:The invention relates to, and the general field of the invention is that of, the synthesis of silicone resins, more particularly the synthesis of silicone resins of type MQ. The process relates to the preparation of MQ silicone resins and permits better control of the operating conditions in the step of the polymerization of a sodium silicate (B) in aqueous medium in the presence of an acid (C) to form a silica hydrosol (polysilicic acid). In the course of the polycondensation step the reactants, a sodium silicate and an acid, are mixed, preferably in continuous fashion, dynamically to form a mixture ( 3 ), by means of at least one intensive mixing tool (M) producing a power ε per unit volume of more than 10 kW/m 3 .

专利号:WO-2010113188-A1
优先权日:2009-03-31
标题 :Fluorurated siliconic polymer, synthesis method and use
发明人：CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
权利人:MAFLON S R L; CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
摘要:The present invention relates to a fluorurated siliconic polymer with controlled molecular weight and viscosity having a structure composed by means of the chaining of oligo-dialkylsiloxane building-blocks having a limited and selected molecular weight and alternated mainly with siloxane units containing a fluorurated substituent and - to a marginal degree - inert siloxane units or substituted by unsaturated groups. When the latter are present -they are used for subsequent reactions of clamping or cross-linking. The present invention relates, moreover, to a synthesis method of the mentioned polymer and its use.

专利号:US-2022355262-A1
优先权日:2019-07-22
标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites
发明人：SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI
权利人:KROSSLINKER PTE LTD
摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.