CAS: 636-09-9; Diethyl Terephthalate

该化合物是一种有机化合物,属于来自磷酸酯酯的酯类,其特性为无色,室温粘性液体形式,有略微甜的气味.二乙烯丙二甲酸在乙醇和丙酮等有机溶剂中可溶解,但在水中溶解性有限.该化合物主要用作生产聚酯纤维和树脂的中间体,在纺织和塑料工业中具有显著作用.它具有良好的热稳定性和对水解的抗药性等特性,有助于其在各种应用中发挥作用.此外,二乙酸戊丙烯酸盐可产生转基因反应,使其成为合成其他化学化合物的宝贵前体.安全数据表明,应谨慎处理该物质,因为它在与皮肤或眼睛接触时可能会引起刺激,并应在通风良好的地区使用,以避免吸入蒸气.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

1,4-benzenedicarboxylic acid dimethyl ester ethanol potassium ethoxide 1,4-Diacetylbenzene4-(benzothiazol-2-yl-acetyl)-benzoic acid ethyl ester Terephthalic acid bis-N-(2-hydroxyethyl)amide 1,4-Diacetylbenzene 1,1'-(1,4-phenylene)bis(butane-1,3-dione)

合成工艺路线路线简述

    📜对苯二甲酸置于盐酸体系中,用 乙醇,水 作为反应溶剂,化学反应生成 对苯二甲酸二乙酯
    参考文献:Tetralin Esters Of Phenols Or Benzoic Acids Having Retinoid Like Activity
    标题:Tetralin Esters Of Phenols Or Benzoic Acids Having Retinoid Like Activity
    摘要:该公式中化合物展现出类似视黄醇的活性,其中r基可以独立地是氢或较低烷基;a是--C(O)O--,--oc(O)--,--C(O)S--或--Sc(O)--;n为0-5;z是h,--Cob,其中b为--Oh或药用可接受的盐,或者b为--Or.Sub.1,其中r.Sub.1是酯形成基团,或者b为--N(R).Sub.2,其中r为氢或较低烷基,或z为--Oe,其中e为氢或醚形成基团,或--Cor.Sub.2,其中r.Sub.2为氢,较低烷基,苯基或较低烷基苯基,或者z为--Cho或其缩醛衍生物,或者z为--Cor.Sub.3,其中r.Sub.3为--(Ch.Sub.2).Sub.M Ch.Sub.3,其中m为0-4,且n和m的总和不超过4.

    海关参考信息

    专利信息


    专利号:US-11548898-B2
    优先权日:2017-07-06
    标题 :Synthesis of halichondrins
    发明人:KISHI YOSHITO; AI YANRAN; YE NING; WANG QIAOYI; YAHATA KENZO; ISO Kentaro; NAINI SANTHOSH REDDY; YAMASHITA SHUJI; LEE JIHOON; OHASHI ISAO; FUKUYAMA TAKASHI
    权利人:HARVARD COLLEGE; EISAI R&D MAN CO LTD
    摘要:The present invention provides methods for the synthesis of ketones involving a Ni/Zr-mediated coupling reaction. The Ni/Zr-mediated ketolization reactions can be used in the synthesis of halichondrins (e.g., halichondrin A, B, C; homohalichondrin A, B, C; norhalichondrin A, B, C), and analogs thereof. Therefore, the present invention also provides synthetic methods useful for the synthesis of halichondrins, and analogs thereof. Also provided herein are compounds (i.e., intermediates) useful in the synthesis of halichondrins, and analogs thereof. In particular, the present invention provides methods and compounds useful in the synthesis of compound of Formula (H3-A).

    专利号:US-5869543-A
    优先权日:1996-10-22
    标题:Process for the synthesis of polyethylene carboxylate from polyethylene carboxylate waste
    发明人:BOOS FRANK; SCHNITTKER NORMAN; SEELIG JOACHIM
    权利人:ZIMMER AG
    摘要:The invention comprises a method for synthesizing polyethylene terephthalate from waste polyethylene terephthalate by cleavage with ethylene glycol and separation of bis(hydroxyethylene) terephthalate from the cleavage mixture with a specific temperature program, recrystallization from water, and esterification and polycondensation with the addition of terephthalic acid. n The invention further comprises a method for synthesis of polyethylene naphthalate from waste polyethylene naphthalate in a similar manner.

    专利号:US-3891594-A
    优先权日:1972-04-07
    标题:Direct synthesis of composite materials
    发明人:TAYLOR LYNN J
    权利人:TAYLOR LYNN J
    摘要:There is disclosed an in situ process for the preparation of a composite material consisting essentially of an organic polymer or copolymer having dispersed therein an inorganic oxide or mixture of oxides, said process comprising the simultaneous or sequential synthesis of the organic polymer from at least one non-polymeric organic precursor and of the inorganic oxide or oxide mixture derived from at least one inorganic-oxide precursor.

    专利号:US-3817911-A
    优先权日:1972-04-07
    标 题 :Direct synthesis of composite materials
    发明人:TAYLOR L
    权利人:TAYLOR L
    摘要:THERE IS DISCLOSED AN IN SITU PROCESS FOR THE PREPARATION OF A COMPOSITE MATERIAL CONSISTING ESSENTIALLY OF AN ORGANIC POLYMER OR COPOLYMER HAVING DISPERSED THEREI AN INORGANIC OXIDE OR MIXTURE OF OXIDES, SAID PROCESS COMPRISING THE SIMULTANEOUS OR SEQUENTIAL SYNTHESIS OF THE ORGANIC POLYMER FROM AT LEAST ONE NON-POLYMERIC ORGANIC PRECUROR AND OF THE INORGANIC OXIDE OR OXIDE MIXTURE DERIVED FROM AT LEAST ONE INORGANIC-OXIDE PRECURSOR.

    专利号:US-3960805-A
    优先权日:1974-04-19
    标 题:Direct synthesis of organic polymer-inorganic oxide composites
    发明人:TAYLOR LYNN JOHNSTON
    权利人:TAYLOR LYNN JOHNSTON
    摘要:There is disclosed an in situ process for the preparation of a composite material consisting essentially of an organic polymer or copolymer having dispersed therein an inorganic oxide or mixture of oxides, said process comprising the simultaneous or sequential synthesis of the organic polymer from at least one non-polymeric organic precursor and of the inorganic oxide or oxide mixture derived from at least one inorganic-oxide precursor.

    专利号:US-2010055750-A1
    优先权日:2008-09-03
    标 题:Polyester synthesis
    发明人:WOSNICK JORDAN H
    权利人:XEROX CORP
    摘要:The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners. In embodiments, crystalline copolymers, which are polyesters, may be synthesized from lactones, cyclic anhydrides, cyclic carbonates, and combinations thereof. These crystalline copolymers, in turn, may be utilized in the synthesis of toner particles.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Liu J, Xu G, Dong W, Xu N, Xin F, Ma J, Fang Y, Zhou J, Jiang M. Biodegradation of diethyl terephthalate (DET) and polyethylene terephthalate (PET) by a novel identified degrader Delftia sp. WL-3 and its proposed metabolic pathway. Lett Appl Microbiol. 2018 Jun 1. doi: 10.1111/lam.13014. [Epub ahead of print] doi: 10.1016/j.ecoenv.2016.08.028. Epub 2016 Sep 10. doi: 10.1002/anie.201509149. Epub 2015 Nov 23. doi: 10.1021/jf3047847. Epub 2013 Feb 5. Spectrochim Acta A Mol Biomol Spectrosc. 2004 Jul;60(8-9):2171-80.

    合成参考文献


    摘要:Satoh, T.; Miura, M., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 202.
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