📜对苯二甲酸置于盐酸体系中,用 乙醇,水 作为反应溶剂,化学反应生成 对苯二甲酸二乙酯 参考文献:Tetralin Esters Of Phenols Or Benzoic Acids Having Retinoid Like Activity 标题:Tetralin Esters Of Phenols Or Benzoic Acids Having Retinoid Like Activity 摘要:该公式中化合物展现出类似视黄醇的活性,其中r基可以独立地是氢或较低烷基;a是--C(O)O--,--oc(O)--,--C(O)S--或--Sc(O)--;n为0-5;z是h,--Cob,其中b为--Oh或药用可接受的盐,或者b为--Or.Sub.1,其中r.Sub.1是酯形成基团,或者b为--N(R).Sub.2,其中r为氢或较低烷基,或z为--Oe,其中e为氢或醚形成基团,或--Cor.Sub.2,其中r.Sub.2为氢,较低烷基,苯基或较低烷基苯基,或者z为--Cho或其缩醛衍生物,或者z为--Cor.Sub.3,其中r.Sub.3为--(Ch.Sub.2).Sub.M Ch.Sub.3,其中m为0-4,且n和m的总和不超过4.
专利号:US-11548898-B2 优先权日:2017-07-06 标题 :Synthesis of halichondrins 发明人:KISHI YOSHITO; AI YANRAN; YE NING; WANG QIAOYI; YAHATA KENZO; ISO Kentaro; NAINI SANTHOSH REDDY; YAMASHITA SHUJI; LEE JIHOON; OHASHI ISAO; FUKUYAMA TAKASHI 权利人:HARVARD COLLEGE; EISAI R&D MAN CO LTD 摘要:The present invention provides methods for the synthesis of ketones involving a Ni/Zr-mediated coupling reaction. The Ni/Zr-mediated ketolization reactions can be used in the synthesis of halichondrins (e.g., halichondrin A, B, C; homohalichondrin A, B, C; norhalichondrin A, B, C), and analogs thereof. Therefore, the present invention also provides synthetic methods useful for the synthesis of halichondrins, and analogs thereof. Also provided herein are compounds (i.e., intermediates) useful in the synthesis of halichondrins, and analogs thereof. In particular, the present invention provides methods and compounds useful in the synthesis of compound of Formula (H3-A).
专利号:US-5869543-A 优先权日:1996-10-22 标题:Process for the synthesis of polyethylene carboxylate from polyethylene carboxylate waste 发明人:BOOS FRANK; SCHNITTKER NORMAN; SEELIG JOACHIM 权利人:ZIMMER AG 摘要:The invention comprises a method for synthesizing polyethylene terephthalate from waste polyethylene terephthalate by cleavage with ethylene glycol and separation of bis(hydroxyethylene) terephthalate from the cleavage mixture with a specific temperature program, recrystallization from water, and esterification and polycondensation with the addition of terephthalic acid. n The invention further comprises a method for synthesis of polyethylene naphthalate from waste polyethylene naphthalate in a similar manner.
专利号:US-3891594-A 优先权日:1972-04-07 标题:Direct synthesis of composite materials 发明人:TAYLOR LYNN J 权利人:TAYLOR LYNN J 摘要:There is disclosed an in situ process for the preparation of a composite material consisting essentially of an organic polymer or copolymer having dispersed therein an inorganic oxide or mixture of oxides, said process comprising the simultaneous or sequential synthesis of the organic polymer from at least one non-polymeric organic precursor and of the inorganic oxide or oxide mixture derived from at least one inorganic-oxide precursor.
专利号:US-3817911-A 优先权日:1972-04-07 标 题 :Direct synthesis of composite materials 发明人:TAYLOR L 权利人:TAYLOR L 摘要:THERE IS DISCLOSED AN IN SITU PROCESS FOR THE PREPARATION OF A COMPOSITE MATERIAL CONSISTING ESSENTIALLY OF AN ORGANIC POLYMER OR COPOLYMER HAVING DISPERSED THEREI AN INORGANIC OXIDE OR MIXTURE OF OXIDES, SAID PROCESS COMPRISING THE SIMULTANEOUS OR SEQUENTIAL SYNTHESIS OF THE ORGANIC POLYMER FROM AT LEAST ONE NON-POLYMERIC ORGANIC PRECUROR AND OF THE INORGANIC OXIDE OR OXIDE MIXTURE DERIVED FROM AT LEAST ONE INORGANIC-OXIDE PRECURSOR.
专利号:US-3960805-A 优先权日:1974-04-19 标 题:Direct synthesis of organic polymer-inorganic oxide composites 发明人:TAYLOR LYNN JOHNSTON 权利人:TAYLOR LYNN JOHNSTON 摘要:There is disclosed an in situ process for the preparation of a composite material consisting essentially of an organic polymer or copolymer having dispersed therein an inorganic oxide or mixture of oxides, said process comprising the simultaneous or sequential synthesis of the organic polymer from at least one non-polymeric organic precursor and of the inorganic oxide or oxide mixture derived from at least one inorganic-oxide precursor.
专利号:US-2010055750-A1 优先权日:2008-09-03 标 题:Polyester synthesis 发明人:WOSNICK JORDAN H 权利人:XEROX CORP 摘要:The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners. In embodiments, crystalline copolymers, which are polyesters, may be synthesized from lactones, cyclic anhydrides, cyclic carbonates, and combinations thereof. These crystalline copolymers, in turn, may be utilized in the synthesis of toner particles.
1: Liu J, Xu G, Dong W, Xu N, Xin F, Ma J, Fang Y, Zhou J, Jiang M. Biodegradation of diethyl terephthalate (DET) and polyethylene terephthalate (PET) by a novel identified degrader Delftia sp. WL-3 and its proposed metabolic pathway. Lett Appl Microbiol. 2018 Jun 1. doi: 10.1111/lam.13014. [Epub ahead of print] doi: 10.1016/j.ecoenv.2016.08.028. Epub 2016 Sep 10. doi: 10.1002/anie.201509149. Epub 2015 Nov 23. doi: 10.1021/jf3047847. Epub 2013 Feb 5. Spectrochim Acta A Mol Biomol Spectrosc. 2004 Jul;60(8-9):2171-80.
合成参考文献
摘要:Satoh, T.; Miura, M., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 202.