CAS: 3634-67-1; Chlorotrihexylsilane

该化合物是有机硅化合物,其特点是存在三氟基硅原子,三氟基和一氯原子;该化合物一般看起来无色,是黄色的,由于碳氢化合物链长,其疏水特性为人所知;氯三氟己基硅烷经常用作硅合金剂,加强无机材料和有机聚合物之间的粘合;其再活性主要归因于氯原子,可水解成硅醇组,便利与表面的结合;此外,该化合物可参与各种化学反应,包括交叉连接和聚合过程;该化合物一般会受到谨慎处理,因为接触时可能会对健康造成危害,因此需要在使用过程中采取适当的安全措施;

结构式图片

相似化合物

995-45-9 995-25-5 3634-59-1

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

n-hexylmagnesium bromide tri-n-hexylsilane tetrachlorosilane 1-bromo-hexane71H94N5O18PSiC71H94N5O18PSi 71H95N4O16PSiC71H95N4O16PSi (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]trihexylsilane [[5,15-bis(4-allyloxyphenyl)-10-ethynyl-20-(trihexylsilyl)ethynyl]-21H,23H-porphinato]zinc

合成工艺路线路线简述

    三正己硅烷置于二氯甲烷,溶剂红 43体系中,化学反应 60.0H,以99%的收率获得氯三己基硅烷
    参考文献:用二氯甲烷对中性曙红-Y-光催化硅烷氯化.
    标题:用二氯甲烷对中性曙红-Y-光催化硅烷氯化.
    摘要:氯硅烷是有机合成和材料科学中的多功能试剂.现在报道了在中性曙红y作为氢原子转移光催化剂和二氯甲烷作为氯化剂的情况下,在可见光照射下氢硅烷定量转化为甲硅烷基氯的温和途径.在连续流微管反应器的辅助下,以高度选择性的方式实现了二氢硅烷和三氢硅烷的逐步氯化.使用曙红y促进的通过光催化si-H活化来获得甲硅烷基的能力为以方便和绿色的方式合成有价值的硅试剂提供了新的视角.
    Doi:10.1002/anie.201908556

    海关参考信息

    专利信息


    专利号:US-5455367-A
    优先权日:1993-04-22
    标 题:Method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides
    发明人:KLEIN KLAUS-DIETER; KNOTT WILFRIED; KOERNER GOETZ
    权利人:GOLDSCHMIDT AG TH
    摘要:A method for the synthesis of silanes or organosilicon hydrides by the reduction of the corresponding silicon halides or organosilicon halides with a magnesium hydride in a liquid reaction medium is carried out by utilizing the following distinguishing features: n a) the use of non-pyrophoric, preferably autocatalytically produced, storage magnesium hydride as magnesium hydride, n b) the use of conventional ethers as reaction medium, and n c) the continuous removal of the magnesium halide formed being deposited on the surface of the magnesium hydride particles during the reaction by the action of mechanical energy or ultrasound so as to form a fresh surface.

    专利号:US-2024010511-A1
    优先权日:2019-05-02
    标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion
    发明人:SAHI SUNIL
    权利人:SOLGO INC; SOLGRO INC
    摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.

    专利号:US-5665882-A
    优先权日:1994-03-14
    标题 :Pyridyl ethylation of lactams
    发明人:CHUNG JOHN Y L; ZHAO DALIAN; MCNAMARA JAMES M; HUGHES DAVID L
    权利人:MERCK & CO INC
    摘要:PCT No. PCT/US94/12671 Sec. 371 Date Aug. 29, 1996 Sec. 102(e) Date Aug. 29, 1996 PCT Filed Nov. 7, 1994 PCT Pub. No. WO95/25101 PCT Pub. Date Sep. 21, 1995The invention is a highly efficient synthesis for making compounds of formula: wherein n=0, 1, R is C1-4 alkyl or benzyl; and R1, when present, is C1-4 alkyl, OH, O-C1-4 alkyl or S-C1-4 alkyl. The process involves silane-mediated conjugation of 4-vinylpyridine to a substituted lactam.

    专利号:US-5202444-A
    优先权日:1990-11-27
    标题:Optically isomeric inositol and process for making optically active compound
    发明人:OZAKI SHOICHIRO; AKIYAMA TAKAHIKO; KAGEYAMA KUNIO; MACHIDA MORIHISA
    权利人:YOKOHAMA RUBBER CO LTD
    摘要:Optically active diols and hydroxycarboxylic acids and their esters are produced by deriving 1L-1,2:5,6-di-O-cyclohexylidene-chiro-inositol from 1L-chiro-inositol as an asymmetric source, followed by introduction of a selected class of sterically hindering and asymmetrically reactive groups into the first-mentioned compound and by subsequent reduction of the resulting compound. Seven specific inositols are also derivable from synthesis of those ultimate compounds.

    专利号:US-2025084108-A1
    优先权日:2021-12-30
    标题:Silylating grafting agents, polymers grafted therewith and methods of synthesis
    发明人:TAMANG SEM; CHISHOLM BRET J
    权利人:BRIDGESTONE CORP
    摘要:Silylating grafting agents and methods for synthesizing the same. The grafting agents are used to produce functionalized polydiene polymers by modifying the backbone of the polymer. Methods for functionalizing a polydiene post-polymerization using hydrosilylation are described. Hydrosilylation provides an advantage of incorporating multiple functional groups on the backbone of the polymer which lead to improved properties, such as rolling resistance, wet traction and polymer filler interaction.

    专利号:JP-H09124666-A
    优先权日:1995-08-18
    标题 :Synthesis of silyl cyanohydrin
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    合成参考文献


    摘要:Rodríguez-Morgade, M. S.; Torres, T., Science of Synthesis Knowledge Updates, (2017) 2, 116.
    摘要:González-Bello, C., Science of Synthesis Knowledge Updates, (2018) 1, 240.
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