CAS: 20191-75-7; 1-Bromonaphthalen-2-Amine

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4185-55-1 54245-33-9 771-14-2

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📜2-萘胺置于n-溴代丁二酰亚胺(Nbs)体系中,用 乙腈 用作溶剂,以93%的收率获得2-氨基-1-溴萘
参考文献:钯(0)催化的对苯二酚-对映选择性ch芳基化的轴向手性二苯并ze庚酮
标题:钯(0)催化的对苯二酚-对映选择性ch芳基化的轴向手性二苯并ze庚酮
摘要:通过引入靠近手性轴的空间体积,对映体-对映体选择性c-H官能化反应在很大程度上限于联芳基底物的动态动力学拆分.本文报道的是一种高度阻转对映体选择性钯(0)催化的方法,该方法在ch功能化过程中形成了手性轴,从而能够合成轴向手性二苯并ze庚酮.计算研究支持实验确定的消旋化障碍,同时也表明通过对映确定cmd产生构型稳定的八元palladacycles来进行ch功能化.
Doi:10.1002/anie.201806527

专利信息

专利号:US-10836774-B2
优先权日:2016-11-30
标题 :Methods for making bacteriochlorin macrocycles comprising an annulated isocyclic ring and related compounds
发明人：LINDSEY JONATHAN S; ZHANG SHAOFEI
权利人:UNIV NORTH CAROLINA STATE
摘要:Described herein are bacteriochlorins comprising an annulated isocyclic ring such as a compound Formula I: n nor a metal conjugate thereof, wherein: R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , and Z are each as defined herein. Also described are methods and intermediates for the synthesis of bacteriochlorins comprising an annulated isocyclic ring, and methods of using such bacteriochlorins for, among other things, diagnostic and therapeutic purposes such as, e.g., luminescent compounds in flow cytometry, and/or as active agents in photodynamic therapy (PDT).

专利号:CN-119241488-A
优先权日:2024-10-31
标题 :Synthesis method of spirofluorene compound for OLED