CAS: 90-74-4; Rutinose

该化合物是一个由两个糖单位组成的分离体: 甘蔗和葡萄糖; 一种在各种植物中经常发现的自然产生的化合物,尤其是与菜菜类有关的化合物,作为甘蓝成分; 鲁蒂诺斯具有甜味,在水中溶解,这使其在食品和药物应用中都具有相关性; 鲁蒂诺斯结构具有甘蔗和葡萄糖两个单位之间的一种晶体系联系,有助于其生物系统的稳定性和功能; 它在某些菜类的代谢中发挥作用,提高了它们的溶性与生物利用率; 此外, 鲁蒂诺斯可能具有抗氧化性特性,有助于植物衍生食品的消费带来的健康惠益; 它存在于各种草药补救和饮食补充中,突出了其在传统医药和现代卫生实践中的重要性. 总的来说, 鲁蒂诺斯是一个重要的碳水化合物,在营养和药理学中具有多种用途.

结构式图片

相似化合物

63-42-3 66009-10-7 34980-39-7

物理性质

MSDS等安全信息

合成工艺路线路线简述

  • 153-18-4 = 90-74-4
    反应条件:1.1 Solvents: Water; Rt; 12 H,Rt
    标题:Syntheses Of R-β-Rutinosides By Rutin-Degrading Reaction
    作者:Zhou,Le; Lu,Chao; Wang,Gai-Ling; Geng,Hui-Ling; Yang,Jian-Wu; Et Al
    参考文献:Journal Of Asian Natural Products Research 日期:2009 卷标:11(1) 页码:18-23]

    88510-08-1 = 90-74-4
    反应条件:1.1 Catalysts: Glucosidase,β- Solvents: Ethanol,Water; > 2 H,30 °C
    标题:α-Rhamnosyl-β-Glucosidase-Catalyzed Reactions For Analysis And Biotransformations Of Plant-Based Foods
    作者:Minig,Marisol; Mazzaferro,Laura S.; Erra-Balsells,Rosa; Petroselli,Gabriela; Breccia,Javier D.
    参考文献:Journal Of Agricultural And Food Chemistry 日期:2011 卷标:59(20) 页码:11238-11243]

    153-18-4 = 90-74-4
    反应条件:1.1 Catalysts: Rutinosidase Solvents: Water; 4 H,Ph 5.0,4 °C
    标题:Immobilization Of Flavonol 3-O-β-Heterodisaccharidase On Porous Glass And Production Of Rutinose From Rutin
    作者:Coniglio,Marcela; Kreis,Wolfgang
    参考文献:Planta Medica 日期:2009 卷标:75(13) 页码:1459-1461]

    50-99-7 + 3615-41-6 = 90-74-4
    反应条件:1.1 Catalysts: α-L-Rhamnosidase; Ph 4,50 °C
    标题:Synthesis Of Rutinosides And Rutinose By Reverse Hydrolysis Catalyzed By Fungal α-L-Rhamnosidases
    作者:Martearena,Maria R.; Daz,Mirta; Ellenrieder,Guillermo
    参考文献:Biocatalysis And Biotransformation 日期:2008 卷标:26(3) 页码:177-185]

    153-18-4 = 90-74-4 + 117-39-5
    反应条件:1.1 Solvents: Dimethyl Sulfoxide,Water; Ph 5,35 °C; 10 Min,100 °C; 24 H,100 °C1.2 Solvents: Water; Ph 3
    标题:α-L-Rhamnosyl-β-D-Glucosidase (Rutinosidase) From Aspergillus Niger: Characterization And Synthetic Potential Of A Novel Diglycosidase
    作者:Simcikova,Daniela; Kotik,Michael; Weignerova,Lenka; Halada,Petr; Pelantova,Helena; Et Al
    参考文献:Advanced Synthesis & Catalysis 日期:2015 卷标:357(1) 页码:107-117]

    153-18-4 = 90-74-4 + 117-39-5
    反应条件:1.1 Solvents: Choline Chloride,Oxalic Acid,Water
    标题:Efficient And Green Strategy Based On Pulsed Electric Field Coupled With Deep Eutectic Solvents For Recovering Flavonoids And Preparing Flavonoid Aglycones From Noni-Processing Wastes
    作者:Li,Jian; Chen,Wen; Niu,Debao; Wang,Rui; Xu,Fei-Yue; Et Al
    参考文献:Journal Of Cleaner Production 日期:2022 卷标:368]

    = 90-74-4 + 106-24-1
    反应条件:1.1 Reagents: Sodium Methoxide Solvents: Methanol
    标题:Unusual Carbonate Formation In Saccharide Synthesis
    作者:Baumes,Raymond L.; Bayonove,Claude L.; Cordonnier,Robert E.; Gunata,Yusuf Z.; Wylde,Renee; Et Al
    参考文献:Carbohydrate Research 日期:1989 卷标:189 页码:331-40]

    520-26-3 + 10236-47-2 = 90-74-4 + 520-33-2 + 480-41-1
    反应条件:1.1 Catalysts: Glucosidase,β- Solvents: Dimethyl Sulfoxide,Water; 90 Min,Ph 5.5,95 °C
    标题:Hydrolysis Of Flavanone Glycosides By β-Glucosidase From Pyrococcus Furiosus And Its Application To The Production Of Flavanone Aglycones From Citrus Extracts
    作者:Shin,Kyung-Chul; Nam,Hyun-Koo; Oh,Deok-Kun
    参考文献:Journal Of Agricultural And Food Chemistry 日期:2013 卷标:61(47) 页码:11532-11540
📜3',4'-Di-O-Methylquercetin-3-O-α-L-Rhamnopyranosyl-(1->6)-β-D-Glucopyranosyl-7-O-α-L-Rhamnopyranosyl-(1->6)-β-D-Galactopyranoside置于盐酸,水体系中,化学反应 0.17H,反应生成 芦丁糖,芸香糖
参考文献:A New Flavonol Glycoside From The Aerial Part Of Alhagi Pseudalhagi
标题:A New Flavonol Glycoside From The Aerial Part Of Alhagi Pseudalhagi
摘要:从alhagi Pseudalhagi(豆科植物)的气生部分分离出了新的黄酮醇苷alhaoside.根据光谱特征和化学转化,确定了3',4'-二-O-甲基槲皮素-3-O-α-L-吡喃鼠李糖基-(1->6)-β-D-吡喃葡萄糖基-7-O-α-吡喃鼠李糖基-(1->6)-β-D-吡喃半乳糖苷的结构.
DOI:10.1007/s10600-013-0632-Y

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主要参考文献

[参考文献]: Marisol Minig, Et Al. Polyethyleneimine Coating Of Magnetic Particles Increased The Stability Of An Immobilized Diglycosidase. Biotechnol Appl Biochem. 2015 Jan-Feb;62(1):94-100.
[参考文献]: Pavel Bartl, Et Al. Anthocyanins In Purple And Blue Wheat Grains And In Resulting Bread: Quantity, Composition, And Thermal Stability. Int J Food Sci Nutr. 2015;66(5):514-9.

合成参考文献


参考文献:10.3390/ijms21165671
摘要:Brodsky K, Kutý M, Pelantová H, Cvačka J, Rebroš M, Kotik M, Kutá Smatanová I, Křen V, Bojarová P. Dual Substrate Specificity of the Rutinosidase from Aspergillus niger and the Role of Its Substrate Tunnel. Int J Mol Sci. 2020 Aug 07;21(16).
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