苯胺置于亚硝酸特丁酯,Copper(Ll) Bromide体系中,用 乙腈 作为反应溶剂,化学反应生成 1,2,4-三溴苯 参考文献:Alkyl Nitrite-Metal Halide Deamination Reactions. 2. Substitutive Deamination Of Arylamines By Alkyl Nitrites And Copper(II) Halides. A Direct And Remarkably Efficient Conversion Of Arylamines To Aryl Halides 标题:Alkyl Nitrite-Metal Halide Deamination Reactions. 2. Substitutive Deamination Of Arylamines By Alkyl Nitrites And Copper(II) Halides. A Direct And Remarkably Efficient Conversion Of Arylamines To Aryl Halides 摘要: DOI:10.1021/jo00434A017
专利信息
专利号:US-2006229475-A1 优先权日:2005-04-11 标题:Synthesis of hydroxylated hydrocarbons 发明人:WEISS MICHAEL J; SUN SHOULI 权利人:WEISS MICHAEL J; SUN SHOULI 摘要:Ethylene glycol, other diols, triols, and polyols are made in an efficient manner by reacting dibromides with water in the presence of a metal oxide. An integrated process of dibromide formation, alcohol synthesis, metal oxide regeneration, and bromine recycling is also provided.
专利号:US-6407299-B1 优先权日:1999-06-02 标 题:Alkyl magnesium catalyzed synthesis of ethylene and α-olefin polymers 发明人:SEN AYUSMAN; KIM JANG SUB 权利人:EXXONMOBIL RES & ENG CO; PENNSYLVANIA STATE RES FOUNDAT 摘要:The present invention is a two-component catalyst system comprising (a) an alkyl magnesium (MgR 2 ) component and (b) a Lewis acid component. The catalyst system is used for catalyzing the oligomerization and polymerization of ethylene and/or α-olefins to form homopolymers and copolymers. The products range from highly linear, high molecular weight, solid polymers to highly branched, lower molecular weight oils.
专利号:WO-2012175725-A1 优先权日:2011-06-24 标 题 :Solution polymerization/co-polymerization of dienes, hydrogenation of dienerubbers and hydrogenated dienerubbers 发明人:SODDEMANN MATTHIAS; GUO SHARON; WEI ZEHNLI; LIU QINGCHUN 权利人:LANXESS DEUTSCHLAND GMBH; SODDEMANN MATTHIAS; GUO SHARON; WEI ZEHNLI; LIU QINGCHUN 摘要:The present invention relates to butadiene rubber polymers having low molecular weights and narrower molecular weight distributions than those known in the art. The present invention also relates to a metal-containing catalyst system, a solution polymerization process for the manufacture of said butadiene rubber, a one-pot process for the synthesis of the hydrogenated diene polymers, and a process for the hydrogenation of diene polymers.
专利号:WO-0073359-A1 优先权日:1999-06-02 标题 :Alkyl magnesium catalyzed synthesis of ethylene and alpha-olefin polymers 发明人:SEN AYUSMAN; KIM JANG SUB 权利人:EXXONMOBIL RES & ENG CO 摘要:The present invention is a two-component catalyst system comprising (a) an alkyl magnesium (MgR2) component and (b) a Lewis acid component. The catalyst system is used for catalyzing the oligomerization and polymerization of ethylene and/or α-olefins to form homopolymers and copolymers. The products range from highly linear, high molecular weight, solid polymers to highly branched, lower molecular weight oils.
专利号:US-2009069606-A1 优先权日:2005-04-11 标题:Method of making alkoxylates 发明人:KOMON ZACHARY JOHN ANTHONY; WEISS MICHAEL J 权利人:GRT INC 摘要:Ethoxylates and other alkoxylates are made in an efficient manner by reacting an organic bromide with a diol in the presence of a metal oxide. An integrated process of bromide formation, alkoxylate synthesis, metal oxide regeneration, and bromine recycling is also provided.
专利号:US-2009227697-A1 优先权日:2006-02-24 标题 :Synthesis of a highly crystalline, covalently linked porous network
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