CAS: 161401-26-9; Tetraethylammonium Bis((Trifluoromethyl)Sulfonyl)Amide

该化合物是一种四硝基铵盐,其独特结构包括一种四乙基氨酸和一种三氟氟乙烷-硫化硫离子,该化合物因其在极地溶剂中的高溶性而引人注目,在各种化学应用中,特别是在有机合成中和作为核循环替代反应的试剂中都有用;三氟甲基组的存在有助于其稳定性和再活性,而全氟辛烷磺酸的功能则增强了其在形成磺酰胺衍生物方面的用途;此外,四乙基二氟乙基氟乙烷-硫化物在制成氟化合物过程中经常使用,这对制药和农用化学物具有价值;其特性,例如热稳定性和再活性,使它在学术和工业研究中都引起兴趣;在处理这一化合物时,应注意安全防范措施,因为可能对环境和毒性产生影响,许多四硝基铵盐.

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210230-40-3 405514-94-5 906478-91-9

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合成工艺路线路线简述

    📜四乙基溴化铵,Bis(Trifluoromethane)Sulfonimide Lithium 以 水 用作溶剂,化学反应生成N,N,N-三乙基乙铵二[(三氟甲基)磺酰基]亚胺
    参考文献:基于(氟磺酰基)(五氟乙烷磺酰基)酰亚胺与各种鎓盐的离子液体
    标题:基于(氟磺酰基)(五氟乙烷磺酰基)酰亚胺与各种鎓盐的离子液体
    摘要:基于(氟磺酰基)(五氟乙烷磺酰)亚胺新的疏水性离子液体([(fso 2)(c 2 ˚f 5 So 2)n]-,Fpfsi-)阴离子与各种鎓,包括咪唑鎓,四烷基铵,吡咯烷,和哌啶鎓,被准备和表征.对它们的物理化学和电化学性质(包括相变,热稳定性,粘度,密度,比电导率和电化学窗口)进行了广泛表征,并使用含有异构但对称的tfsi-([(cf 3 So 2)2 N]−)阴离子.这些新的fpfsi-系离子液体显示出低的熔点,低的粘度,非常好的热稳定性和宽的电化学窗口允许li沉积/溶解.所有这些所需的特性表明它们是锂(或锂离子)电池的潜在电解质材料.
    Doi:10.1016/j.Electacta.2010.06.085

    海关参考信息

    专利信息


    专利号:US-9267213-B1
    优先权日:2005-03-25
    标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array
    发明人:MAURER KARL; COOPER JOHN J
    权利人:CUSTOMARRAY INC
    摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

    专利号:US-10407676-B2
    优先权日:2014-12-09
    标题 :High efficiency, small volume nucleic acid synthesis
    发明人:POEHMERER THOMAS; KUHN PHILLIP; NOTKA FRANK; ZEIDLER ANDREAS; HEIL KORBINIAN; TREFZER AXEL; FONNUM GEIR; KATZEN FEDERICO; ANDERSSON KRISTIAN
    权利人:LIFE TECHNOLOGIES CORP; THERMO FISHER SCIENT GENEART GMBH; LIFE TECH AS
    摘要:The disclosure generally relates to compositions and methods for the production of nucleic acid molecules. In some aspects, the invention allows for the microscale generation of nucleic acid molecules, optionally followed by assembly of these nucleic acid molecules into larger molecules. In some aspects, the invention allows for efficient production of nucleic acid molecules (e.g., large nucleic acid molecules such as genomes).

    专利号:MX-2007011815-A
    优先权日:2005-03-25
    标题 :ELECTROCHEMICAL UNLOCK SOLUTION FOR ELECTROCHEMICAL SYNTHESIS OF OLIGOMEROS IN AN ARRANGEMENT OF ELECTRODES.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1134/s0036024421030031
    摘要:Arkhipova EA, Ivanov AS, Maslakov KI, Chernyak SA, Savilov SV. Nitrogen Heterosubstitution in Graphene Nanoflakes: An Effective Approach to Improving Performance of Supercapacitors with Ionic Liquid Electrolyte. Russian Journal of Physical Chemistry A. 2021 Mar;95(3):565–9. doi: 10.1134/s0036024421030031.
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