CAS: 124-12-9; Octanenitrile

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CAS号929-55-5 Capryl aldoxime | CAS号5458-59-3 正辛酸异丙酯 | CAS号111-87-5 正辛醇 | CAS号629-01-6 正辛酰胺 | CAS号124-13-0 正辛醛 | CAS号111-86-4 辛胺 | CAS号693-03-8 正丁基溴化镁 | CAS号5332-06-9 4-溴丁腈 | CAS号5813-91-2 °Ctanethioamide | CAS号1120-48-5 二正辛胺 | CAS号142-95-0 正辛胺盐酸盐 | CAS号2306-88-9 辛酸辛酯 | CAS号111-87-5 正辛醇 | CAS号124-13-0 正辛醛 | CAS号111-14-8 庚酸 | CAS号22348-96-5 3-氧代癸酸甲酯 | CAS号124-07-2 辛酸 | CAS号629-01-6 正辛酰胺 | CAS号619-55-6 对甲基苯甲酰胺 | CAS号101506-39-2 tert-butyl N-°C...

(E)-octanal O-Methyl Oxime置于ru(Co)(Pph3)3H2 4,5-双二苯基膦-9,9-二甲基氧杂蒽体系中,用 甲苯 用作溶剂,化学反应 24.0H,以83%的收率获得正辛腈
参考文献:钌催化的肟醚向腈的转化
标题:钌催化的肟醚向腈的转化
摘要:使用ru(co)(pph 3)3 H 2和二齿配体xantphos作为催化剂,在中性条件下实现了肟醚向腈的转化.
Doi:10.1016/j.Tetlet.2007.09.028

专利信息

专利号:US-2004024238-A1
优先权日:1999-07-02
标 题:Use of nitriles as polar aprotic solvents
发明人：LAURAIN NATHALIE; ZARD SAMIR
摘要:The invention concerns the use of aliphatic nitriles with relatively high molecular weight, as polar aprotic solvents, in particular in nucleophilic substitution reactions of the aromatic type. Said nitriles have a molecular mass more 79, preferably more than 90. The invention is useful for synthesis of fluorinated aromatic compounds.

专利号:US-5900496-A
优先权日:1990-03-21
标 题 :Microbial production of a novel compound 7,10-dihydroxy-8-octadecenoic acid from oleic acid
发明人：HOU CHING T
权利人:US AGRICULTURE
摘要:A strain of Pseudomonas Sp. bacterium (NRRL B-18602) has been discovered which is capable of converting oleic acid to the novel compound, 7,10-dihydroxy-8-octadecenoic acid (DOD). The production of DOD is unique in that it involves a hydroxylation at two positions and a rearrangement of the double bond of the substrate molecule. The new multifunctional, long-chain aliphatic acid has potential utility as a plasticizer and as a source of intermediates in the synthesis of specialty chemicals.

专利号:US-8673251-B2
优先权日:2007-11-02
标 题:Methods of preparing Clusterboron
发明人：COOK KEVIN S; OXFORD MARK
权利人:COOK KEVIN S; OXFORD MARK; SEMEQUIP INC
摘要:The invention provides new methods for synthesis of ClusterBoron® (B 18 H 22 ). Preferred methods of the invention include generation of the conjugate acid of B 20 H 18 2− and degradation of the acid in solution to produce B 18 H 22 in high yields and high purity. The invention further provides isotopically enriched boranes, particularly isotopically enriched 10 B 18 H 22 and 11 B 18 H 22 .

专利号:US-8729283-B2
优先权日:2009-01-29
标 题 :Chain-selective synthesis of fuel components and chemical feedstocks
发明人：OLSON EDWIN S
权利人:ENERGY & ENVIRON RES CT FOUND
摘要:A method comprising providing a starting composition comprising a polyunsaturated fatty acid, a polyunsaturated fatty ester, a carboxylate salt of a polyunsaturated fatty acid, a polyunsaturated triglyceride, or a mixture thereof; self-metathesizing the starting composition or cross-metathesizing the starting composition with at least one short-chain olefin in the presence of a metathesis catalyst to form self-/cross-metathesis products comprising: cyclohexadiene; at least one olefin; and one or more acid-, ester-, or salt-functionalized alkene; and reacting cyclohexadiene to produce at least one cycloalkane or cycloalkane derivatives. A method for producing cycloalkanes for jet fuel by providing a starting composition comprising at least one selected from the group consisting of algal and polyunsaturated vegetable oils, subjecting the starting composition to metathesis to produce metathesis product comprising at least one olefin, cyclohexadiene, and at least one acid-, ester-, or salt-functionalized alkene, and reacting the at least one olefin and cyclohexadiene to form cycloalkane(s).

专利号:US-4219684-A
优先权日:1979-04-02
标 题 :Synthesis of alcohols by hydroformylation with nitrile promoter
发明人：IMAI TAMOTSU
权利人:UOP INC
摘要:Alcohols may be synthesized by reacting an olefinic compound, carbon monoxide and hydrogen in the presence of a Group VIII organometallic complex catalyst at reaction conditions which include a temperature in the range of from about 50° to about 250° C. and a pressure in the range of from about 10 to about 300 atmospheres. In addition, the reaction is also effected in the presence of a promoter compound comprising a nitrile.

专利号:US-7960589-B2
优先权日:2006-09-06
标 题:Synthesis of sphingosines and their derivatives
发明人：YANG HAO; LIEBESKIND LANNY S
权利人:UNIV EMORY
摘要:Embodiments of the present disclosure provide for methods of making sphingosines and derivatives thereof, and the like.