CAS: 1048-05-1; Tetraphenylgermane

该化合物是一种高度稳定的有机合成化合物,具有特殊的热抗药性和化学抗药性,其独特的结构有助于其高折射指数和极佳的电气特性,使之适合用于光电子和先进的半导体装置,该化合物的低挥发性和对氧化的抗药性增强了其在各种环境中的稳定性.

结构式图片

相似化合物

1626-24-0 2816-43-5 1018982-18-7

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

bromobenzene diethyl ether triphenyl germane; sodium-compound phenyllithiumdiphenylgermane triphenyl germane; sodium-compound diphenyldiiodogermane triphenylgermanium bromide

合成工艺路线路线简述

  • 合成目标产物 Tetraphenylgermane 主要起始原料 Bromobenzene And Germanium(Iv) Chloride
  • (文献来源)合成步骤主要原料 Bromobenzene 和 Germanium(Iv) Chloride
📜Aminotriphenylgermane 以 乙醚,氨 用作溶剂,化学反应生成四苯基锗
参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Ge: Mvol.,20,Page 53-57
标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Ge: Mvol.,20,Page 53-57

专利信息


专利号:US-4565896-A
优先权日:1984-10-22
标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
发明人:KNIFTON JOHN F; DURANLEAU ROGER G
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

专利号:US-4609768-A
优先权日:1984-10-22
标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

专利号:US-4568780-A
优先权日:1984-10-22
标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane
发明人:KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silane or germane-containing promoter dispersed in a hydrocarbon solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi, where the particular solvents used allow the desired product to be separated from the reaction mixture by phase separation.

专利号:US-4409405-A
优先权日:1982-05-13
标题:Production of ethanol from methanol and synthesis gas
发明人:LIN JIANG-JEN; KNIFTON JOHN F
权利人:TEXACO INC
摘要:Ethanol is formed by contacting a mixture of carbon monoxide, hydrogen and methanol with a catalyst comprising a cobalt-containing compound and a germanium-containing compound, such as dicobalt octacarbonyl and triphenylgermanium hydride in the presence of an inert, oxygenated hydrocarbon solvent at a temperature of about 50 DEG to about 350 DEG C. and at a pressure of about 500 psig or greater.

专利号:FR-2722781-A1
优先权日:1994-07-20
标题:Non-catalytic synthesis of organic or organo-metallic prods.

专利号:CN-107774253-A
优先权日:2016-08-29
标题 :Hydrogenation catalyst for the synthesis of 1,4-diacetoxybutane

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Thornton, P., Science of Synthesis, (2003) 5, 86.
摘要:Oshima, K., Science of Synthesis, (2003) 5, 9.
摘要:Thornton, P., Science of Synthesis, (2003) 5, 64.
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