CAS: 934557-66-1; 6,6'-(9H-Fluorene-9,9-Diyl)Bis(Naphthalen-2-Ol)

该化合物是有机化合物,其结构复杂,具有中氟环环球,与两个环烷烃单位相连,具有中枢氟环球,具有显著的特性,如强大的荧光度,因此对各种应用,包括有机发光二极管(OLEDs)和生物化学鉴定中的潜在荧光探测感兴趣.

英文名称6,6'-(9H-Fluorene-9,9-Diyl)Bis(Naphthalen-2-Ol)
中文名称6,6-(9H-芴-9,9-二基)双(萘-2-醇)
IUPAC名称6,6'-(9H-fluorene-9,9-diyl)bis(naphthalen-2-ol)
其它别名2-萘ol, 6,6'-(9H-芴-9-亚基)双-; 6,6'-(9H-Fluorene-9,9-Diyl)Di(2-Naphthol)
CAS编号934557-66-1
MFCD编号:MFCD24038938
分子式:C33H22O2
分子量:450.53
产品CID: 1974038
产品分类有机原料→分子砌块→芳环类化合物→萘类化合物

相似结构搜索
InChIKey: DYOPVXMHYSXHNG-UHFFFAOYSA-N
InChI=1S/C33H22O2/c34-27-15-11-21-17-25(13-9-23(21)19-27)33(26-14-10-24-20-28(35)16-12-22(24)18-26)31-7-3-1-5-29(31)30-6-2-4-8-32(30)33/h1-2…
计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数2.0

相似化合物

3236-71-3 88938-12-9 80850-00-6

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H315-H319
防范说明P264-P280-P302+P352-P362+P364

合成工艺路线路线简述

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Reagents: 3-Mercaptopropionic Acid,Sulfuric Acid Solvents: Toluene; 6 H,60 °C1.2 Solvents: Diisopropyl Ether; 1 H,60 °C; 10 °C
标题:Process For Preparation Of Fluorene Derivatives As Thermosetting Resin
参考文献:Japan]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Catalysts: 12-Tungstophosphoric Acid Solvents: Chlorobenzene; 7 H,20 Kpa,86 °C; 86 °C -> 63 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 5 Min,60 - 65 °C
标题:Crystals Of Bisnaphthol Having Fluorene Skeleton And Production Method Therefor
参考文献:Japan]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Catalysts: Tungstate(3-),Tetracosa-μ-Oxododecaoxo[μ12-[phosphato(3-)-Ko:Ko:Ko:Ko′:Ko′:Ko′:... Solvents: Toluene; Reflux
标题:Optical Lens Comprising Thermoplastic Resin
参考文献:World Intellectual Property Organization]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Reagents: γ-Butyrolactone,1-Dodecanethiol Catalysts: Tungsten Hydroxide Oxide Phosphate Solvents: Toluene; 7 H,49.3 Kpa,Rt -> 100 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; Neutralized,100 °C -> 120 °C
标题:Method For Producing Alcohol Having Fluorene Skeleton
参考文献:World Intellectual Property Organization]

135-19-3 + 486-25-9 = 934557-66-1 [标题:Reaction Conditions
标题:Acid Anhydride-Modified Fluorene-Containing Acrylic Resins With High Refractive Index And Their Manufacture
参考文献:Japan]

= 934557-66-1 [标题:Reaction Conditions
标题:Preparation Of Vinyl-Group-Containing Fluorene Compounds
参考文献:World Intellectual Property Organization]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Solvents: Xylene; Rt; Rt -> 90 °C; 2 H,90 °C
标题:Method For Preparation Of Fluorenes Compound
参考文献:China]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Reagents: 3-Mercaptopropionic Acid,Sulfuric Acid Solvents: 1,4-Dioxane,Water; 6 H,60 °C1.2 Reagents: Sodium Hydroxide Solvents: Toluene,1,4-Dioxane,Water; Ph 7
标题:Crystal Polymorphs Of 6,6-(9-Fluorenylidene)-Di(2-Naphthol) And Their Preparation
参考文献:Japan]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Reagents: Sulfuric Acid Catalysts: 3-Mercaptopropionic Acid Solvents: Toluene; 4 - 8 H,50 - 60 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; Neutralized
标题:Preparation Of 9,9-Bis(6-Hydroxynaphthalen-2-Yl)Fluorene Crystal Without Residual Solvent
参考文献:China]

86-73-7 + 135-19-3 = 934557-66-1
反应条件:1.1 Reagents: Sulfuric Acid Solvents: Toluene,Water; Rt; 10 H,80 °C1.2 Reagents: Sodium Hydroxide Solvents: Toluene,Water; Ph 7
标题:Fluorene-Based Dianhydrides And Polyimides With Thermoplastic Ability And Excellent Thermal Stability
参考文献:United States]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Reagents: Sulfuric Acid Catalysts: 3-Mercaptopropionic Acid Solvents: 1,4-Dioxane; 60 °C; 55 °C -> 65 °C; 4 H,60 °C
标题:Method For The Preparation Of Alcohol Compound Having Fluorene Skeleton
参考文献:Japan]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Reagents: Sulfuric Acid Catalysts: 3-Mercaptopropionic Acid Solvents: 1,4-Dioxane; Rt -> 60 °C; 6 H,60 °C
标题:Method For Manufacturing Polycarbonate Resin Or Polyester Resin For Forming Molded Product And Optical Material
参考文献:Japan]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Catalysts: Sulfuric Acid Solvents: 1,4-Dioxane; 6 H,60 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; Ph 7
标题:9,9-Bis(6-Hydroxy-2-Naphthyl)Fluorene Crystal Polymorph And Preparation Method Thereof
参考文献:Japan]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Reagents: 3-Mercaptopropionic Acid,Sulfuric Acid Solvents: Toluene; 60 °C
标题:Resin Composition With Good Desmear Property And Heat Resistance,And Low Dielectric Loss Tangent For Multilayer Substrate
参考文献:World Intellectual Property Organization]

135-19-3 + 486-25-9 = 934557-66-1
反应条件:1.1 Catalysts: P-Toluenesulfonic Acid,3-Mercaptopropionic Acid Solvents: P-Xylene; Rt -> 135 °C; 15 H,135 °C
标题:Fluorene Condensate Composition And Epoxidized Composition And Production Method Thereof
参考文献:Japan]

5593-70-4 + 934557-66-1 = 934557-66-1
反应条件:1.1 Solvents: 1-Butanol,Toluene; 30 Min,90 °C
标题:Preparation Of Organic Metal Compound
参考文献:World Intellectual Property Organization]

135-19-3 + 486-25-9 = 934557-66-1 [标题:Reaction Conditions
标题:Fluorene-Containing (Meth)Acrylates And Photocurable Compositions Containing Them
参考文献:Japan]

86-73-7 + 135-19-3 = 934557-66-1
反应条件:1.1 Reagents: 3-Mercaptopropionic Acid,Sulfuric Acid Solvents: Toluene,Water; 10 H,80 °C1.2 Solvents: Toluene,Water1.3 Reagents: Tetramethylammonium Hydroxide; Ph 7
标题:Photoresist Underlayer Film Compositions Comprising A Fullerene Compound For A Multilayered Resist Film With Resistance To Twisting After Etching And With Excellent Property For Filling Up A Height Difference Of A Substrate,Process For Forming Photoresist Underlayer Film,And Patterning Process Using The Photoresist Underlayer Film-Forming Compositions
参考文献:United States

9-芴酮,2-萘酚置于硫酸,3-巯基丙酸体系中,用 1,4-二氧六环作为反应溶剂,化学反应 6.0H,以59.7%的收率获得产物6,6-(9H-芴-9,9-二基)双(萘-2-醇)
参考文献:9,9−ビス(6−ヒドロキシ−2−ナフチル)フルオレンの結晶多形およびその製造方法
标题:9,9−ビス(6−ヒドロキシ−2−ナフチル)フルオレンの結晶多形およびその製造方法
摘要:提供一种在热稳定性或高温环境下具有非常好保存稳定性的bnf新型多形体(结晶多形体)及其制备方法.从芳香族烃类,酚类和酮类中选择至少一种溶剂与混合溶剂结晶化bnf,得到在粉末x射线衍射图案中,具有衍射角度2θ=9.6+/-0.2°,20.6+/-0.2°和21.3+/-0.2°的衍射峰的结晶多形体δ.结晶多形体δ还可以具有在衍射角度2θ=9.2+/-0.2°,9.8+/-0.2°,17.1+/-0.2°,23.3+/-0.2°和23.8+/-0.2°中至少一个角度的衍射峰.[选择图]图7