CAS: 922-65-6; 1,4-Pentadien-3-Ol

该化合物是一个有机化合物,其特点是五碳链,由两个相交双环和氢氧(OH)组组成,该结构将其归类为多饱和酒精;氢氧基组的存在具有极性特征,使其在水和其他极溶剂中溶解;混合物表现出典型的酒精和高温反应,允许其参与各种化学反应,如氧化和聚合;其相交的双重结合还有助于独特的光学特性和再活动模式,使其对有机合成和材料科学感兴趣;此外,1,4-Pentadien-3-ol可能用于特殊化学,香味或合成更复杂的有机分子的中间体.安全数据表明,与许多有机化合物一样,应谨慎地处理,因为吸入或吸入会给健康带来风险.

结构式图片

相似化合物

598-32-3 115-18-4 616-25-1

物理性质

MSDS等安全信息

欧盟法规

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CAS号593-60-2 溴乙烯 | CAS号109-94-4 甲酸乙酯 | CAS号62418-65-9 3-TRIETHYLSILOX... | CAS号107-31-3 甲酸甲酯 | CAS号1826-67-1 乙烯基溴化镁 | CAS号107-02-8 丙烯醛 | CAS号74-88-4 碘甲烷 | CAS号930-22-3 3,4-环氧-1-丁烯 | CAS号2181-42-2 三甲基碘代磺酸 | CAS号1219113-69-5 3-dimethylpheny... | CAS号6018-27-5 DL-阿拉伯糖醇 | CAS号87-99-0 木糖醇 | CAS号488-81-3 侧金盏花醇 | CAS号1890-28-4 1,4-Pentadien-3-one | CAS号3051-94-3 1-脱氧-1-[((3,4-二... | CAS号22862-76-6 茴香霉素 | CAS号100017-22-9 (1S)-1-[(2R)-ox... | CAS号102490-00-6 (1R)-1-[(2S)-ox... | CAS号81661-61-2 (S)-1-((S)-oxir... | CAS号1001-93-0 5-bromopenta-1,...

合成工艺路线路线简述

  • 109-94-4 = 922-65-6
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; Rt; Rt -> 40 °C; 1 H,30 - 40 °C; 1.5 H,Rt; Cooled1.2 1 H,5 - 15 °C; 1 H,Rt
    标题:6,8,10-Undecatrien-3- Or 4-Ol,Preparation Thereof,And Fragrance Compositions Containing The Same
    参考文献:Japan]

    109-94-4 + 1826-67-1 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; 1 H,5 - 15 °C; 1 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water
    标题:Preparation Of 6,8,10-Undecatriene-4-One And Perfume Composition
    参考文献:Japan]

    109-94-4 + 1826-67-1 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; 1 H,5 - 15 °C; 1 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water
    标题:Preparation Of 6,8,10-Undeca-Triene-3-One And Perfume Composition
    参考文献:Japan]

    = 922-65-6
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; 40 °C1.2 Solvents: Tetrahydrofuran; Reflux; 1 H,Reflux; Reflux -> 0 °C1.3 0 °C; 0 °C -> 23 °C; 2 H,23 °C; 23 °C -> -20 °C1.4 Reagents: Hydrochloric Acid Solvents: Water
    标题:Enantioselective Total Synthesis Of Pladienolide B: A Potent Spliceosome Inhibitor
    作者:Ghosh,Arun K.; Anderson,David D.
    参考文献:Organic Letters 日期:2012 卷标:14(18) 页码:4730-4733]

    1826-67-1 = 922-65-6
    反应条件:1.1 0 °C; 3 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water
    标题:Construction Of Silicon-Containing Seven-Membered Rings By Catalytic [4 + 2 + 1] Cycloaddition Through Rhodium Silylenoid
    作者:Sasaki,Ikuo; Ohmura,Toshimichi; Suginome,Michinori
    参考文献:Organic Letters 日期:2020 卷标:22(8) 页码:2961-2966]

    1826-67-1 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; 15 Min,0 °C; 0 °C -> Rt; 1 - 3 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water
    标题:A Cu/pd Cooperative Catalysis For Enantioselective Allylboration Of Alkenes
    作者:Jia,Tao; Cao,Peng; Wang,Bing; Lou,Yazhou; Yin,Xuemei; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2015 卷标:137(43) 页码:13760-13763]

    62418-65-9 = 922-65-6
    反应条件:1.1 Reagents: Selectfluor Solvents: Acetonitrile; 3 Min,150 °C
    标题:A Novel,Chemoselective And Efficient Microwave-Assisted Deprotection Of Silyl Ethers With Selectfluor
    作者:Shah,Syed Tasadaque A.; Singh,Surendra; Guiry,Patrick J.
    参考文献:Journal Of Organic Chemistry 日期:2009 卷标:74(5) 页码:2179-2182]

    62418-65-9 = 922-65-6
    反应条件:1.1 Catalysts: Bromotrimethylsilane Solvents: Methanol; 5 Min,Rt1.2 Reagents: Sodium Bicarbonate Solvents: Water; Rt
    标题:The Chemoselective And Efficient Deprotection Of Silyl Ethers Using Trimethylsilyl Bromide
    作者:Shah,Syed Tasadaque A.; Guiry,Patrick J.
    参考文献:Organic & Biomolecular Chemistry 日期:2008 卷标:6(12) 页码:2168-2172]

    109-94-4 = 922-65-6
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; Rt; Rt; Rt -> 40 °C; 1 H,30 - 40 °C; 1.5 H,Rt; Cooled1.2 1 H,5 - 15 °C; 1 H,Rt
    标题:Preparation Of 6,8,10-Undecatrien-3-One And Its Intermediate
    参考文献:Japan]

    109-94-4 = 922-65-6
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; Rt; 1 H,Rt -> 40 °C; Rt; 1.5 H,Rt1.2 Solvents: Water; 1 H,5 - 15 °C; 1 H,Rt
    标题:8,9-Epoxyundeca-1,3,5-Trienes,Their Preparation,And Perfume Compositions Containing Them
    参考文献:Japan]

    109-94-4 = 922-65-6
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; Rt; Rt -> 40 °C; 1 H,30 - 40 °C; 1.5 H,Rt1.2 1 H,5 - 15 °C; 1 H,Rt1.3 Reagents: Ammonium Chloride Solvents: Water
    标题:Preparation Of 6,8,10-Undeca-Triene-2-One And Perfume Composition
    参考文献:Japan]

    109-94-4 = 922-65-6
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; 25 °C; 2.5 H,Reflux; 0 °C1.2 0 °C; 1 H,25 °C1.3 Reagents: Ammonium Chloride Solvents: Water
    标题:Divinylcarbinol Desymmetrization Strategy: A Concise And Reliable Approach To Chiral Hydroxylated Fatty Acid Derivatives
    作者:Sugimoto,Kenji; Kobayashi,Ami; Kohyama,Aki; Sakai,Haruka; Matsuya,Yuji
    参考文献:Journal Of Organic Chemistry 日期:2021 卷标:86(5) 页码:3970-3980]

    107-31-3 + 1826-67-1 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; < 5 °C; 4 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water
    标题:Thioreductones And Derivatives
    作者:Schank,Kurt; Buegler,Stephan; Folz,Harald; Schott,Norbert
    参考文献:Helvetica Chimica Acta 日期:2007 卷标:90(8) 页码:1606-1649]

    = 922-65-6
    反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether,Tetrahydrofuran
    标题:An Efficient Synthesis Of Functionalized Tricyclo[6.3.1.01.6]Dodec-4-Enes By A Stereoselective Intramolecular Diels-Alder Reaction
    作者:Shishido,Kozo; Hiroya,Kou; Ueno,Yutaka; Fukumoto,Keiichiro; Kametani,Tetsuji; Et Al
    参考文献:Journal Of The Chemical Society 日期:1986 卷标:(5) 页码:829-36]

    109-94-4 = 922-65-6
    反应条件:1.1 Reagents: Magnesium,Iodine Solvents: Tetrahydrofuran
    标题:Novel Aspects Of The Chemistry Of Thioamides
    作者:Naylor,Elizabeth Mary
    参考文献:1987]

    1219113-69-5 = 922-65-6 + 616-25-1 + 584-02-1
    反应条件:1.1 Reagents: Methanol,Hydrogen Catalysts: Rhodium(1+),[(2,3,5,6-η)-Bicyclo[2.2.1]Hepta-2,5-Diene][(2S,2′s,5S,5′s)-1,1′-(1... Solvents: Methanol; 1.6 Atm,21 °C
    标题:Stereoselectivity In The Rhodium-Catalyzed Reductions Of Non-Conjugated Dienes
    作者:Nguyen,Bao; Brown,John M.
    参考文献:Advanced Synthesis & Catalysis 日期:2009 卷标:351(9) 页码:1333-1343]

    109-94-4 + 3536-96-7 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; 0 °C; 1 H,0 °C1.2 Reagents: Ammonium Chloride Solvents: Water
    标题:Polymethylene-Based Eight-Shaped Cyclic Block Copolymers
    作者:Jiang,Yu; Hadjichristidis,Nikos
    参考文献:Macromolecules (Washington 日期:2020 卷标:53(1) 页码:267-275]

    1826-67-1 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; 0 °C; 1 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water; Rt
    标题:Olefin-Migrative Cleavage Of Cyclopropane Rings Through The Nickel-Catalyzed Hydrocyanation Of Allenes And Alkenes
    作者:Hori,Hiroto; Arai,Shigeru; Nishida,Atsushi
    参考文献:Advanced Synthesis & Catalysis 日期:2017 卷标:359(7) 页码:1170-1176]

    1826-67-1 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; 0 °C; Overnight,0 °C1.2 Reagents: Ammonium Chloride Solvents: Water
    标题:F- Nucleophilic-Addition-Induced Allylic Alkylation
    作者:Tian,Panpan; Wang,Cheng-Qiang; Cai,Sai-Hu; Song,Shengjin; Ye,Lu; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2016 卷标:138(49) 页码:15869-15872]

    109-94-4 + 3536-96-7 = 922-65-6
    反应条件:1.1 Solvents: Tetrahydrofuran; 0 °C; 1 H,Rt1.2 Reagents: Ammonium Chloride Solvents: Water; Rt
    标题:Synthesis Of Well-Defined Polyethylene-Based 3-Miktoarm Star Copolymers And Terpolymers
    作者:Zhang,Zhen; Altaher,Maryam; Zhang,Hefeng; Wang,De; Hadjichristidis,Nikos
    参考文献:Macromolecules (Washington 日期:2016 卷标:49(7) 页码:2630-2638
1,4-戊二烯 反应生成 1,4-戊二烯-3-醇
参考文献:Di Maio,G. Et Al.,Gazzetta Chimica Italiana,1973,Vol. 103,P. 477-482
标题:Di Maio,G. Et Al.,Gazzetta Chimica Italiana,1973,Vol. 103,P. 477-482

海关参考信息

专利信息


专利号:US-5087703-A
优先权日:1988-01-28
标题 :Process for synthesis of FK-506 intermediates
发明人：VOLANTE RALPH P; ASKIN DAVID; SHINKAI ICHIRO; RYAN KENNETH M
权利人:MERCK & CO INC
摘要:A process is described for the synthesis of diastereomeric 2-methyl-4-hydroxy-5-protected-hydroxy-hept-6-en-prolinolamides, which are useful as intermediates in the synthesis of the C10-C18 chain of the macrolide structure for the immunosuppressant FK-506. These compounds are also useful as intermediates for preparing lactone ultraviolet radiation absorbers.

专利号:US-9879043-B1
优先权日:2013-06-06
标 题:Synthesis of non-natural cofactor analogs of S-adenosyl-L-methionine using methionine adenosyltransferase
发明人：THORSON JON; HUBER TYLER; ZHANG JIANJUN; Singh Shanteri
权利人:UNIV KENTUCKY RES FOUND
摘要:The present disclosure relates to the synthesis of non-natural analogs of S-adenosyl-L-methionine (SAM) and/or of Se-adenosyl-L-methionine (SeAM) by reacting a methionine analog and adenosine triphosphate (ATP) in the presence of at least one methionine adenosyltransferase (MAT), and to use thereof with downstream SAM and/or SeAM utilizing enzymes. The non-natural analogs of SAM and/or SeAM have the general formula: n nwhere X is S or Se, and R 1 is an alkyl group.

专利号:US-5637757-A
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds
发明人：HILL JOHN E; FAVSTRITSKY NICOLAI A; MAMUZIC RASTKO I; BHATTACHARYA BHABATOSH
权利人:GREAT LAKES CHEMICAL CORP
摘要:A method of preparing tetrabromobenzoate compounds from tetrabromophthalic anhydride by reacting tetrabromophthalic anhydride with alcohol in the presence of a decarboxylation catalyst. The reaction may be carried out in an excess of alcohol, or with a near stoichiometric amount of alcohol by performing the reaction in an inert solvent.

专利号:US-2010298504-A1
优先权日:2007-09-19
标题 :Amphiphilic polymer and processes of forming the same
发明人：Janczewski Dominik; TOMCZAK NIKODEM; KHIN YIN WIN; HAN MINGYONG; VANCSO JULIUS
权利人:AGENCY SCIENCE TECH & RES
摘要:Disclosed are an amphiphilic polymer, its synthesis and uses thereof. The polymer has a hydrocarbon backbone with —COOH side groups. It further has first aliphatic moieties with a main chain of about 3 to about 20 carbon atoms and 0 to about 3 heteroatoms, and second aliphatic moieties that have a main chain of about 3 to about 80 carbon atoms and about 2 to about 40 heteroatoms. The second aliphatic moieties have a copolymerisable group. In the synthesis a maleic anhydride polymer of formula (I) where n is an integer from about 10 to about 10000 and R1 is H or methyl, is reacted with a monofunctional compound with an alkyl chain of about 3 to about 20 carbon atoms and 0 to about 2 heteroatoms, and with an at least bifunctional compound with an alkyl chain of about 3 to about 80 carbon atoms and 0 to about 40 heteroatoms. The functional group of the monofunctional compound and one functional group of the at least bifunctional compound can form a linkage with an anhydride. Another functional group of the at least bifunctional compound, which is not allowed to react with the maleic anhydride polymer, is copolymerisable.

专利号:US-2014114086-A1
优先权日:2012-10-22
标 题:Clinprost, Isocarbacyclin And Analogs Thereof And Methods Of Making The Same
发明人：CROATT MITCHELL
权利人:UNIV NORTH CAROLINA AT GREENSBORO
摘要:In one aspect, methods of synthesizing clinprost, isocarbacyclin and analogs thereof are described herein which, in some embodiments, permit an abbreviated synthetic pathway in comparison to one or more prior synthetic methods. By providing a compact synthetic scheme, methods described herein can reduce cost, waste and time of clinprost and isocarbacyclin synthesis while facilitating the development and investigation of analogs of these compounds.

专利号:US-9676676-B2
优先权日:2014-07-02
标题 :Selective olefin metathesis with cyclometalated ruthenium complexes
发明人：HARTUNG JR JOHN; QUIGLEY BRENDAN L; DORNAN PETER K; GRUBBS ROBERT H
权利人:CALIFORNIA INST OF TECHN
摘要:This invention relates generally to C—H activated ruthenium olefin metathesis catalyst compounds which are stereogenic at the ruthenium center, to their preparation, and the use of such catalysts in the metathesis of olefins and olefin compounds. In particular, the invention relates to the use of C—H activated ruthenium olefin metathesis catalyst compounds in Z-selective olefin metathesis reactions, enantio-selective olefin metathesis reactions, and enantio-Z-selective olefin metathesis reactions. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.

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合成参考文献


摘要:Bubnov, Yu. N.; Kolomnikova, G. D., Science of Synthesis Knowledge Updates, (2012) 3, 317.
摘要:Matsumoto, K.; Katsuki, T.; Arends, I. W. C. E., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 81.
摘要:Matsumoto, K.; Katsuki, T.; Arends, I. W. C. E., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 76.
摘要:Szabó, K. J., Science of Synthesis: Multicomponent Reactions, (2013) 2, 351.
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