CAS: 88816-02-8; 2,4-Bis(4-Phenoxyphenyl)-1,3,2,4-Dithiadiphosphetane 2,4-Disulfide

该化合物是一种化学化合物,主要用于有机合成,特别是酒精氧化成碳基化合物,因其选择性和温和反应条件而具有价值,适合敏感基质.试剂通常用于制备甲状腺和酮,不过度氧化成碳酸,这是较强氧化剂的一个常见问题.其稳定性和易于处理进一步提高其在实验室环境中的效用.Belleau的试剂在复杂的合成路径中特别有利,因为需要精确控制氧化状态,确保高产量和最小的侧面反应.

结构式图片

合成工艺路线路线简述

  • 101-84-8 = 88816-02-8
    反应条件:1.1 Reagents: 2,4,6,8,9,10-Hexathia-1,3,5,7-Tetraphosphatricyclo[3.3.1.13,7]Decane,1,3,5,7-Te...; 3 H,180 °C
    标题:Convenient And Scalable Synthesis Of Aryldichlorophosphines And Primary Arylphosphines Via Perthiophosphonic Anhydrides
    作者:Picthall,Daniel; Surgenor,Brian A.; Kilian,Petr
    参考文献:Synthesis 日期:2023 卷标:55(6) 页码:919-926]

    101-84-8 = 88816-02-8
    反应条件:1.1 Reagents: 2,4,6,8,9,10-Hexathia-1,3,5,7-Tetraphosphatricyclo[3.3.1.13,7]Decane,1,3,5,7-Te...
    标题:Synthesis And Selective Reduction Of Protected Endothiopeptides
    作者:Ripperger,H.
    参考文献:Journal Fuer Praktische Chemie (Leipzig) 日期:1987 卷标:329(6) 页码:1039-44

海关参考信息

专利信息


专利号:US-2013012706-A1
优先权日:2010-03-01
标 题 :Methods and Intermediates for the Synthesis of 4-oxo-3,4-dihydro-imidazo[5,1-d][1,2,3,5]tetrazines
发明人:HUMMERSONE MARC GEOFFERY; COUSIN DAVID
权利人:PHARMINOX LTD; HUMMERSONE MARC GEOFFERY; COUSIN DAVID
摘要:The present invention provides a compound of general formula (II), or a salt or solvate thereof: n n n n n n n n n n n n wherein n A is independently -A 1 , -A 2 , -A 3 , -A 4 , -A 5 , -A 6 , or -A 7 , wherein:n -A 1 is independently C 5-12 heteroaryl, and is optionally substituted; -A 2 is independently thioamido or substituted thioamido; -A 3 is independently imidamido, substituted imidamido, N-hydroxyimidamido, or substituted N-hydroxyimidamido; -A 4 is independently hydroxamic acid or hydroxamate; -A 5 is independently carboxamide or substituted carboxamide; -A 6 is independently aliphatic C 2-6 alkenyl, and is optionally substituted; and -A 7 is independently carboxy or C 1-4 alkyl-carboxylate;n nand its use in the synthesis of temozolomide and analogues thereof.

专利号:US-2024376065-A1
优先权日:2021-07-29
标 题:Thionolactones, processes of synthesis, uses as comonomers and for polymer functionalization and degradation
发明人:DUFILS PIERRE-EMMANUEL; PLUMMER CHRISTOPHER MARK; WILSON DAVID JAMES; GIGMES DIDIER; GUILLANEUF YOHANN
权利人:SPECIALTY OPERATIONS FRANCE; UNIV AIX MARSEILLE; CENTRE NAT RECH SCIENT
摘要:The instant invention relates to thionolactone compounds useful as comonomers to introduce weak bonds for polymer degradation or functionalization. The invention is also directed to processes for the preparation of said compounds, notably by thionation of the corresponding lactones. The invention is furthermore directed to uses of said thionolactones as comonomers, copolymers made from these comonomers, and processes for the preparation of said copolymers.

专利号:EP-3567040-B1
优先权日:2013-06-24
标 题 :Method for the preparation of intermediates useful for the synthesis of [1,2,4]-triazolo[4,3-a]pyridines

专利号:WO-2011107726-A1
优先权日:2010-03-01
标 题:Methods and intermediates for the synthesis of 4-oxo-3,4-dihydro-imidazo[5,1-d][1,2,3,5]tetrazines

专利号:EP-3567040-A1
优先权日:2013-06-24
标题 :Method for the preparation of intermediates useful for the synthesis of [1,2,4]-triazolo[4,3-a]pyridines

专利号:EP-2542553-A1
优先权日:2010-03-01
标 题:Methods and intermediates for the synthesis of 4-oxo-3,4-dihydro-imidazo[5,1-d][1,2,3,5]tetrazines

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Wicha, J., Science of Synthesis, (2009) 48, 140.
摘要:Koutentis, P. A.; Ioannidou, H. A., Science of Synthesis Knowledge Updates, (2010) 1, 307.
摘要:Koutentis, P. A.; Ioannidou, H. A., Science of Synthesis Knowledge Updates, (2010) 1, 272.
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