CAS: 639-97-4; D-Apiose

该化合物是属于碳水化合物类别的天然甘醇,是一种粉笔糖,具体地说是一种五碳单沙律,在结构上与其他糖,如糖和xylose有联系.D-Apiose具有甜味的特点,经常出现在各种植物中,有助于它们的口味特征.D-Apiose在水中溶解,这增强了其在食品和饮料应用中的效用.该化合物由于在代谢过程中的作用等潜在的健康利益,在营养和生物化学领域引起了兴趣.此外,D-Apiose可用于合成其他有机化合物,使其在化学研究和工业中具有价值.D-Apiose在不同条件下的稳定性及其相对低的热量含量进一步有助于其在食品科学和与健康有关的研究中的吸引力.总的来说,D-Apiose是一种多用途化合物,对自然和应用科学都具有重大影响.

结构式图片

合成工艺路线路线简述

    📜(3S)-O2,O3-Isopropylidene-β-L-Apiofuranose置于dowex 50W (H+ Form)体系中,用 水 作为反应溶剂,化学反应 5.0H,反应生成 洋芹糖
    参考文献:Triterpenoid Saponins From Becium Grandiflorum Var. Obovatum
    标题:Triterpenoid Saponins From Becium Grandiflorum Var. Obovatum
    摘要:Two New Triterpenoid Saponins,Beciumecine I And 2,Were-Isolated From The Root Bark Of Becium Grandiflorum Var,Obovatum And Their Structures Established As 3-O-(Beta-D-Glucopyranosyl) Terminolic Acid 28-O-Beta-D-Apiofuranosyl(1-3)-[alpha-L-Rhamnopyranosyl(1-3)-Beta-D-Xylopyranosyl(1-4)]-Alpha-L-Rhamnopyranosyl(1-2)-Alpha-L-Arabinopyranoside And 3-O-(Beta-D-Glucopyranosyl) 24-Hydroxyterminolic Acid 28-O-Alpha-L-Rhamnopyranosyl(1-3)-Beta-D-Xylopyranosyl(1-4)-Alpha-L-Rhamnopyranosyl(1-2)-Alpha-L-Arabinopyranoside,Respectively. (C) 1998 Published By Elsevier Science Ltd. All Rights Reserved.
    DOI:10.1016/s0031-9422(98)00413-0

    海关参考信息

    专利信息


    专利号:WO-2024003514-A1
    优先权日:2022-06-29
    标题 :Methods and compositions relating to the synthesis of the qs-7 molecule
    发明人:OSBOURN ANNE; REED JAMES; ORME ANASTASIA; MARTIN LAETITIA
    权利人:PLANT BIOSCIENCE LTD
    摘要:The present invention relates to a biosynthetic route to precursors of the QS-7 molecule, as well as routes to make the QS-7 molecule, enzymes involved, the products produced and uses of the product.

    专利号:US-2025243525-A1
    优先权日:2022-06-24
    标 题 :Biocatalytic manufacture of sugar nucleotides
    发明人:HOEPKER ALEXANDER CHRIS; CILA MEGHA; GISKA FABIAN
    权利人:ZYMTRONIX CATALYTIC SYSTEMS INC
    摘要:The invention provides the production of sugar-nucleotides and the isolation of sugar-nucleotides. In some embodiments the production or isolation are accomplished under acidic conditions. The production is a cell-free synthesis using enzymes, including immobilized enzymes. They may be accomplished using a one-pot reaction protocol. The synthesis may be used as a highly customizable and highly efficient cell-free manufacturing process. In some embodiments, the sugar-nucleotides are used to prepare UDP-Gal, lactose derivatives, and human milk oligosaccharides (HMOs).

    专利号:EP-4547855-A1
    优先权日:2022-06-29
    标题 :Methods and compositions relating to the synthesis of the qs-7 molecule

    专利号:WO-2006053688-A1
    优先权日:2004-11-17
    标 题:Cosmetic and dermatological preparations for the treatment of mature skin
    发明人:DOERING THOMAS
    权利人:HENKEL KGAA; DOERING THOMAS
    摘要:The invention relates to topical cosmetic or dermatological compositions for the treatment of mature or intrinsically or extrinsically aged skin, in particular, for anti-wrinkle treatment, containing a combination of at least two selected peptides in a suitable cosmetic or dermatological vehicle, which have an effect at differing points of the process of collagen and/or fibronectin synthesis.

    专利号:WO-2006042625-A2
    优先权日:2004-10-15
    标 题 :Compositions with inhibitors of the synthesis of prostaglandin and/or of leukotriene in conjunction with stimulators of the release of cutaneous neuromediators

    专利号:EP-1799311-A2
    优先权日:2004-10-15
    标 题:Compositions with inhibitors of the synthesis of prostaglandin and/or of leukotriene in conjunction with stimulators of the release of cutaneous neuromediators

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s004250000481
    摘要:Willats WG, McCartney L, Knox JP. In-situ analysis of pectic polysaccharides in seed mucilage and at the root surface of Arabidopsis thaliana. Planta. 2001 May;213(1):37–44. doi: 10.1007/s004250000481.
    参考文献:10.1007/s00425-019-03220-4
    摘要:Landi M, Margaritopoulou T, Papadakis IE, Araniti F. Boron toxicity in higher plants: an update. Planta. 2019 Oct;250(4):1011–32. doi: 10.1007/s00425-019-03220-4.
    参考文献:10.1007/s004250050747
    摘要:Kosegarten, Grolig, Esch, Glusenkamp, Mengel. Effects of NH(4)(+), NO(3)(-) and HCO(3)(-) on apoplast pH in the outer cortex of root zones of maize, as measured by the fluorescence ratio of fluorescein boronic acid. Planta. 1999 Oct;209(4):444–52. doi: 10.1007/s004250050747.
    参考文献:10.1007/s10565-008-9085-7
    摘要:Barranco WT, Kim DH, Stella Jr. SL, Eckhert CD. Boric acid inhibits stored Ca2+ release in DU-145 prostate cancer cells. Cell Biology and Toxicology. 2008 May 31;25(4):309–20. doi: 10.1007/s10565-008-9085-7.
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