专利号:WO-2023123884-A1 优先权日:2021-12-31 标题 :Tetraaryl ethoxy side-chain mono-metallocene compound, catalyst system comprising same, and polyolefin synthesis method using same 发明人:MA KECUN; WANG YULONG; GAO MENG; YANG CHUNJI; JI YONGGANG; XU XIANMING; ZHAO GUANGHUI; ZENG QUNYING; LIANG LIWEI; ZHAO TIEKAI 权利人:PETROCHINA CO LTD 摘要:Disclosed in the present invention are a tetraaryl ethoxy side-chain mono-metallocene compound, a catalyst system containing same, and a polyolefin synthesis method using same. The structural formula of the tetraaryl ethoxy side-chain mono-metallocene compound is shown in FIG. 1, wherein M is selected from Ti, Zr or Hf; Cp' is selected from cyclopentadienyl, a substituted cyclopentadienyl, indenyl, a substituted indenyl, fluorenyl and a substituted fluorenyl; Ar is selected from phenyl and a substituted phenyl; and X is selected from halogen, alkyl, alkoxy, dialkylamino, phenyl and benzyl. An olefin polymerization reaction is catalyzed with a catalyst system containing the tetraaryl ethoxy side-chain mono-metallocene compound, and since the activity center of the tetraaryl ethoxy side-chain single metallocene is single, an α-olefin isomerization side reaction is highly inhibited, such that the α-olefin content of a polyisobutylene product can be significantly improved, and the molecular weight distribution of the product is reduced.
专利号:US-11643503-B2 优先权日:2020-07-10 标题 :Highly spherical polyamide microparticles and synthesis methods related thereto 发明人:JAMALI HOJJAT SEYED 权利人:XEROX CORP 摘要:A method of synthesizing polyamide microparticles may comprise: dehydrating and shearing a mixture comprising a matrix fluid, an emulsion stabilizer at about 0.01 wt % to about 50 wt % based on the weight of the matrix fluid, a solvent at about 13 wt % to about 75 wt % based on the weight of the matrix fluid, and a cyclic amide monomer at about 20 wt % to about 90 wt % based on the weight of the matrix fluid to yield an emulsion having a water content of about 1 wt % or less based on the total weight of the emulsion; adding a deprotonating agent to the emulsion at a concentration of about 0.01 wt % to about 1 wt % based on the weight of the matrix fluid; and contacting the emulsion with a polymerization initiator under conditions effective to polymerize the cyclic amide monomer into a plurality of polyamide microparticles.
专利号:ES-2393352-B1 优先权日:2011-06-07 标题 :DERIVATIVES OF SULFONIC ACID FOR SYNTHESIS OF BIODIESEL.
专利号:US-9893302-B2 优先权日:2013-03-06 标 题:Heterocyclic fluorescent dyes and method of production thereof 发明人:GRYKO DANIEL T; GRZYBOWSKI MAREK 权利人:BASF SE 摘要:The invention relates to novel compounds of formula (III) that can be used as heterocyclic dyes of unique structure and properties. These compounds can be obtained in a three-step synthesis from simple substrates. The compounds according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the compounds according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
专利号:US-8940895-B2 优先权日:2011-12-21 标 题:Heterocyclic fluorescent dyes and method of production thereof 发明人:GRZYBOWSKI MAREK; GRYKO DANIEL T 权利人:BASF SE 摘要:The invention relates to novel compounds of formula (III) that can be used as heterocyclic dyes of unique structure and properties. These dyes can be obtained in a three-step synthesis from simple substrates.
专利号:ES-2393352-A1 优先权日:2011-06-07 标题 :DERIVATIVES OF SULFONIC ACID FOR SYNTHESIS OF BIODIESEL.
参考文献:10.1007/s12668-023-01272-1 摘要:Goreninskii SI, Konishchev ME, Bolbasov EN, Evdokimov KE, Tran T, Trusova ME, Akhmedov SD, Tverdokhlebov SI. Physico-chemical Evaluation of Antiatherosclerotic Coronary Stent Coatings Based on Poly(lactic acid) Doped with Functionalized Fe@C Nanoparticles. BioNanoSci. 2023 Dec 18;14(1):447–56. doi: 10.1007/s12668-023-01272-1. 参考文献:10.1007/978-981-97-0264-0_59 摘要:Liu L, Xiong W, Fan W, Wang L. Study on the Synergistic Effects of Changqing Petroleum Sulfonate Complex System. 2024. In: Springer Series in Geomechanics and Geoengineering.