CAS: 41203-22-9; 1,4,8,11-Tetramethyl-1,4,8,11-Tetraazacyclotetradecane

该化合物是一种由14个环形结构组成的大型环形衍生物,通常称为替代环环环.该化合物具有很强的铬化特性,特别是具有过渡性金属离子,因为其四个氮捐献原子在硬循环框架内排列.甲基替代成分增强了其在有机溶剂中的溶解性,并影响其协调行为,使其在催化,金属离子提取和生物医学应用方面有用.该化合物对特定金属的稳定性和选择性有利于设计工业和研究目的的协调综合体.该化合物的结构僵硬性也有助于其在超分子化学方面的用途.

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相似化合物

214078-92-9 295-37-4 201610-16-4

欧盟法规

ECHA物质C&L通报

上下游产品

1,4,8,11-Tetraazacyclotetradecane methyl iodide 1,4,8,11-tetraazatricyclo[9.3.1.14,8]hexadecane 1,1,4,7,10,10-hexamethyltriethylenetetramine N,N,N,N,-tetramethylethylenediamine trans-dichloro(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N',N'',N''')rhodium(III) tetraphenylborate cryptand 211 1,1,4,7,10,10-hexamethyltriethylenetetramine

合成工艺路线路线简述

    📜1,4,8,11-四氮杂环十四烷置于sodium Hydroxide,聚合甲醛,甲酸体系中,用 水 作为反应溶剂,化学反应生成 1,4,8,11-四甲基-1,4,8,11-四氮环十四烷
    参考文献:Composition,Synthesis And Therapeutic Applications Of Polyamines
    标题:Composition,Synthesis And Therapeutic Applications Of Polyamines
    摘要:这项发明涉及一种合成和构成开链(环),闭环,线性分支和/或取代聚胺,聚胺衍生的酪氨酸磷酸酶抑制剂和ppar部分激动剂/部分拮抗剂的过程,通过一系列的取代反应来优化化合物的生物利用度和生物活性.聚胺可以预防神经毒素和导致糖尿病的毒素的毒性,包括百草枯,甲基苯基吡啶自由基,洛特侬,重组蛋白酶和阿洛克瑞.这些聚胺可以用于治疗哺乳动物主体中的神经系统,心血管系统,内分泌系统获得性和遗传性线粒体dna损伤疾病以及其他疾病,更具体地用于治疗帕金森病,阿尔茨海默病,路易氏氏病,宾斯旺格氏病,橄榄桥小脑变性,Lewy小体病,糖尿病,中风,动脉粥样硬化,心肌缺血,心肌病,肾病,缺血,青光眼,老年性耳聋,癌症,骨质疏松症,类风湿性关节炎,炎症性肠病,多发性硬化症以及作为毒素暴露的解毒剂.

    海关参考信息

    专利信息


    专利号:US-2024075466-A1
    优先权日:2021-04-09
    标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites
    发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE
    权利人:UMICORE AG & CO KG
    摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.

    专利号:US-9878313-B2
    优先权日:2012-12-12
    标题:One-pot method for the synthesis of Cu-SSZ-13, the compound obtained by the method and use thereof
    发明人:MARIN MANUEL MOLINER; FRANCO RAQUEL MARTINEZ; CANÓS AVELINO CORMA; THØGERSEN JOAKIM REIMER
    权利人:HALDOR TOPSOE AS
    摘要:Process for the direct synthesis of Cu-SSZ-13 from a synthesis mixture comprising water, at least one silicon source, at least one Al source, at least one Cu source, at least one polyamine for complexing with Cu, and a single organic structure directing agent. A Cu containing molecular sieve having the framework structure of SSZ-13, obtainable by the process and use of the Cu containing molecular sieve.

    专利号:US-9561498-B2
    优先权日:2012-04-27
    标 题 :Process for the direct synthesis of Cu-SAPO-34
    发明人:FRANCO RAQUEL MARTINEZ; MARIN MANUEL MOLINER; CANÓS AVELINO CORMA; KUSTOV ARKADY; THØGERSEN JOAKIM REIMER
    权利人:FRANCO RAQUEL MARTINEZ; MARIN MANUEL MOLINER; CANÓS AVELINO CORMA; KUSTOV ARKADY; THØGERSEN JOAKIM REIMER; HALDOR TOPSOE AS
    摘要:A process for the direct synthesis of Cu-SAPO-34 comprising at least the steps: preparation of a mixture of water, at least one silicon source, at least one Al source, at least one P source, at least one Cu source, at least one 0SDA1 (any polyamine), and at least one OSDA2 source (where OSDA2 is any organic molecule capable of directing the synthesis of SAPO 34); and where the final synthesis mixture has the molar composition: a Si:0.5 Al:c Cu:d OSDA1:e OSDA2:f H2O wherein a is in the range from 0.01 to 0.3; b is in the range from 0.2 to 0.49; c is in the range from 0.001 to 0.6; d is in the range from 0.001 to 0.6; e is in the range from 0.001 to 2; f is in the range 1 to 200; hydrothermal treatment of the mixture at 80−200° C. until formation of the crystalline material, and recovery of the crystalline material.

    专利号:US-10676367-B2
    优先权日:2015-05-05
    标 题 :Direct synthesis of Cu-CHA by means of combining a Cu complex and tetraethylammonium and applications in catalysis
    发明人:CORMA CANÓS AVELINO; MOLINER MARÃ?N MANUEL; MARTIN GARCIA NURIA
    权利人:CONSEJO SUPERIOR INVESTIGACION; UNIV VALENCIA POLITECNICA
    摘要:The present invention relates to a process for the direct synthesis of a material with a CHA zeolite structure in the silicoaluminate form thereof containing copper atoms, which comprises at least the following steps:n (i) Preparation of a mixture which contains at least one water source, one copper source, one polyamine, one source of Y tetravalent element, one source of X trivalent element, the tetraethylammonium cation as the only OSDA and one source of alkaline or alkaline earth (A) cations, and wherein the synthesis mixture has the following molar composition:n nYO 2 :aX 2 O 3 :bOSDA:cA:dH 2 O:eCu:fpolyaminen (ii) Crystallization of the mixture obtained in (i) in a reactor; (iii) Recovery of the crystalline material obtained in (ii).

    专利号:US-10005076-B2
    优先权日:2014-06-03
    标题 :Synthesis of SAPO-18 and the catalytic applications thereof
    发明人:CORMA CANÓS AVELINO; MOLINER MARÃ?N MANUEL; MARTÃ?NEZ FRANCO RAQUEL
    权利人:CONSEJO SUPERIOR INVESTIGACION; UNIV VALENCIA POLITECNICA
    摘要:Synthesis of the silicoaluminophosphate and metal silicoaluminophosphate polymorphs of the molecular sieve SAPO-18 using cyclic quaternary ammoniums as organic structure-directing agents (OSDA) and use thereof as a catalyst.

    专利号:US-10792617-B2
    优先权日:2015-04-16
    标 题 :Method for the direct synthesis of Cu-containing silicoaluminate material with the AEI zeolite structure, and the catalytic applications thereof
    发明人:CORMA CANOS AVELINO; MOLINER MARIN MANUEL; MARTIN GARCIA NURIA
    权利人:CONSEJO SUPERIOR INVESTIGACION; UNIV VALENCIA POLITECNICA
    摘要:The main object of the present invention is to provide a new method for preparing the copper-containing silicoaluminate form of the AEI zeolite structure by means of a direct synthesis methodology. This new process involves combining a organometallic copper-complex with an additional organic molecule capable of directing the crystallisation of the silicoaluminate form of the AEI zeolite structure as organic structure-directing agents (OSDAs).

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1021/jp057191i
    摘要:Coullerez G, Malmström E, Jonsson M. Solvent effects on the redox properties of Cu complexes used as mediators in atom transfer radical polymerization. J Phys Chem A. 2006 Aug 31;110(34):10355–60. doi: 10.1021/jp057191i.
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