CAS: 2212-67-1; Molinate

该化合物是一种化学化合物,被归类为除草剂,主要用于农业,以控制稻田中的某些杂草;它属于硫氨酸盐家族,以对草和一些大叶杂草采取选择性行动而著称;软糖的分子结构具有硫氯酸酯功能组的特点,有助于其除草性能;它通常在发芽前和发芽后阶段应用,以抑制杂草生长;它的特点在于水中的中等溶性及其在环境中降解的能力,尽管它在某些条件下可能持续存在于土壤中;安全考虑很重要,因为软糖与潜在的健康风险有关,导致在各区域进行监管检查;它的使用必须遵守具体准则,以尽量减少环境影响,确保农业工人和消费者的安全;

结构式图片

欧盟法规

统一分类与标签"欧盟管控危险化学品"ECHA物质欧盟农药活性物质ECHA物质化妆品禁用物质清单C&L通报食品接触材料-禁用CMR物质工作场所安全标识要求OtherREACH预注册废弃物危险特性清单

上下游产品

CAS号111-49-9 环己亚胺 | CAS号201230-82-2 carbon monoxide | CAS号75-03-6 碘乙烷 | CAS号101506-43-8 O-(1-chloroethy... | CAS号64-67-5 硫酸二乙酯 | CAS号56525-84-9 O-ethyl azepane... | CAS号463-58-1 羰基硫 | CAS号54404-54-5 molinate-sulfone

合成工艺路线路线简述

    📜环己亚胺置于potassium Carbonate,Sulfur体系中,用 二甲基亚砜 用作溶剂,20.0 °C,101.33 Kpa 条件下,反应 6.0H,反应生成禾草敌
    参考文献:通过一氧化碳和硫将胺羰基化来实际合成s-烷基硫代氨基甲酸酯除草剂
    标题:通过一氧化碳和硫将胺羰基化来实际合成s-烷基硫代氨基甲酸酯除草剂
    摘要:已经开发了胺与一氧化碳和硫的工业和经济羰基化,以合成硫代氨基甲酸酯的s-烷基除草剂.在碳酸钾和dmso溶剂存在下,在温和的条件下(1 Atm,20oc)由胺,一氧化碳,硫和烷基卤化物以优异的收率合成s-烷基硫代氨基甲酸酯,例如硫代苯甲酸酯和邻苯甲酸酯(除草剂) .
    Doi:10.1016/j.Tet.2004.01.060

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:UY-34940-A
    优先权日:2012-07-24
    标题 :HERBICIDE COMPOSITIONS CONTAINING 4-AMINO-3-CHLORO-5-FLUOR-6- (4-CHLORO-2-FLUOR-3-METOXY-PHENYL) ACID-2-CARBOXYL, OR A DERIVATIVE OF THE SAME AND THE HERBICIDES THAT INHIBIT THE SYNTHESIS OF THE VERY LONG CHAIN FATTY ACIDS AND THE SYNTHESIS OF THE FAT / LIPID ACIDS

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Davoodi M, Davar F, Rezayat MR, Jafari MT, Shalan AE. Expression of concern: Cobalt metal-organic framework-based ZIF-67 for the trace determination of herbicide molinate by ion mobility spectrometry: investigation of different morphologies. RSC Adv. 2023 Nov 9;13(47):33079. doi: 10.1039/d3ra90112b.
    2: Lee H, An G, Park J, Lim W, Song G. Molinate induces organ defects by promoting apoptosis, inflammation, and endoplasmic reticulum stress during the developmental stage of zebrafish. Sci Total Environ. 2023 Aug 10;885:163768. doi: 10.1016/j.scitotenv.2023.163768. Epub 2023 May 3. 12(1):15502. doi: 10.1038/s41598-022-18732-5.
    4: Heidarbeigi M, Jafari MT, Saraji M. Centrifuge-free dispersive liquid-liquid microextraction coupled with thin-film microextraction for the preconcentration of molinate in real samples by ion mobility spectrometry. Talanta. 2021 Apr 1;225:122027. doi: 10.1016/j.talanta.2020.122027. Epub 2020 Dec 30. 11(5):2643-2655. doi: 10.1039/d0ra09298c.

    合成参考文献


    参考文献:10.1007/s10661-011-2167-7
    摘要:Anjum R, Malik A. Mutagenicity assessment of contaminated soil in the vicinity of industrial area. Environmental Monitoring and Assessment. 2011 Jul 15;184(5):3013–26. doi: 10.1007/s10661-011-2167-7.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知