CAS: 1813-60-1; Tetrabutylphosphonium Tetrafluoroborate

该化合物是一种四氟磷盐,其化学配方为 \ ([C_4H_9]_4P[BF_4]_4-\].该离子化合物以高热稳定性和低粘度而著称,因此适合作为电解剂应用于电化学系统,包括电池和电容器,其四氟乙酸阴离子有助于极地有机溶剂中良好的溶解性,而四丁基磷酸盐则在恶劣条件下增强稳定性.该化合物还被用作有机合成中的逐步转移催化剂,因为它能够促进不易相交阶段之间的反应.其非腐化性质和宽阔的电化学窗口进一步扩大了其先进材料研究的效用.

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相似化合物

2304-30-5 3115-68-2 113978-91-9

欧盟法规

C&L通报

合成工艺路线路线简述

    📜四正丁基溴化膦置于氟硼酸钠体系中,用 水 用作溶剂,以93%的收率获得四丁基膦四氟硼酸盐
    参考文献:Chemisorption Of Carbon Dioxide In Carboxylate-Functionalized Ionic Liquids: A Mechanistic Study
    标题:Chemisorption Of Carbon Dioxide In Carboxylate-Functionalized Ionic Liquids: A Mechanistic Study
    摘要:以羧酸根功能化离子液体为例,对甲酸四正丁基鏻对 Co2 化学吸附的光谱研究表明,氢键配合物(例如二甲酸根阴离子)的形成提供了化学吸附的驱动力.
    Doi:10.1246/cl.131180

    海关参考信息

    专利信息


    专利号:US-2023286918-A1
    优先权日:2020-07-02
    标 题:Manufacturing process for 3,5-dichloropicolinonitrile for synthesis of vadadustat
    发明人:JURKAUSKAS VALDAS; JUNG YOUNG CHUN; KWON TAESOO; KANNAN ARUNACHALAM; GONDI VIJAYA BHASKER
    权利人:AKEBIA THERAPEUTICS INC
    摘要:Disclosed herein are methods and processes of preparing vadadustat or a pharmaceutically acceptable salts thereof, and intermediates (e.g., a compound of Formula (I), (I-F), (II), or (IV), or a pharmaceutically acceptable salts thereof) useful for the synthesis of vadadustat.

    专利号:US-4451680-A
    优先权日:1982-10-21
    标题:Alcohols prepared from olefins and synthesis gas
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention concerns a process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound coupled with one or more bidentate or multidentate, phosphine-containing promoters, dispersed in a low melting quaternary phosphonium salt, and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.

    专利号:US-4451679-A
    优先权日:1982-10-21
    标题 :Alcohols and aldehydes prepared from olefins and synthesis gas
    发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRIGSBY JR ROBERT A; BRADER JR WALTER H
    权利人:TEXACO INC
    摘要:This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols and aldehydes.

    专利号:US-4469895-A
    优先权日:1982-10-21
    标题 :Process for preparing alcohols from olefins and synthesis gas
    发明人:KNIFTON JOHN F; GRIGSBY JR ROBERT A
    权利人:TEXACO INC
    摘要:This invention concerns an improved process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound in conjunction with one or more tertiary amine promoters, dispersed in a low melting quaternary phosphonium salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.

    专利号:US-4332914-A
    优先权日:1981-06-26
    标 题 :Manufacture of alkanols from synthesis gas
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention concerns a process of making alkanols and particularly methanol which comprises the steps of contacting a mixture of CO and H2 with a catalyst system comprising a ruthenium-containing compound and a halogen-free rhenium-containing compound or a halogen-free manganese-containing compound dispersed in a low melting quaternary phosphonium base or salt, and heating said resultant reaction mixture under a pressure of 500 psig or greater at a temperature of at least 150 DEG C.

    专利号:US-4265828-A
    优先权日:1979-12-31
    标 题 :Manufacture of ethylene glycol from synthesis gas
    发明人:KNIFTON JOHN F
    权利人:TEXACO DEVELOPMENT CORP
    摘要:This invention concerns a process of making ethylene glycol which comprises the steps of contacting a mixture of CO and H2 with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt, and heating said resultant reaction mixture under a pressure of 500 psi or greater at a temperature of at least 150 DEG C. for a sufficient time to provide said ethylene glycol.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Schiltz, P.; Gosmini, C., Science of Synthesis: Special Topics, (2021) 1, 92.
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